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Title: Thermal acceleration of ozone interaction with graphite and other organocarbons

Authors:
;
Publication Date:
Research Org.:
Sandia Labs., Albuquerque, N.Mex. (USA)
OSTI Identifier:
5052583
Report Number(s):
SAND-75-0538
DOE Contract Number:
AT(29-1)-789
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; GRAPHITE; CHEMICAL REACTIONS; HYDROCARBONS; OZONE; BONDING; CLEANING; CORONA DISCHARGES; DEFECTS; ELECTRONIC CIRCUITS; METALLURGICAL FLUX; REMOVAL; TEMPERATURE DEPENDENCE; CARBON; ELECTRIC DISCHARGES; ELEMENTS; FABRICATION; JOINING; NONMETALS; ORGANIC COMPOUNDS; 360604* - Materials- Corrosion, Erosion, & Degradation; 360105 - Metals & Alloys- Corrosion & Erosion

Citation Formats

Hof, G.J., and Sharp, D.J. Thermal acceleration of ozone interaction with graphite and other organocarbons. United States: N. p., 1975. Web. doi:10.2172/5052583.
Hof, G.J., & Sharp, D.J. Thermal acceleration of ozone interaction with graphite and other organocarbons. United States. doi:10.2172/5052583.
Hof, G.J., and Sharp, D.J. Wed . "Thermal acceleration of ozone interaction with graphite and other organocarbons". United States. doi:10.2172/5052583. https://www.osti.gov/servlets/purl/5052583.
@article{osti_5052583,
title = {Thermal acceleration of ozone interaction with graphite and other organocarbons},
author = {Hof, G.J. and Sharp, D.J.},
abstractNote = {},
doi = {10.2172/5052583},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Oct 01 00:00:00 EDT 1975},
month = {Wed Oct 01 00:00:00 EDT 1975}
}

Technical Report:

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  • Selected newer literature from 1986 through 1988 on the vegetation and health effects resulting from exposure to ozone is reviewed and summarized for the purpose of providing the Agency with information useful in identifying new data that may be relevant for developing primary and secondary National Ambient Air Quality Standards for Ozone.
  • Since completion of the 1986 Air Quality Criteria Document for Ozone, additional information has become available that warrants consideration by U.S. Environmental Protection Agency (U.S. EPA) in its review of the National Ambient Air Quality Standards (NAAQS) for ozone. The summary reviews and evaluates selected literature published from 1986 through early 1989 on the vegetation and health effects resulting from exposure to ozone. Emphasis has been placed on evaluation of key human health effects literature and other data most pertinent to determination by U.S. EPA of the appropriate level and form of the primary NAAQs and the appropriate form ofmore » the secondary NAAQs.« less
  • Molten sodium attacks artificial graphites, causing dilation and, under some conditions, decrepitation. Because of the anisotropy of extruded grsphite, dilation perpendicular to the extrusion axis is slightly greater than parallel to the extension axis. At 600 to 1OOO deg F, sodium is initially nonwetting to graphite, but becomes wetting in a matter of minutes. The liqiud soaks into the pores of the graphite through chemisorption and intergranular penetration; in- terlamellar compounds or complexes may also be formed. Coatings and coating techniques were investigated for the protection of graphite from attack by molten sodium. The coatings examined included chromium, nickel, zirconium,more » zirconium carbide, tungsten carbide, silicon carbide, silicon nitride, and molybdenum disilicide. None of the coatings, tested by soaking in static sodium at 1OOO deg F, gave satisfactory protection. Failure in all cases resulted from continuous porosity or cracks in the coating material. (auth)« less