Screening of alkali-promoted vapor-phase-synthesized molybdenum sulfide catalysts for the production of alcohols from synthesis gas
- West Virginia Univ., Morgantown, WV (United States)
A series of molybdenum sulfide catalysts has been prepared using vapor-phase decomposition of molybdenum hexacarbonyl in an atmosphere of hydrogen sulfide. The effect of the decomposition conditions on the properties of the molybdenum sulfides formed has been studied over a temperature range of 300--900 C. These materials, when promoted with alkali, have been found to have a high activity for the production of alcohols from synthesis gas. The effects of the catalyst preparation temperature (i.e., decomposition temperature) and reaction conditions (temperature, flow rate) have been studied, as well as the effect of the type and concentration of the alkali promoter. In all cases, the alcohols formed are primarily straight-chain, terminal {single_bond}OH compounds. The variations in preparation procedure have only small effects on the conversion and the selectivity to higher alcohols. Increasing the reactant flow rate increases the selectivity to methanol at the expense of the hydrocarbons and the higher-molecular-weight alcohols. Increasing the reaction temperature changes the selectivity toward higher alcohols but also changes the selectivity toward hydrocarbons. A maximum in selectivity to higher alcohols with the reaction temperature is observed for all catalysts tested.
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC22-91PC91034
- OSTI ID:
- 536414
- Journal Information:
- Industrial and Engineering Chemistry Research, Vol. 36, Issue 8; Other Information: PBD: Aug 1997
- Country of Publication:
- United States
- Language:
- English
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