The kinetic ion mobility mass spectrometer: Measurements of ion-molecule reaction rate constants at atmospheric pressure
Journal Article
·
· Journal of Physical Chemistry
- Montana State Univ., Bozeman, MT (United States)
This paper discusses how the kinetic ion mobility mass spectrometer is used to measure the rate constants of ion-molecule reactions in an atmospheric pressure buffer gas. One operational mode of the instrument avoids measurement errors associated with aperture sampling of a high-pressure ionized gas. This instrument is used to study the S{sub N}2 nucleophilic displacement reactions of chloride anions with a series of alkyl bromides in nitrogen. 40 refs., 13 figs., 2 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 468077
- Journal Information:
- Journal of Physical Chemistry, Vol. 96, Issue 16; Other Information: PBD: 6 Aug 1992
- Country of Publication:
- United States
- Language:
- English
Similar Records
Atmospheric and reduced pressure helium microwave-induced plasmas as ion sources for mass spectrometry
Probing trapped ion energies in a quadrupole ion trap mass spectrometer
The FUNPET—a New Hybrid Ion Funnel-Ion Carpet Atmospheric Pressure Interface for the Simultaneous Transmission of a Broad Mass Range
Miscellaneous
·
Sun Jan 01 00:00:00 EST 1989
·
OSTI ID:468077
Probing trapped ion energies in a quadrupole ion trap mass spectrometer
Miscellaneous
·
Wed Jan 01 00:00:00 EST 1992
·
OSTI ID:468077
The FUNPET—a New Hybrid Ion Funnel-Ion Carpet Atmospheric Pressure Interface for the Simultaneous Transmission of a Broad Mass Range
Journal Article
·
Thu Nov 15 00:00:00 EST 2018
· Journal of the American Society for Mass Spectrometry
·
OSTI ID:468077