Cermets and method for making same
The present invention is directed to a method for making a wide variety of general-purpose cermets and for radioactive waste disposal from ceramic powders prepared from urea-dispersed solutions containing various metal values. The powders are formed into a compact and subjected to a rapid temperature increase in a reducing atmosphere. During this reduction, one or more of the more readily reducible oxides in the compact is reduced to a selected substoichiometric state at a temperature below the eutectic phase for that particular oxide or oxides and then raised to a temperature greater than the eutectic temperature to provide a liquid phase in the compact prior to the reduction of the liquid phase forming oxide to solid metal. This liquid phase forms at a temperature below the melting temperature of the metal and bonds together the remaining particulates in the cermet to form a solid polycrystalline cermet.
- DOE Contract Number:
- W-7405-ENG-26
- Assignee:
- Dept. of Energy
- Application Number:
- ON: DE82007303
- OSTI ID:
- 5227809
- Country of Publication:
- United States
- Language:
- English
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Cermets and method for making same
CERAMICS RESEARCH
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12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
CERMETS
REDUCTION
RADIOACTIVE WASTE PROCESSING
EUTECTICS
PHASE TRANSFORMATIONS
CHEMICAL REACTIONS
COMPOSITE MATERIALS
MANAGEMENT
MATERIALS
PROCESSING
WASTE MANAGEMENT
WASTE PROCESSING
360201* - Ceramics
Cermets
& Refractories- Preparation & Fabrication
052001 - Nuclear Fuels- Waste Processing