Quantitative analysis of orthorhombic and tetragonal lead monoxide mixtures using internal standard raman spectroscopy

Journal Article · Mon Oct 01 00:00:00 EDT 1984 · Proc. - Electrochem. Soc.; (United States)

OSTI ID:5319964

Trischan, G M

A Raman spectroscopic method has been developed for the quantitative analysis of mixed oxide materials for orthorhombic and tetragonal phases of PbO. The technique employs an Sb/sub 2/O/sub 3/ internal standard for improved analytical reliability. Samples mixed with KBr are pelletized onto a pure KBr support substrate. The sample pellets are rotated during analysis to minimize irradiation induced alteration or damage. Linear responses for both o-PbO and t-PbO throughout the entire concentration range have been observed. The presence of metallic Pb, which is a Raman inactive material, does not appear to interfere significantly with the linearity of the response.

• Research Organization: Johnson Controls Inc., Milwaukee WI
• OSTI ID: 5319964
• Journal Information: Proc. - Electrochem. Soc.; (United States), Vol. 84-14
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
LEAD OXIDES
QUANTITATIVE CHEMICAL ANALYSIS
RAMAN SPECTROSCOPY
LEAD-ACID BATTERIES
RELIABILITY
CHALCOGENIDES
CHEMICAL ANALYSIS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
LASER SPECTROSCOPY
LEAD COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SPECTROSCOPY
250903* - Energy Storage- Batteries- Materials
Components
& Auxiliaries