Time-resolved EPR study on the photochemical reactions of benzil
Abstract
TREPR and optical studies on the photochemical reactions of benzil in 2-propanol and benzene-TEA conclude that emissive signals are due to the reaction from T{sub n} produced via the S{sub n} pointing right T{sub n} intersystem crossing process. The free-pair radical-pair mechanism can account for the main features of the slow rise component of the chemically induced dynamic electron polarization signal of the ketyl radical in 2-propanol. 27 refs., 10 figs., 2 tabs.
- Authors:
-
- Kyoto Univ. (Japan)
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 440661
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Physical Chemistry
- Additional Journal Information:
- Journal Volume: 96; Journal Issue: 8; Other Information: PBD: 16 Apr 1992
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 40 CHEMISTRY; 36 MATERIALS SCIENCE; 66 PHYSICS; CARBONYLS; ELECTRON SPIN RESONANCE; PHOTOCHEMICAL REACTIONS; BENZOYL RADICALS; PROPANOLS; BENZENE; PHOTOLYSIS
Citation Formats
Mukai, Masahiro, Yamnauchi, Seigo, and Hirota, Noboru. Time-resolved EPR study on the photochemical reactions of benzil. United States: N. p., 1992.
Web. doi:10.1021/j100187a025.
Mukai, Masahiro, Yamnauchi, Seigo, & Hirota, Noboru. Time-resolved EPR study on the photochemical reactions of benzil. United States. https://doi.org/10.1021/j100187a025
Mukai, Masahiro, Yamnauchi, Seigo, and Hirota, Noboru. 1992.
"Time-resolved EPR study on the photochemical reactions of benzil". United States. https://doi.org/10.1021/j100187a025.
@article{osti_440661,
title = {Time-resolved EPR study on the photochemical reactions of benzil},
author = {Mukai, Masahiro and Yamnauchi, Seigo and Hirota, Noboru},
abstractNote = {TREPR and optical studies on the photochemical reactions of benzil in 2-propanol and benzene-TEA conclude that emissive signals are due to the reaction from T{sub n} produced via the S{sub n} pointing right T{sub n} intersystem crossing process. The free-pair radical-pair mechanism can account for the main features of the slow rise component of the chemically induced dynamic electron polarization signal of the ketyl radical in 2-propanol. 27 refs., 10 figs., 2 tabs.},
doi = {10.1021/j100187a025},
url = {https://www.osti.gov/biblio/440661},
journal = {Journal of Physical Chemistry},
number = 8,
volume = 96,
place = {United States},
year = {Thu Apr 16 00:00:00 EDT 1992},
month = {Thu Apr 16 00:00:00 EDT 1992}
}
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