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Title: Nickel/metal hydride secondary batteries using an alkaline solid polymer electrolyte

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/1.1391558· OSTI ID:321126

Sealed alkaline solid polymer electrolyte nickel/metal hydride laboratory cells have been constructed and tested to evaluate their properties. Studies of the cycle life, self-discharge, and behavior of cells at different temperatures were carried out. The first results on the electrochemical behavior of an alkaline solid polymer electrolyte [based on poly(ethylene oxide), potassium hydroxide, and water] medium are presented here and show good reversibility of this all-solid-state system for more than 500 cycles, without significant loss of capacity and with a reasonable average discharge efficiency (close to 80%). The temperature-dependence study allowed the determination of optimum operating conditions between 0 and 40 C. Characteristics of the solid polymer electrolyte based Ni/MH cells are compared to those of several other rechargeable battery systems.

OSTI ID:
321126
Journal Information:
Journal of the Electrochemical Society, Vol. 146, Issue 1; Other Information: PBD: Jan 1999
Country of Publication:
United States
Language:
English