Bench-Scale Development of Fluidized-Bed Spray-Dried Sorbents
Abstract
Successful development of regenerable mixed-metal oxide sorbents for removal of reduced sulfur species (such as H{sub 2}S and COS) from coal-derived fuel gas streams at high=temperature, high-pressure (HTHP) conditions is a key to commercialization of the integrated-gasification-combined-cycle (IGCC) power systems. Among the various available coal-to-electricity pathways, IGCC power plants have the most potential with high thermal efficiency, simple system configuration, low emissions of SO{sub 2}, NO{sub x} and other contaminants, modular design, and low capital cost. Due to these advantages, the power plants of the 21st century are projected to utilize IGCC technology worldwide. Sorbents developed for sulfur removal are primarily zinc oxide-based inorganic materials, because of their ability to reduce fuel gas sulfur level to a few parts-per-million (ppm). This project extends the prior work on the development of fluidizable zinc titanate particles using a spray-drying technique to impart high reactivity and attrition resistance. Specific objectives are to develop highly reactive and attrition-resistant zinc titanate sorbents in 40- to 150-{mu}m particle size range for transport reactor applications using semicommercial- to full commercial-scale spray dryers, to transfer sorbent production technology to private sector, and to provide technical support for Sierra Pacific`s Clean Coal Technology Demonstration plant and METC`s hot-gas desulfurizationmore »
- Authors:
-
- Research Triangle Inst., Research Triangle Park, NC (United States)
- Publication Date:
- Research Org.:
- USDOE Morgantown Energy Technology Center (METC), WV (United States)
- Sponsoring Org.:
- USDOE Assistant Secretary for Fossil Energy, Washington, DC (United States)
- OSTI Identifier:
- 427512
- Report Number(s):
- DOE/MC/25006-97/C0722; CONF-960757-15
ON: DE97051019
- DOE Contract Number:
- AC21-88MC25006
- Resource Type:
- Technical Report
- Resource Relation:
- Conference: Advanced coal-fired power systems review meeting, Morgantown, WV (United States), 16-18 Jul 1996; Other Information: PBD: [1996]
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 01 COAL, LIGNITE, AND PEAT; COAL GAS; DESULFURIZATION; ZINC COMPOUNDS; SORPTIVE PROPERTIES; TITANATES; HOT GAS CLEANUP; ADSORBENTS; BENCH-SCALE EXPERIMENTS; FLUIDIZED-BED COMBUSTION; COMBINED-CYCLE POWER PLANTS; SPRAY DRYING; PARTICLE SIZE; ADSORPTION; HYDROGEN SULFIDES; EXPERIMENTAL DATA; SULFUR DIOXIDE; SULFIDATION; SORBENT RECOVERY SYSTEMS
Citation Formats
Gupta, R P, Turk, B S, and Gangwal, S K. Bench-Scale Development of Fluidized-Bed Spray-Dried Sorbents. United States: N. p., 1996.
Web. doi:10.2172/427512.
Gupta, R P, Turk, B S, & Gangwal, S K. Bench-Scale Development of Fluidized-Bed Spray-Dried Sorbents. United States. https://doi.org/10.2172/427512
Gupta, R P, Turk, B S, and Gangwal, S K. 1996.
"Bench-Scale Development of Fluidized-Bed Spray-Dried Sorbents". United States. https://doi.org/10.2172/427512. https://www.osti.gov/servlets/purl/427512.
@article{osti_427512,
title = {Bench-Scale Development of Fluidized-Bed Spray-Dried Sorbents},
author = {Gupta, R P and Turk, B S and Gangwal, S K},
abstractNote = {Successful development of regenerable mixed-metal oxide sorbents for removal of reduced sulfur species (such as H{sub 2}S and COS) from coal-derived fuel gas streams at high=temperature, high-pressure (HTHP) conditions is a key to commercialization of the integrated-gasification-combined-cycle (IGCC) power systems. Among the various available coal-to-electricity pathways, IGCC power plants have the most potential with high thermal efficiency, simple system configuration, low emissions of SO{sub 2}, NO{sub x} and other contaminants, modular design, and low capital cost. Due to these advantages, the power plants of the 21st century are projected to utilize IGCC technology worldwide. Sorbents developed for sulfur removal are primarily zinc oxide-based inorganic materials, because of their ability to reduce fuel gas sulfur level to a few parts-per-million (ppm). This project extends the prior work on the development of fluidizable zinc titanate particles using a spray-drying technique to impart high reactivity and attrition resistance. Specific objectives are to develop highly reactive and attrition-resistant zinc titanate sorbents in 40- to 150-{mu}m particle size range for transport reactor applications using semicommercial- to full commercial-scale spray dryers, to transfer sorbent production technology to private sector, and to provide technical support for Sierra Pacific`s Clean Coal Technology Demonstration plant and METC`s hot-gas desulfurization process development unit (PDU), both employing a transport reactor system.},
doi = {10.2172/427512},
url = {https://www.osti.gov/biblio/427512},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 31 00:00:00 EST 1996},
month = {Tue Dec 31 00:00:00 EST 1996}
}