STUDIES ON THE SOLUBILITY OF ZIRCONIUM, THORIUM AND URANIUM PHENYLARSONATES (in Russian)
Abstract
The solubility of sexa- and tetravalent uranium, zirconium, and thorium phenylarsonates in solutions of different acidity, in the presence of phenylarsonic acid, was studied by the labeled atom method. The conditions for their most complete precipitation were established and the solubility was determined as follows: uranium(IV) phenylarsonate 3 x 10/sup -5/ M; uranium(IV) phenylarsonate 1 x 10/sup -5/ M; zirconium phenylarsonate (0.5 plus or minus 0.2) x 10/sup -5/ M; and thorium phenylarsonate 10/sup -5/ M. The logarithms of the concentration constants for the reactions of phenylarsonate formation were calculated to be equal: uranium(VI) 2.2 plus or minus 0.2; uranium(IV) 6.5 + 0.3; zirconium 11.5 plus or minus 0.3; and thorium
- Authors:
- Publication Date:
- Research Org.:
- Originating Research Org. not identified
- OSTI Identifier:
- 4115104
- NSA Number:
- NSA-15-007351
- Resource Type:
- Journal Article
- Journal Name:
- Zhur. Anal. Khim.
- Additional Journal Information:
- Journal Volume: Vol: 15; Other Information: Orig. Receipt Date: 31-DEC-61
- Country of Publication:
- Country unknown/Code not available
- Language:
- Russian
- Subject:
- CHEMISTRY; ACIDITY; ARSENIC COMPOUNDS; ARSONIC ACID; ATOMS; LABELLED COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; PHENYL RADICALS; PRECIPITATION; SOLUBILITY; SOLUTIONS; THORIUM COMPOUNDS; TRACER TECHNIQUES; URANIUM COMPOUNDS; ZIRCONIUM COMPOUNDS
Citation Formats
Mikhailov, V A. STUDIES ON THE SOLUBILITY OF ZIRCONIUM, THORIUM AND URANIUM PHENYLARSONATES. Country unknown/Code not available: N. p., 1960.
Web.
Mikhailov, V A. STUDIES ON THE SOLUBILITY OF ZIRCONIUM, THORIUM AND URANIUM PHENYLARSONATES. Country unknown/Code not available.
Mikhailov, V A. 1960.
"STUDIES ON THE SOLUBILITY OF ZIRCONIUM, THORIUM AND URANIUM PHENYLARSONATES". Country unknown/Code not available.
@article{osti_4115104,
title = {STUDIES ON THE SOLUBILITY OF ZIRCONIUM, THORIUM AND URANIUM PHENYLARSONATES},
author = {Mikhailov, V A},
abstractNote = {The solubility of sexa- and tetravalent uranium, zirconium, and thorium phenylarsonates in solutions of different acidity, in the presence of phenylarsonic acid, was studied by the labeled atom method. The conditions for their most complete precipitation were established and the solubility was determined as follows: uranium(IV) phenylarsonate 3 x 10/sup -5/ M; uranium(IV) phenylarsonate 1 x 10/sup -5/ M; zirconium phenylarsonate (0.5 plus or minus 0.2) x 10/sup -5/ M; and thorium phenylarsonate 10/sup -5/ M. The logarithms of the concentration constants for the reactions of phenylarsonate formation were calculated to be equal: uranium(VI) 2.2 plus or minus 0.2; uranium(IV) 6.5 + 0.3; zirconium 11.5 plus or minus 0.3; and thorium},
doi = {},
url = {https://www.osti.gov/biblio/4115104},
journal = {Zhur. Anal. Khim.},
number = ,
volume = Vol: 15,
place = {Country unknown/Code not available},
year = {Thu Sep 01 00:00:00 EDT 1960},
month = {Thu Sep 01 00:00:00 EDT 1960}
}