Some laws governing the electrosynthesis of organic compounds with a solid polymetric electrolyte

Journal Article · Wed Jan 01 00:00:00 EST 1986 · Sov. Electrochem. (Engl. Transl.); (United States)

OSTI ID:5264161

Rodionova, N A; Avrutskaya, I A; Fioshin, M Ya; Khrizolitova, M A

The electrosynthesis of organic compounds with a solid polymetric electrolyte (SPE) makes it possible to carry out the process in the absence of a supporting electrolyte. This facilitates the recovery of the desired product, eliminates the inorganic waste products, and allows a small interelectrode distance, and the absence of the accumulation of gases lowers the voltage in the cell. Some laws governing syntheses of SPE were studied in the example cases of the electrochemical reduction of 2,2,6,6-tetramethyl-4-oxopiperidine to 2,2,6,6-tetramethyl-4-hydroxy-piperidine, the reduction of triacetonamine oxime and triacetonamine azine to 2,2,6,6-tetramethyl-4- aminopiperidine and the oxidation of isobutanol to isobutyric acid. The electrolysis with an SPE was carried out under galvanostatic conditions in an electrolyzer of the filter-press type with forced circulation of the catholyte and anolyte. Low reaction rates are found to be characteristic of all the compounds investigated when the electrolysis is carried out with an SPE.

• Research Organization: D.I. Mendeleev Moscow Chemical Technology Institute
• OSTI ID: 5264161
• Journal Information: Sov. Electrochem. (Engl. Transl.); (United States), Vol. 21:7
• Country of Publication: United States
• Language: English

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ELECTROLYTIC CELLS
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