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Title: Time-resolved EPR study on the photochemical reactions of benzil

Abstract

TREPR and optical studies on the photochemical reactions of benzil in 2-propanol and benzene-TEA conclude that emissive signals are due to the reaction from T{sub n} produced via the S{sub n} pointing right T{sub n} intersystem crossing process. The free-pair radical-pair mechanism can account for the main features of the slow rise component of the chemically induced dynamic electron polarization signal of the ketyl radical in 2-propanol. 27 refs., 10 figs., 2 tabs.

Authors:
; ;  [1]
  1. Kyoto Univ. (Japan)
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
440661
Resource Type:
Journal Article
Journal Name:
Journal of Physical Chemistry
Additional Journal Information:
Journal Volume: 96; Journal Issue: 8; Other Information: PBD: 16 Apr 1992
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; 36 MATERIALS SCIENCE; 66 PHYSICS; CARBONYLS; ELECTRON SPIN RESONANCE; PHOTOCHEMICAL REACTIONS; BENZOYL RADICALS; PROPANOLS; BENZENE; PHOTOLYSIS

Citation Formats

Mukai, Masahiro, Yamnauchi, Seigo, and Hirota, Noboru. Time-resolved EPR study on the photochemical reactions of benzil. United States: N. p., 1992. Web. doi:10.1021/j100187a025.
Mukai, Masahiro, Yamnauchi, Seigo, & Hirota, Noboru. Time-resolved EPR study on the photochemical reactions of benzil. United States. https://doi.org/10.1021/j100187a025
Mukai, Masahiro, Yamnauchi, Seigo, and Hirota, Noboru. 1992. "Time-resolved EPR study on the photochemical reactions of benzil". United States. https://doi.org/10.1021/j100187a025.
@article{osti_440661,
title = {Time-resolved EPR study on the photochemical reactions of benzil},
author = {Mukai, Masahiro and Yamnauchi, Seigo and Hirota, Noboru},
abstractNote = {TREPR and optical studies on the photochemical reactions of benzil in 2-propanol and benzene-TEA conclude that emissive signals are due to the reaction from T{sub n} produced via the S{sub n} pointing right T{sub n} intersystem crossing process. The free-pair radical-pair mechanism can account for the main features of the slow rise component of the chemically induced dynamic electron polarization signal of the ketyl radical in 2-propanol. 27 refs., 10 figs., 2 tabs.},
doi = {10.1021/j100187a025},
url = {https://www.osti.gov/biblio/440661}, journal = {Journal of Physical Chemistry},
number = 8,
volume = 96,
place = {United States},
year = {Thu Apr 16 00:00:00 EDT 1992},
month = {Thu Apr 16 00:00:00 EDT 1992}
}