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Title: Production of negative alkali and alkaline earth ions

Authors:
Publication Date:
Research Org.:
Heidelberg Univ. (F.R. Germany)
OSTI Identifier:
4931733
Report Number(s):
ORNL-tr-2720
NSA Number:
NSA-28-028172
Resource Type:
Technical Report
Resource Relation:
Other Information: TIC (Technical Information Center); Related Information: Translation of a German thesis
Country of Publication:
Germany
Language:
English
Subject:
N60100* -Physics (Atomic & Molecular)-Atomic, Electron, Ion & Molecular Beams & Reactions; BERYLLIUM HYDRIDES; ION BEAMS; BERYLLIUM IONS; HYDROGEN IONS 1 MINUS; ION SOURCES; BEAM CURRENTS; LITHIUM HYDRIDES; LITHIUM IONS; MAGNESIUM HYDRIDES; MAGNESIUM IONS; POTASSIUM HYDRIDES; SODIUM HYDRIDES; CATIONS; PENNING DISCHARGES; PLASMA

Citation Formats

Heinicke, Erhard. Production of negative alkali and alkaline earth ions. Germany: N. p., 1967. Web. doi:10.2172/4931733.
Heinicke, Erhard. Production of negative alkali and alkaline earth ions. Germany. doi:10.2172/4931733.
Heinicke, Erhard. Sun . "Production of negative alkali and alkaline earth ions". Germany. doi:10.2172/4931733. https://www.osti.gov/servlets/purl/4931733.
@article{osti_4931733,
title = {Production of negative alkali and alkaline earth ions},
author = {Heinicke, Erhard},
abstractNote = {},
doi = {10.2172/4931733},
journal = {},
number = ,
volume = ,
place = {Germany},
year = {Sun Dec 31 00:00:00 EST 1967},
month = {Sun Dec 31 00:00:00 EST 1967}
}

Technical Report:

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  • Measurements have been made of the total backscattered D/sup -/ and H/sup -/ yields from thick, clean targets of Cs, Rb, K, Na, and Li, bombarded with H/sub 2//sup +/, H/sub 3//sup +/, D/sub 2//sup +/, and D/sub 3//sup +/ with incident energies from 0.15 to 4.0 keV/nucleus. All of the measurements were made at background pressures less than 10/sup -9/ Torr and the alkali-metal targets were evaporated onto a cold substrate (T = 77K) in situ to assure thick, uncontaminated targets. Measurements of the H/sup -/ yield from various transition metal targets with thin coverages of alkali-metals have alsomore » been made as a function of the surface work function. The negative ion yields are discussed in terms of the probabilities of reflection of the incident particles, of formation of the negative ion at the surface and of the survival of the negative ion leaving the surface. For each thick alkali-metal target, the negative ion yield measurements have been used in a least squares fit to determine two parameters in a theoretically derived expression for the negative ion yield. The parameters obtained from a thick Na target have been used to calculate the yield from a Cu target with thin coverage of Na (such that the surface work function is equal to thick Na).« less
  • The H/sub 2/O-CHCl/sub 3/-H/sub 2/O liquid membrane system was characterized with respect to the effect on cation (K/sup +/) transport rate of salt concentration and anion type. A bulk liquid membrane cell was used. A mathematical model for cation flux is being developed for several cations, several macrocycles, and mixtures of two or three cations. Eu/sup 3 +/ was not transported by 18-crown-6, but its reduced from Eu/sup 2 +/ was. Cation transport properties of calixarenes are also being investigated. Emulsion membrane systems were studied as a way of increasing the cation transport. Pb/sup 2 +/ was found to bemore » transported by dicyclohexano-18-crown-6 through the liquid membrane. Transport rates of metal cation nitrates were measured in a water-toluene-water emulsion membrane system. 14 figures, 7 tables. (DLC)« less
  • Results of a study of the physical properties of molten boron oxide and binary alkali, alkaline earth. amd rare earth borates with special emphasis on rubidium and cesium borates are presented. Rubidium and cesium borates were found to exhibit the same type of boron anomaly as was reported by previous authors in case of other alkali borates. From the breaks, as observed in the case of viscosity and density measurements, and substantiated in part by electrical resistivity and to a certain extent surface tension measurements, it was inferred that definite changes in structural configuration are taking place under those conditions.more » Density determinations of the rare earth borates point to the fact that necdymium and yttrium act as glass network formers. The rare earth oxides, so far studied, were found to lower the viscosity of the parent boron oxide glass at temperatures lower than 620 tained C. An inversion point was found at 620 to 670 tained C, above which all the rare earth oxides increase the viscosity of the base glass. (auth)« less
  • The overall objective of this project is to study the use of liquid membrane systems employing macrocyclic ligand carriers in making separations among metal cations. During the third year of the project, work continued in the development of a mathematical model to describe cation transport. The model was originally developed to describe the relationship between cation transport rate (J/sub M/) and the cation-macrocycle stability constant (K). The model was tested by determining the rates of transport of alkali and alkaline earth cations through chloroform membranes containing carrier ligands where the stability constants for their reaction with cations in methanol weremore » known. From the results, it is clear that the model correctly describes the dependence of J/sub M/ on log K. The model also correctly describes the effect of cation concentration and carrier concentration on cation transport rates, as detailed in the previous progress report. During the third year of the project, the transport model was expanded so as to apply to competitive transport of cations from mixtures of two cations in the source aqueous phase. Data were collected under these conditions and the ability of the model to predict the flux of each cation was tested. Representative data of this type are presented along with corresponding data which were obtained when each cation was transported by the same carrier from a source phase containing only that cation. Comparison of transport rates determined under the two experimental conditions indicates that the relationship between the two sets of data is complex. To date, a few of these data involving transport from binary cation mixtures have been tested against the transport model. It was found that the model correctly predicts the cation fluxes from cation mixtures. These preliminary results indicate that the transport model can successfully predict separation factors when cation mixtures are used.« less