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Title: Plasma-polymerized carbon disulfide thin-film rechargeable batteries

Journal Article · · Chemistry of Materials
DOI:https://doi.org/10.1021/cm9505557· OSTI ID:391027
;  [1]
  1. Westinghouse Science & Technology Center, Pittsburgh, PA (United States)

This paper discusses the results on deposition conditions, rates of polymerization, and properties of carbon disulfide films prepared by two techniques, viz., plasma polymerization and argon-plasma-assisted polymerization of carbon disulfide. A higher rate of polymerization and sulfur content was obtained for carbon disulfide films prepared by the plasma-polymerization technique. A Li/LiClO{sub 4} propylene carbonate/PPCS cell was assembled using lithium foil, 2 M LiClO{sub 4}/PC electrolyte with polyolefin separator, and PPCS deposited on Pt foil. The electrode area was 1.3 cm{sup 2}. The cell cycled reversibly between 1 and 3 V and retained its capacity (5 mA h/g) well over 12 cycles. 14 refs., 11 figs., 5 tabs.

OSTI ID:
391027
Journal Information:
Chemistry of Materials, Vol. 8, Issue 6; Other Information: PBD: Jun 1996
Country of Publication:
United States
Language:
English