skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis and crystal structure of ZrP{sub 2}S{sub 6} and ZrP{sub 2}S{sub 7}

Abstract

Two new compounds have been synthesized and characterized: ZrP{sub 2}S{sub 6} and ZrP{sub 2}S{sub 7}. Both were prepared from direct combination of the elements at high temperature using a chemical transporting agent. Single crystal X-ray diffraction and elemental analysis (ICP-AE) were performed on the materials. ZrP{sub 2}S{sub 6} crystallized in a tetragonal space group (P-4, a = 6.6758(4) {angstrom}, c = 9.491(1) {angstrom}) whereas the ZrP{sub 2}S{sub 7} crystallized in a monoclinic space group (C2/c, a = 8.614(1) {angstrom}, b = 29.684(4) {angstrom}, c = 8.583(1) {angstrom}, {beta} = 120.126{degree}). The ZrP{sub 2}S{sub 6} displayed a weak second harmonic generation at 1064 nm.

Authors:
; ; ;  [1];  [2]
  1. Gonzaga Univ., Spokane, WA (United States). Dept. of Chemistry
  2. Eastern Washington Univ., Cheney, WA (United States). Dept. of Chemistry
Publication Date:
Sponsoring Org.:
National Science Foundation, Washington, DC (United States)
OSTI Identifier:
338449
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 143; Journal Issue: 2; Other Information: PBD: Mar 1999
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; CRYSTAL STRUCTURE; SYNTHESIS; ZIRCONIUM SULFIDES; PHOSPHORUS SULFIDES; X-RAY DIFFRACTION; LATTICE PARAMETERS; BOND LENGTHS; BOND ANGLE; EXPERIMENTAL DATA

Citation Formats

Lott, D R, Fincher, T, LeBret, G C, Cleary, D A, and Breneman, G L. Synthesis and crystal structure of ZrP{sub 2}S{sub 6} and ZrP{sub 2}S{sub 7}. United States: N. p., 1999. Web. doi:10.1006/jssc.1998.8099.
Lott, D R, Fincher, T, LeBret, G C, Cleary, D A, & Breneman, G L. Synthesis and crystal structure of ZrP{sub 2}S{sub 6} and ZrP{sub 2}S{sub 7}. United States. https://doi.org/10.1006/jssc.1998.8099
Lott, D R, Fincher, T, LeBret, G C, Cleary, D A, and Breneman, G L. 1999. "Synthesis and crystal structure of ZrP{sub 2}S{sub 6} and ZrP{sub 2}S{sub 7}". United States. https://doi.org/10.1006/jssc.1998.8099.
@article{osti_338449,
title = {Synthesis and crystal structure of ZrP{sub 2}S{sub 6} and ZrP{sub 2}S{sub 7}},
author = {Lott, D R and Fincher, T and LeBret, G C and Cleary, D A and Breneman, G L},
abstractNote = {Two new compounds have been synthesized and characterized: ZrP{sub 2}S{sub 6} and ZrP{sub 2}S{sub 7}. Both were prepared from direct combination of the elements at high temperature using a chemical transporting agent. Single crystal X-ray diffraction and elemental analysis (ICP-AE) were performed on the materials. ZrP{sub 2}S{sub 6} crystallized in a tetragonal space group (P-4, a = 6.6758(4) {angstrom}, c = 9.491(1) {angstrom}) whereas the ZrP{sub 2}S{sub 7} crystallized in a monoclinic space group (C2/c, a = 8.614(1) {angstrom}, b = 29.684(4) {angstrom}, c = 8.583(1) {angstrom}, {beta} = 120.126{degree}). The ZrP{sub 2}S{sub 6} displayed a weak second harmonic generation at 1064 nm.},
doi = {10.1006/jssc.1998.8099},
url = {https://www.osti.gov/biblio/338449}, journal = {Journal of Solid State Chemistry},
number = 2,
volume = 143,
place = {United States},
year = {Mon Mar 01 00:00:00 EST 1999},
month = {Mon Mar 01 00:00:00 EST 1999}
}