(Comparison of group transfer, inner sphere and outer sphere electron transfer mechanisms of organometallic complexes: Progress report)

Technical Report · Mon Jan 01 00:00:00 EST 1990

DOI:https://doi.org/10.2172/5573799· OSTI ID:5573799

Atwood, J

We have constructed an infrared stopped-flow spectrophotometer and initiated a study of the mechanisms of reactions that involve a change in the oxidation state of organometallic complexes. In this summary we highlight our results on reactions (1) that formally involve exchange of a charged species between two metal carbonyl anions, (2) that involve addition of an electron to, or removal of an electron from organometallic complexes that contain a metal-metal bond, and (3) between coordination complexes and metal carbonyl anions.

• Research Organization: State Univ. of New York, Buffalo, NY (United States). Research Foundation
• Sponsoring Organization: USDOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG02-87ER13775
• OSTI ID: 5573799
• Report Number(s): DOE/ER/13775-3; ON: DE92012539
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ORGANOMETALLIC COMPOUNDS
CHARGE EXCHANGE
ELECTRON TRANSFER
ANIONS
CARBON MONOXIDE LASERS
CARBONYLS
INFRARED SPECTROMETERS
LIQUID FLOW
PROGRESS REPORT
CHARGED PARTICLES
DOCUMENT TYPES
FLUID FLOW
GAS LASERS
IONS
LASERS
MEASURING INSTRUMENTS
ORGANIC COMPOUNDS
SPECTROMETERS
400201* - Chemical & Physicochemical Properties