Regular solution theory and the surface tensions of molten salt mixtures. 2. Thallium nitrate--lithium nitrate and thallium nitrate--potassium nitrate

Journal Article · Thu Feb 23 00:00:00 EST 1978 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100493a011· OSTI ID:5171414

Nissen, D A

The isothermal surface tensions of the binary, charge-symmetrical mixtures TlNO/sub 3/-LiNO/sub 3/ and TlNO/sub 3/-KNO/sub 3/ are compared with values calculated from equations based on regular solution theory. The deviations found are attributed to the presence of significant non-Coulombic interactions in the melt which invalidate the random mixing assumption implicit in the theoretical equations.

• Research Organization: Sandia Labs., Livermore, CA
• OSTI ID: 5171414
• Journal Information: J. Phys. Chem.; (United States), Vol. 82:4
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
THALLIUM NITRATES
SURFACE TENSION
LITHIUM NITRATES
POTASSIUM NITRATES
BINARY MIXTURES
MOLTEN SALTS
ALKALI METAL COMPOUNDS
DISPERSIONS
LITHIUM COMPOUNDS
MIXTURES
NITRATES
NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
SALTS
SURFACE PROPERTIES
THALLIUM COMPOUNDS
400201* - Chemical & Physicochemical Properties