A MOLECULAR-ORBITAL APPROACH TO THE DEVELOPMENT OF VIBRATIONAL POTENTIAL FUNCTIONS: CO FORCE CONSTANT AND STRETCH-STRETCH INTERACTION CONSTANTS FOR METAL HEXACARBONYLS

doi:https://doi.org/10.1016/0022-2852(62)90220-5

Title: A MOLECULAR-ORBITAL APPROACH TO THE DEVELOPMENT OF VIBRATIONAL POTENTIAL FUNCTIONS: CO FORCE CONSTANT AND STRETCH-STRETCH INTERACTION CONSTANTS FOR METAL HEXACARBONYLS

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Abstract

From a consideration of the molecular-orbitals of carbon monoxide it is shown that the observed CO force constants of the metal carbonyls indicate considerable metalcarbon pi bonding. The seven stretch-stretch interaction constants of the meral hexacarbonyls of octahedral symmetry are reduced to three constants using a molecularorbital development. The results are the same as those derived using a valence-bond approach. (auth)

Authors:: Jones, L H

Publication Date:: 1962-01-01

Research Org.:: Los Alamos Scientific Lab., N. Mex.

OSTI Identifier:: 4769460

Report Number(s):: TID-14800; LADC-5216

NSA Number:: NSA-17-005108

Resource Type:: Journal Article

Journal Name:: J. Mol. Spectr.

Additional Journal Information:: Journal Volume: Vol: 9; Other Information: TID-14800; LADC-5216. Orig. Receipt Date: 31-DEC-63

Country of Publication:: United States

Language:: English

Subject:: PHYSICS; BONDING; CARBON MONOXIDE; CARBONYLS; INTERACTIONS; METALS; MOLECULES; ORBITS; VALENCE; VIBRATIONS

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                    Jones, L H. A MOLECULAR-ORBITAL APPROACH TO THE DEVELOPMENT OF VIBRATIONAL POTENTIAL FUNCTIONS: CO FORCE CONSTANT AND STRETCH-STRETCH INTERACTION CONSTANTS FOR METAL HEXACARBONYLS.  United States: N. p., 1962. 
        Web.  doi:10.1016/0022-2852(62)90220-5.

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                    Jones, L H. A MOLECULAR-ORBITAL APPROACH TO THE DEVELOPMENT OF VIBRATIONAL POTENTIAL FUNCTIONS: CO FORCE CONSTANT AND STRETCH-STRETCH INTERACTION CONSTANTS FOR METAL HEXACARBONYLS.  United States.  https://doi.org/10.1016/0022-2852(62)90220-5

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                    Jones, L H. Mon .  
        "A MOLECULAR-ORBITAL APPROACH TO THE DEVELOPMENT OF VIBRATIONAL POTENTIAL FUNCTIONS: CO FORCE CONSTANT AND STRETCH-STRETCH INTERACTION CONSTANTS FOR METAL HEXACARBONYLS".  United States.  https://doi.org/10.1016/0022-2852(62)90220-5.

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@article{osti_4769460,

  title        = {A MOLECULAR-ORBITAL APPROACH TO THE DEVELOPMENT OF VIBRATIONAL POTENTIAL FUNCTIONS: CO FORCE CONSTANT AND STRETCH-STRETCH INTERACTION CONSTANTS FOR METAL HEXACARBONYLS},

  author       = {Jones, L H},

  abstractNote = {From a consideration of the molecular-orbitals of carbon monoxide it is shown that the observed CO force constants of the metal carbonyls indicate considerable metalcarbon pi bonding. The seven stretch-stretch interaction constants of the meral hexacarbonyls of octahedral symmetry are reduced to three constants using a molecularorbital development. The results are the same as those derived using a valence-bond approach. (auth)},

  doi          = {10.1016/0022-2852(62)90220-5},

  url          = {https://www.osti.gov/biblio/4769460},
  journal      = {J. Mol. Spectr.},
number       = ,

  volume       = Vol: 9,

  place        = {United States},

  year         = {1962},

  month        = {1}

}

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