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Title: Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ compounds with layer structure (Ln: Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn)

Abstract

A series of new compounds Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ (Ln : Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn) were successfully synthesized and their lattice constants were determined. These compounds have the same crystal structure as YbFe/sub 2/O/sub 4/ and Fe/sup 3 +/ and M/sup 2 +/ are both surrounded by five oxygen ions forming a trigonal bipyramid. The synthetic conditions are presented. They are strongly dependent upon the constituent cations of the compound.

Authors:
;
Publication Date:
Research Org.:
National Inst. for Research in Inorganic Materials, Japan
OSTI Identifier:
5555332
Resource Type:
Journal Article
Journal Name:
J. Solid State Chem.; (United States)
Additional Journal Information:
Journal Volume: 40:1
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COBALT OXIDES; CHEMICAL PREPARATION; CRYSTAL LATTICES; LATTICE PARAMETERS; COPPER OXIDES; ERBIUM OXIDES; IRON OXIDES; LUTETIUM OXIDES; MAGNESIUM OXIDES; MANGANESE OXIDES; THULIUM OXIDES; YTTERBIUM OXIDES; YTTRIUM OXIDES; ZINC OXIDES; EXPERIMENTAL DATA; X-RAY DIFFRACTION; ALKALINE EARTH METAL COMPOUNDS; CHALCOGENIDES; COBALT COMPOUNDS; COHERENT SCATTERING; COPPER COMPOUNDS; CRYSTAL STRUCTURE; DATA; DIFFRACTION; ERBIUM COMPOUNDS; INFORMATION; IRON COMPOUNDS; LUTETIUM COMPOUNDS; MAGNESIUM COMPOUNDS; MANGANESE COMPOUNDS; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; SCATTERING; SYNTHESIS; THULIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; YTTERBIUM COMPOUNDS; YTTRIUM COMPOUNDS; ZINC COMPOUNDS; 400201* - Chemical & Physicochemical Properties

Citation Formats

Kimizuka, N, and Takayama, E. Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ compounds with layer structure (Ln: Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn). United States: N. p., 1981. Web. doi:10.1016/0022-4596(81)90368-6.
Kimizuka, N, & Takayama, E. Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ compounds with layer structure (Ln: Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn). United States. https://doi.org/10.1016/0022-4596(81)90368-6
Kimizuka, N, and Takayama, E. 1981. "Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ compounds with layer structure (Ln: Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn)". United States. https://doi.org/10.1016/0022-4596(81)90368-6.
@article{osti_5555332,
title = {Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ compounds with layer structure (Ln: Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn)},
author = {Kimizuka, N and Takayama, E},
abstractNote = {A series of new compounds Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ (Ln : Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn) were successfully synthesized and their lattice constants were determined. These compounds have the same crystal structure as YbFe/sub 2/O/sub 4/ and Fe/sup 3 +/ and M/sup 2 +/ are both surrounded by five oxygen ions forming a trigonal bipyramid. The synthetic conditions are presented. They are strongly dependent upon the constituent cations of the compound.},
doi = {10.1016/0022-4596(81)90368-6},
url = {https://www.osti.gov/biblio/5555332}, journal = {J. Solid State Chem.; (United States)},
number = ,
volume = 40:1,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 1981},
month = {Thu Jan 01 00:00:00 EST 1981}
}