APPLICATION OF A HIGH-SPEED ELECTRONIC COMPUTER IN DIFFUSION KINETICS. II. DEPLETION EFFECT IN THE SPHERICAL ONE-RADICAL ONE-SOLUTE MODEL

Journal Article · Fri Apr 01 00:00:00 EST 1960 · Journal of Chemical Physics (U.S.)

DOI:https://doi.org/10.1063/1.1730871· OSTI ID:4172603

Fricke, H; Phillips, D L

Earlier computations on diffusion in the spherical one-radical one- solute model were extended by taking account of the transient dilution of the solute which occurs during the reaction. Although the drop in concentration of the solute near the center of the reaction zone may be considerable, its effect on the fraction of radicals combining with the solute is only of the order of one percent under the most unfavorable conditions likely to be encountered when the model is applied to gamma -irradiated aqueous solutions. (auth)

• Research Organization: Argonne National Lab., Lemont, Ill.
• Sponsoring Organization: USDOE
• NSA Number: NSA-14-013728
• OSTI ID: 4172603
• Journal Information: Journal of Chemical Physics (U.S.), Vol. Vol: 32; Other Information: Orig. Receipt Date: 31-DEC-60
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

CHEMISTRY
COMPUTERS
DIFFUSION
FREE RADICALS
GAMMA RADIATION
IRRADIATION
REACTION KINETICS
SOLUTIONS
USES
WATER