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Title: The Validity of Onsager's Reciprocal Relations in Ternary Diffusion

Abstract

The validity of Onsager's reciprocal relations in ternary diffusion was verified by transformation of the thermodynamic expressions into concentration gradient form while assuming no volume flow. A table containing several systems is presented, and the estimated error is assigned solely to uncertainties in diffusion coefficients based on concentration gradients; however, some error undoubtedly exists in the activity coefficients since they were estimated in the absence of experimental data.

Authors:
Publication Date:
Research Org.:
Univ. of California, Livermore
Sponsoring Org.:
USDOE
OSTI Identifier:
4329340
NSA Number:
NSA-12-012245
Resource Type:
Journal Article
Journal Name:
Journal of Physical Chemistry
Additional Journal Information:
Journal Volume: 62; Journal Issue: 6; Other Information: Orig. Receipt Date: 31-DEC-58; Journal ID: ISSN 0022-3654
Country of Publication:
Country unknown/Code not available
Language:
English
Subject:
CHEMISTRY; DIFFUSION; EQUATIONS; ERRORS; MATHEMATICS; QUANTITY RATIO; TABLES; THERMODYNAMICS

Citation Formats

Miller, Donald G. The Validity of Onsager's Reciprocal Relations in Ternary Diffusion. Country unknown/Code not available: N. p., 1958. Web. doi:10.1021/j150564a039.
Miller, Donald G. The Validity of Onsager's Reciprocal Relations in Ternary Diffusion. Country unknown/Code not available. https://doi.org/10.1021/j150564a039
Miller, Donald G. 1958. "The Validity of Onsager's Reciprocal Relations in Ternary Diffusion". Country unknown/Code not available. https://doi.org/10.1021/j150564a039.
@article{osti_4329340,
title = {The Validity of Onsager's Reciprocal Relations in Ternary Diffusion},
author = {Miller, Donald G.},
abstractNote = {The validity of Onsager's reciprocal relations in ternary diffusion was verified by transformation of the thermodynamic expressions into concentration gradient form while assuming no volume flow. A table containing several systems is presented, and the estimated error is assigned solely to uncertainties in diffusion coefficients based on concentration gradients; however, some error undoubtedly exists in the activity coefficients since they were estimated in the absence of experimental data.},
doi = {10.1021/j150564a039},
url = {https://www.osti.gov/biblio/4329340}, journal = {Journal of Physical Chemistry},
issn = {0022-3654},
number = 6,
volume = 62,
place = {Country unknown/Code not available},
year = {Sun Jun 01 00:00:00 EDT 1958},
month = {Sun Jun 01 00:00:00 EDT 1958}
}