Iridium(III) salts as homogeneous metal catalysts for hydrogen isotope exchange in organic compounds: a comparison with heterogeneous iridium for the deuteriation of alkylbenzenes
Journal Article
·
· J. Chem. Soc., Chem. Commun., no. 19, pp. 749-750
Hydrogen exchange between organic compounds and heawy water is homogeneously catalysed by sodium chloroiridite; resuits for alkylbenzenes are compared with those from heterogeneous catalysis by iridium metal and are interpreted in terms of the role of pi -complex intermediates. (auth)
- Research Organization:
- Univ. of New South Wales, Kensington, Australia
- NSA Number:
- NSA-29-002515
- OSTI ID:
- 4408519
- Journal Information:
- J. Chem. Soc., Chem. Commun., no. 19, pp. 749-750, Other Information: Orig. Receipt Date: 30-JUN-74; Bib. Info. Source: UK (United Kingdom (sent to DOE from))
- Country of Publication:
- United Kingdom
- Language:
- English
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