Mechanisms of photoinduced electron transfer: Final report, July 1, 1977-September 30, 1987
Work which has been conducted under Department of Energy sponsorship over the past ten years at Boston University is described. A general theme for projects which are summarized involves photochemically induced electron transfer reactions for organic compounds. Early studies in the series were directed to the development of new mechanisms for driving isomerization processes which store light energy as latent heat. Other investigations were devoted to an understanding of the dynamics of charge separation for photoexcited (charge-transfer) complexes or ion-pairs. Recent studies focused on the development of charge relays such as dithioethers and viologen or pyridinium ions, the electron transfer photochemistry of high potential quinones, and the photophysical properties of organic dyes bound to water-soluble polymers. 9 figs.
- Research Organization:
- Boston Univ., MA (USA). Dept. of Chemistry
- DOE Contract Number:
- AC02-77ER04380
- OSTI ID:
- 5482942
- Report Number(s):
- DOE/ER/04380-8; ON: DE88004917
- Resource Relation:
- Other Information: Portions of this document are illegible in microfiche products
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
25 ENERGY STORAGE
PHOTOCHEMICAL REACTIONS
ELECTRON TRANSFER
RESEARCH PROGRAMS
DYES
EXPERIMENTAL DATA
ISOMERIZATION
PHOTOCHEMICAL ENERGY STORAGE
PHOTOLYSIS
PROGRESS REPORT
REDOX REACTIONS
CHEMICAL REACTIONS
DATA
DECOMPOSITION
DOCUMENT TYPES
ENERGY STORAGE
INFORMATION
NUMERICAL DATA
STORAGE
400500* - Photochemistry
250800 - Energy Storage- Chemical