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Title: Hydrothermal synthesis and characterization of two- and three-dimensional solids of the oxovanadium(IV)-phosphite system. The structures of [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H]-[(VO){sub 4}(OH){sub 2}(HPO{sub 3}){sub 4}], [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}(H{sub 2}O){sub 2}], and [VO(HPO{sub 3})(H{sub 2}O)]

Abstract

Hydrothermal reaction of VCl{sub 4} with phosphorous acid H{sub 3}PO{sub 3}, in the presence of organoamines, yields oxovanadium (IV)-phosphite materials: [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H][(VO){sub 4}(OH){sub 2}-(HPO{sub 3}){sub 4}] (1), [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}-(H{sub 2}O){sub 2}] (2), and [VO(HPO{sub 3})H{sub 2}O] (3). The framework structure of 3 is presented. 32 refs., 3 figs.

Authors:
; ;  [1]
  1. Syracuse Univ., NY (United States) [and others
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
415033
Resource Type:
Journal Article
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 7; Journal Issue: 11; Other Information: PBD: Nov 1995
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; 36 MATERIALS SCIENCE; VANADIUM OXIDES; STRUCTURAL CHEMICAL ANALYSIS; PHOSPHORUS OXIDES; CHEMICAL REACTION YIELD; HYDROTHERMAL SYNTHESIS; ABSORPTION SPECTROSCOPY

Citation Formats

Bonavia, G., DeBord, J., and Rose, D. Hydrothermal synthesis and characterization of two- and three-dimensional solids of the oxovanadium(IV)-phosphite system. The structures of [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H]-[(VO){sub 4}(OH){sub 2}(HPO{sub 3}){sub 4}], [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}(H{sub 2}O){sub 2}], and [VO(HPO{sub 3})(H{sub 2}O)]. United States: N. p., 1995. Web. doi:10.1021/cm00059a002.
Bonavia, G., DeBord, J., & Rose, D. Hydrothermal synthesis and characterization of two- and three-dimensional solids of the oxovanadium(IV)-phosphite system. The structures of [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H]-[(VO){sub 4}(OH){sub 2}(HPO{sub 3}){sub 4}], [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}(H{sub 2}O){sub 2}], and [VO(HPO{sub 3})(H{sub 2}O)]. United States. doi:10.1021/cm00059a002.
Bonavia, G., DeBord, J., and Rose, D. Wed . "Hydrothermal synthesis and characterization of two- and three-dimensional solids of the oxovanadium(IV)-phosphite system. The structures of [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H]-[(VO){sub 4}(OH){sub 2}(HPO{sub 3}){sub 4}], [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}(H{sub 2}O){sub 2}], and [VO(HPO{sub 3})(H{sub 2}O)]". United States. doi:10.1021/cm00059a002.
@article{osti_415033,
title = {Hydrothermal synthesis and characterization of two- and three-dimensional solids of the oxovanadium(IV)-phosphite system. The structures of [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H]-[(VO){sub 4}(OH){sub 2}(HPO{sub 3}){sub 4}], [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}(H{sub 2}O){sub 2}], and [VO(HPO{sub 3})(H{sub 2}O)]},
author = {Bonavia, G. and DeBord, J. and Rose, D.},
abstractNote = {Hydrothermal reaction of VCl{sub 4} with phosphorous acid H{sub 3}PO{sub 3}, in the presence of organoamines, yields oxovanadium (IV)-phosphite materials: [HN(Me)(CH{sub 2}CH{sub 2}){sub 2}N(Me)H][(VO){sub 4}(OH){sub 2}-(HPO{sub 3}){sub 4}] (1), [H{sub 2}N(CH{sub 2}CH{sub 2}){sub 2}NH{sub 2}][(VO){sub 3}(HPO{sub 3}){sub 4}-(H{sub 2}O){sub 2}] (2), and [VO(HPO{sub 3})H{sub 2}O] (3). The framework structure of 3 is presented. 32 refs., 3 figs.},
doi = {10.1021/cm00059a002},
journal = {Chemistry of Materials},
number = 11,
volume = 7,
place = {United States},
year = {1995},
month = {11}
}