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Title: Directing effects in a fullerene epoxide addition. Formation and structural characterization of ({eta}{sup 2}-C{sub 60}O)Ir(CO)Cl(P(C{sub 6}H{sub 5}){sub 3}){sub 2}

Abstract

The authors report on the reaction of Ir(CO)Cl(PPh{sub 3}){sub 2}, 1, and C{sub 60}O. The focus here was to investigate the ability of O to direct addition of an iridium compound. The products were separated by liquid chromatography. X-ray diffraction and NMR was used in the characterization of the products. Two epoxide products were produced.

Authors:
; ; ; ;  [1]
  1. Univ. of California, Davis, CA (United States)
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
450851
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorganic Chemistry; Journal Volume: 33; Journal Issue: 10; Other Information: PBD: 11 May 1994
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; IRIDIUM COMPLEXES; CHEMICAL REACTIONS; FULLERENES; EPOXIDES; ABSORPTION SPECTROSCOPY

Citation Formats

Balch, A.L., Costa, D.A., Lee, J.W., Noll, B.C., and Olmstead, M.M. Directing effects in a fullerene epoxide addition. Formation and structural characterization of ({eta}{sup 2}-C{sub 60}O)Ir(CO)Cl(P(C{sub 6}H{sub 5}){sub 3}){sub 2}. United States: N. p., 1994. Web. doi:10.1021/ic00088a002.
Balch, A.L., Costa, D.A., Lee, J.W., Noll, B.C., & Olmstead, M.M. Directing effects in a fullerene epoxide addition. Formation and structural characterization of ({eta}{sup 2}-C{sub 60}O)Ir(CO)Cl(P(C{sub 6}H{sub 5}){sub 3}){sub 2}. United States. doi:10.1021/ic00088a002.
Balch, A.L., Costa, D.A., Lee, J.W., Noll, B.C., and Olmstead, M.M. Wed . "Directing effects in a fullerene epoxide addition. Formation and structural characterization of ({eta}{sup 2}-C{sub 60}O)Ir(CO)Cl(P(C{sub 6}H{sub 5}){sub 3}){sub 2}". United States. doi:10.1021/ic00088a002.
@article{osti_450851,
title = {Directing effects in a fullerene epoxide addition. Formation and structural characterization of ({eta}{sup 2}-C{sub 60}O)Ir(CO)Cl(P(C{sub 6}H{sub 5}){sub 3}){sub 2}},
author = {Balch, A.L. and Costa, D.A. and Lee, J.W. and Noll, B.C. and Olmstead, M.M.},
abstractNote = {The authors report on the reaction of Ir(CO)Cl(PPh{sub 3}){sub 2}, 1, and C{sub 60}O. The focus here was to investigate the ability of O to direct addition of an iridium compound. The products were separated by liquid chromatography. X-ray diffraction and NMR was used in the characterization of the products. Two epoxide products were produced.},
doi = {10.1021/ic00088a002},
journal = {Inorganic Chemistry},
number = 10,
volume = 33,
place = {United States},
year = {Wed May 11 00:00:00 EDT 1994},
month = {Wed May 11 00:00:00 EDT 1994}
}