Spectrophotometric Evidence for the Existence of UCl$sub 5$ as the Double Compound UCl$sub 6$.UCl$sub 4$
Technical Report
·
OSTI ID:4431111
- Research Organization:
- Originating Research Org. not identified
- NSA Number:
- NSA-02-001035
- OSTI ID:
- 4431111
- Report Number(s):
- AECD-2443; (Y-187)
- Resource Relation:
- Other Information: Proposed for publication in J. Amer. Chem. Soc.(See also MDDC-1094; Decl. Jan. 19, 1949. Orig. Receipt Date: 30-JUN-49
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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SPECTROPHOTOMETRIC EVIDENCE FOR THE EXISTENCE OF UCl$sub 5$ AS A DOUBLE COMPOUND OF UCl$sub 6$ AND UCl$sub 4$
Structural Changes in Molten Salt Fuel and/or Waste Stream Compounds Cs2UCl6 and Cs2UO2Cl4 from Room Temperature to Melting and Related Materials [Slides]
f-Element/crown ether complexes. 10. Oxidation of UCl/sub 4/ to (UO/sub 2/Cl/sub 4/)/sup 2/minus// in the presence of crown ethers: Structural characterization of crown ether complexed ammonium ions ((NH/sub 4/)(15-crown-5)/sub 2/)/sub 2/(UO/sub 2/Cl/sub 4/) /times/2CH/sub 3/CN, ((NH/sub 4/)(benzo-15-crown-5)/sub 2/)/sub 2/(UCl/sub 6/) /times/ 4CH/sub 3/CN, and ((NH/sub 4/)(dibenzo-18-crown-6))/sub 2/(UO/sub 2/Cl/sub 4/) /times/ 2CH/sub 3/CN and synthesis of (Na(12-crown-4)/sub 2/)/sub 2/(UO/sub 2/Cl/sub 4/) /times/ 2OHMe and (UO/sub 2/Cl/sub 2/(OH/sub 2/)/sub 3/) /times/ 18-crown-6 /times/ H/sub 2/O /times/ OHMe
Technical Report
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Sun Dec 01 00:00:00 EST 1946
·
OSTI ID:4431111
Structural Changes in Molten Salt Fuel and/or Waste Stream Compounds Cs2UCl6 and Cs2UO2Cl4 from Room Temperature to Melting and Related Materials [Slides]
Technical Report
·
Wed Aug 17 00:00:00 EDT 2022
·
OSTI ID:4431111
f-Element/crown ether complexes. 10. Oxidation of UCl/sub 4/ to (UO/sub 2/Cl/sub 4/)/sup 2/minus// in the presence of crown ethers: Structural characterization of crown ether complexed ammonium ions ((NH/sub 4/)(15-crown-5)/sub 2/)/sub 2/(UO/sub 2/Cl/sub 4/) /times/2CH/sub 3/CN, ((NH/sub 4/)(benzo-15-crown-5)/sub 2/)/sub 2/(UCl/sub 6/) /times/ 4CH/sub 3/CN, and ((NH/sub 4/)(dibenzo-18-crown-6))/sub 2/(UO/sub 2/Cl/sub 4/) /times/ 2CH/sub 3/CN and synthesis of (Na(12-crown-4)/sub 2/)/sub 2/(UO/sub 2/Cl/sub 4/) /times/ 2OHMe and (UO/sub 2/Cl/sub 2/(OH/sub 2/)/sub 3/) /times/ 18-crown-6 /times/ H/sub 2/O /times/ OHMe
Journal Article
·
Wed Dec 30 00:00:00 EST 1987
· Inorg. Chem.; (United States)
·
OSTI ID:4431111