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Title: Promoter effect of iron on olefin hydroformylation catalyzed by SiO/sub 2/-supported rhodium-iron bimetallic carbonyl clusters: Rh-Fe/sup 3 +/ bimetallic activation of catalytic CO insertion

Abstract

Rh-Fe bimetallic carbonyl clusters have been employed as precursor for the preparation of Rh-Fe bimetallic catalysts. The structural properties of the Rh-Fe bimetallic cluster supported on SiO/sub 2/ were studied by means of Moessbauer and ir spectroscopy of chemisorbed CO. The results reported for the hydroformylation of ethylene and propylene indicate that the Rh-Fe/sup 3 +/ species derived from SiO/sub 2/-supported Rh-Fe carbonyl clusters are highly active for migratory CO insertion. These catalysts also enhanced the simple hydrogenation reactions. The activity and selectivity of the catalysts is thought to be due to the bi-site interaction with C- and O-bonded CO that is reflected in Fe promotion for C/sub 1/-C/sub 2/ alcohol production from CO and H/sub 2/ catalyzed on the Rh-Fe catalysts. 20 references, 1 table.

Authors:
; ; ;
Publication Date:
Research Org.:
Hokkaido Univ., Sapporo (Japan)
OSTI Identifier:
5081684
DOE Contract Number:  
FG02-86ER13640
Resource Type:
Journal Article
Journal Name:
Inorg. Chem.; (United States)
Additional Journal Information:
Journal Volume: 26:22
Country of Publication:
United States
Language:
English
Subject:
10 SYNTHETIC FUELS; ETHANOL; CHEMICAL PREPARATION; ETHYLENE; CARBONYLATION; IRON; CATALYTIC EFFECTS; METHANOL; PROPYLENE; RUTHENIUM; SILICA; CATALYST SUPPORTS; CATALYSIS; ALCOHOLS; ALKENES; CHALCOGENIDES; CHEMICAL REACTIONS; ELEMENTS; HYDROCARBONS; HYDROXY COMPOUNDS; METALS; MINERALS; ORGANIC COMPOUNDS; OXIDE MINERALS; OXIDES; OXYGEN COMPOUNDS; PLATINUM METALS; SILICON COMPOUNDS; SILICON OXIDES; SYNTHESIS; TRANSITION ELEMENTS; 090221* - Alcohol Fuels- Chemical Synthesis- (1976-1989); 090110 - Hydrocarbon Fuels- Properties- (1979-1989)

Citation Formats

Fukuoka, A, Ichikawa, M, Hriljac, J A, and Shriver, D R. Promoter effect of iron on olefin hydroformylation catalyzed by SiO/sub 2/-supported rhodium-iron bimetallic carbonyl clusters: Rh-Fe/sup 3 +/ bimetallic activation of catalytic CO insertion. United States: N. p., 1987. Web. doi:10.1021/ic00269a001.
Fukuoka, A, Ichikawa, M, Hriljac, J A, & Shriver, D R. Promoter effect of iron on olefin hydroformylation catalyzed by SiO/sub 2/-supported rhodium-iron bimetallic carbonyl clusters: Rh-Fe/sup 3 +/ bimetallic activation of catalytic CO insertion. United States. https://doi.org/10.1021/ic00269a001
Fukuoka, A, Ichikawa, M, Hriljac, J A, and Shriver, D R. 1987. "Promoter effect of iron on olefin hydroformylation catalyzed by SiO/sub 2/-supported rhodium-iron bimetallic carbonyl clusters: Rh-Fe/sup 3 +/ bimetallic activation of catalytic CO insertion". United States. https://doi.org/10.1021/ic00269a001.
@article{osti_5081684,
title = {Promoter effect of iron on olefin hydroformylation catalyzed by SiO/sub 2/-supported rhodium-iron bimetallic carbonyl clusters: Rh-Fe/sup 3 +/ bimetallic activation of catalytic CO insertion},
author = {Fukuoka, A and Ichikawa, M and Hriljac, J A and Shriver, D R},
abstractNote = {Rh-Fe bimetallic carbonyl clusters have been employed as precursor for the preparation of Rh-Fe bimetallic catalysts. The structural properties of the Rh-Fe bimetallic cluster supported on SiO/sub 2/ were studied by means of Moessbauer and ir spectroscopy of chemisorbed CO. The results reported for the hydroformylation of ethylene and propylene indicate that the Rh-Fe/sup 3 +/ species derived from SiO/sub 2/-supported Rh-Fe carbonyl clusters are highly active for migratory CO insertion. These catalysts also enhanced the simple hydrogenation reactions. The activity and selectivity of the catalysts is thought to be due to the bi-site interaction with C- and O-bonded CO that is reflected in Fe promotion for C/sub 1/-C/sub 2/ alcohol production from CO and H/sub 2/ catalyzed on the Rh-Fe catalysts. 20 references, 1 table.},
doi = {10.1021/ic00269a001},
url = {https://www.osti.gov/biblio/5081684}, journal = {Inorg. Chem.; (United States)},
number = ,
volume = 26:22,
place = {United States},
year = {1987},
month = {11}
}