Reaction of ammonium pertechnetate with anhydrous hydrogen fluoride. Vibrational spectra of pertechnetyl fluoride
Ammonium pertechnetate dissolves slightly in anhydrous hydrogen fluoride to give solutions of pertechnetyl fluoride. Raman spectra of the solutions as well as infrared and Raman spectra of the pure compound indicate that TcO/sub 3/F has symmetry C/sub 3v/ with the following assignments (in cm/sup -1): (a/sub 1/) 696, 962, 317; (e) 951, 347, 231. A comparison with other MO/sub 3/X compounds indicates a necessity to reverse some of the original assignments. (auth)
- Research Organization:
- Soreq Nuclear Research Center, Yavne, Israel
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-29-015423
- OSTI ID:
- 4363432
- Journal Information:
- Inorganic Chemistry, Vol. 13, Issue 2; Other Information: Orig. Receipt Date: 30-JUN-74; ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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