Phosphine nickel complex as catalyst in reactions of organic bromides RBr with {alpha},{beta}-unsaturated ketones, nitriles, and esters. Conjugate addition of R group and H atom across the C=C bond
Journal Article
·
· Russian Journal of General Chemistry
OSTI ID:457725
Reactions of organic bromides, particularly of secondary and tertiary alkyl bromides, with {alpha},{beta}-unsaturated carbonyl compounds and acrylonitrile in the presence of the catalytic system nickel complex-zinc. The products correspond to the conjugate addition of the organic moiety of the bromide and a hydrogen atom across the C=C double bond of the unsaturated substrate. 9 refs., 1 tab.
- OSTI ID:
- 457725
- Journal Information:
- Russian Journal of General Chemistry, Vol. 65, Issue 3; Other Information: PBD: 10 Sep 1995; TN: Translated from Zhurnal Obshchei Khimii; 65: No. 3, 501-503(Mar 1995)
- Country of Publication:
- United States
- Language:
- English
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