SOME DEUTERIUM KINETIC ISOTOPE EFFECTS: IV. β-DEUTERIUM EFFECTS IN WATER SOLVOLYSIS OF ETHYL, ISOPROPYL, AND tert -BUTYL COMPOUNDS
Journal Article
·
· Canadian Journal of Chemistry
The secondary to 1000 deg F. -deuterium isotope effects were measured in the water solvolytic reaction of alkyl halides and sulfonated for primary, secondary, and tertiary species. In (k/sub H//k/sub D/) 1). This isotope effect may be associated with varying degrees of hyperconjugation or altered nonbonding intramolecular forces. The experiments make it difficult to decide which effect is most important.
- Research Organization:
- National Research Council, Ottawa
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-15-003974
- OSTI ID:
- 4138782
- Report Number(s):
- NRC-5969; 0008-4042
- Journal Information:
- Canadian Journal of Chemistry, Vol. 38, Issue 11; Other Information: Orig. Receipt Date: 31-DEC-61; ISSN 0008-4042
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
Similar Records
Secondary deuterium isotope effects in the solvolysis of cis- and trans-2-acetoxycyclohexyl-2,2,2-trifluoroethanesulfonates
n participation and secondary deuterium isotope effects in solvolysis of 1-aryl-4-methoxy-1-butyl chlorides. Are there two distinct k/sub. delta. / pathways
The Effects of Deuterium Substitution on the Rates of Organic Reactions. VI. Secondary Isotope Effects on the Solvolysis Rates of γ-Methyl Substituted t-Alkyl Chlorides
Journal Article
·
Fri Mar 05 00:00:00 EST 1976
· J. Org. Chem.; (United States)
·
OSTI ID:4138782
n participation and secondary deuterium isotope effects in solvolysis of 1-aryl-4-methoxy-1-butyl chlorides. Are there two distinct k/sub. delta. / pathways
Journal Article
·
Fri Nov 09 00:00:00 EST 1979
· J. Org. Chem.; (United States)
·
OSTI ID:4138782
+2 more
The Effects of Deuterium Substitution on the Rates of Organic Reactions. VI. Secondary Isotope Effects on the Solvolysis Rates of γ-Methyl Substituted t-Alkyl Chlorides
Journal Article
·
Sun Jan 01 00:00:00 EST 1961
· Journal of the American Chemical Society
·
OSTI ID:4138782