Reactivity of the linear tetranuclear ruthenium cluster Ru{sub 4}(CO){sub 10}[CH{sub 3}C=C(H)C(H)=NC(H)(CH{sub 3}){sub 2}]{sub 2} toward CO. Regioselective aliphatic C-H activation processes and the X-ray crystal structure of Ru{sub 2}(CO){sub 6}[CH{sub 3}CC(H)C(H)N=C(CH{sub 3}){sub 2}]
- Universiteit van Amsterdam (Netherlands); and others
The chemical reactivity of the linear tetranuclear ruthenium cluster toward CO was determined. The conversion of the ligands under exclusion of light took from 3 days to 2 weeks and was reversible. The X-ray crystal structure has also been determined. 44 refs., 1 fig., 5 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 552722
- Journal Information:
- Organometallics, Vol. 11, Issue 5; Other Information: PBD: May 1992
- Country of Publication:
- United States
- Language:
- English
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