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Title: ELECTRONIC STRUCTURE OF NEPTUNIUM HEXAFLUORIDE

Abstract

An analysis of NpF/sub 6/ structure based on ligand field theory is offered. The symmetries GAMMA /sub 7u/, GAMMA /sub 8u/, and GAMMA /sub 7u/ are assigned to energy levels at 0, 7420, and 9290 cm/sup -1/ respectively. The sign of g' is given to be negative, and levels are predicted at 23,220, and 28,000 cm/sup -1/ having the symmetries GAMMA /sub 8u/ and GAMMA /sub 6u/, all of which agrees nicely with experimental data. (T.R.H.)

Authors:
;
Publication Date:
Research Org.:
Harvard Univ., Cambridge, Mass.; Argonne National Lab., Lemont, Ill.
Sponsoring Org.:
USDOE
OSTI Identifier:
4273994
NSA Number:
NSA-13-009746
Resource Type:
Journal Article
Journal Name:
Journal of Chemical Physics (U.S.)
Additional Journal Information:
Journal Volume: Vol: 30; Other Information: Orig. Receipt Date: 31-DEC-59
Country of Publication:
Country unknown/Code not available
Language:
English
Subject:
CHEMISTRY; CONFIGURATION; ELECTRONS; NEPTUNIUM FLUORIDES

Citation Formats

Goodman, G.L., and Fred, M. ELECTRONIC STRUCTURE OF NEPTUNIUM HEXAFLUORIDE. Country unknown/Code not available: N. p., 1959. Web. doi:10.1063/1.1730060.
Goodman, G.L., & Fred, M. ELECTRONIC STRUCTURE OF NEPTUNIUM HEXAFLUORIDE. Country unknown/Code not available. doi:10.1063/1.1730060.
Goodman, G.L., and Fred, M. Sun . "ELECTRONIC STRUCTURE OF NEPTUNIUM HEXAFLUORIDE". Country unknown/Code not available. doi:10.1063/1.1730060.
@article{osti_4273994,
title = {ELECTRONIC STRUCTURE OF NEPTUNIUM HEXAFLUORIDE},
author = {Goodman, G.L. and Fred, M.},
abstractNote = {An analysis of NpF/sub 6/ structure based on ligand field theory is offered. The symmetries GAMMA /sub 7u/, GAMMA /sub 8u/, and GAMMA /sub 7u/ are assigned to energy levels at 0, 7420, and 9290 cm/sup -1/ respectively. The sign of g' is given to be negative, and levels are predicted at 23,220, and 28,000 cm/sup -1/ having the symmetries GAMMA /sub 8u/ and GAMMA /sub 6u/, all of which agrees nicely with experimental data. (T.R.H.)},
doi = {10.1063/1.1730060},
journal = {Journal of Chemical Physics (U.S.)},
number = ,
volume = Vol: 30,
place = {Country unknown/Code not available},
year = {1959},
month = {3}
}