Role of nitrogen atoms and electronically (N/sub 2/(A/sup 3/. sigma. /sup +/ /SUB u/ )) and vibrationally excited nitrogen molecules in the decomposition of hydrazine
Journal Article
·
· High Energy Chem. (Engl. Transl.); (United States)
OSTI ID:5030739
The decomposition of hydrazine molecules in a nitrogen afterglow at an overall pressure of 1.87 kPa is examined. Based on experimental data, estimates are made of the effect of nitrogen atoms, as well as of electronically (N/sub 2/(A/sup 3/..sigma../sup +/ /SUB u/ )) and vibrationally excited nitrogen molecules, on the decomposition of hydrazine. It is shown that the principal channel for the decomposition of N/sub 2/H/sub 4/ is the reaction N + N/sub 2/H/sub 4/ ..-->.. products. The interaction constant is determined.
- Research Organization:
- Mendeleev Institute of Chemical Technology, Moscow
- OSTI ID:
- 5030739
- Journal Information:
- High Energy Chem. (Engl. Transl.); (United States), Vol. 20:1
- Country of Publication:
- United States
- Language:
- English
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ABSOLUTE INTEGRAL CROSS SECTIONS AND PRODUCT BRANCHING RATIOS FOR THE VIBRATIONALLY SELECTED ION-MOLECULE REACTIONS: N{sub 2}{sup +}(X {sup 2}{Sigma}{sub g}{sup +}; v {sup +} = 0-2) + CH{sub 4}
Dependence of electron-impact dissociative excitation cross sections on the initial vibrational quantum number in H[sub 2] and D[sub 2] molecules: [ital X] [sup 1][Sigma][sub g][sup +][r arrow]B [sup 1][Sigma][sub u][sup +] and [ital X] [sup 1][Sigma][sub g][sup +][r arrow]C [sup 1][Pi][sub u] transitions
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· High Energy Chem. (Engl. Transl.); (United States)
·
OSTI ID:5030739
+2 more
ABSOLUTE INTEGRAL CROSS SECTIONS AND PRODUCT BRANCHING RATIOS FOR THE VIBRATIONALLY SELECTED ION-MOLECULE REACTIONS: N{sub 2}{sup +}(X {sup 2}{Sigma}{sub g}{sup +}; v {sup +} = 0-2) + CH{sub 4}
Journal Article
·
Mon May 20 00:00:00 EDT 2013
· Astrophysical Journal
·
OSTI ID:5030739
Dependence of electron-impact dissociative excitation cross sections on the initial vibrational quantum number in H[sub 2] and D[sub 2] molecules: [ital X] [sup 1][Sigma][sub g][sup +][r arrow]B [sup 1][Sigma][sub u][sup +] and [ital X] [sup 1][Sigma][sub g][sup +][r arrow]C [sup 1][Pi][sub u] transitions
Journal Article
·
Thu Dec 01 00:00:00 EST 1994
· Physical Review A; (United States)
·
OSTI ID:5030739
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HYDRAZINE
AFTERGLOW
DISSOCIATION
NITROGEN
EXCITED STATES
ATOMS
CHEMICAL REACTION KINETICS
CRYOGENICS
DECOMPOSITION
EXCITATION
GAS DISCHARGE TUBES
GLOW DISCHARGES
LUMINOSITY
RECOMBINATION
CHEMICAL REACTIONS
ELECTRIC DISCHARGES
ELECTRON TUBES
ELEMENTS
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
KINETICS
NITROGEN COMPOUNDS
NONMETALS
OPTICAL PROPERTIES
PHYSICAL PROPERTIES
REACTION KINETICS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HYDRAZINE
AFTERGLOW
DISSOCIATION
NITROGEN
EXCITED STATES
ATOMS
CHEMICAL REACTION KINETICS
CRYOGENICS
DECOMPOSITION
EXCITATION
GAS DISCHARGE TUBES
GLOW DISCHARGES
LUMINOSITY
RECOMBINATION
CHEMICAL REACTIONS
ELECTRIC DISCHARGES
ELECTRON TUBES
ELEMENTS
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
KINETICS
NITROGEN COMPOUNDS
NONMETALS
OPTICAL PROPERTIES
PHYSICAL PROPERTIES
REACTION KINETICS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)