Photoelectron spectroscopy of f-element organometallic complexes. 8. DV-X{alpha} and gas-phase UV photoelectron spectroscopic investigation of the electronic structure of tris ({eta}{sup 5}-cyclopentadienyl)uranium(IV) complexes
- Universita di Catania, Catania (Italy); and others
The electronic structures of a series of closely related U({eta}{sup 5}-C{sub 5}H{sub 5}){sub 3}L (L = -CH{sub 3}, -NH{sub 2}, -BH{sub 4}, - NCS) complexes has been studied using the SCF Hartree-Fock-Slater first-principles discrete variational X{alpha} method in combination with HeI and HeII UV photoelectron spectroscopy. The theoretical results reproduce the experimental HeI and He II photoelectron spectroscopic data, thus providing a reliable description of the metal-ligand bonding. 29 refs., 9 figs., 6 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 273904
- Journal Information:
- Organometallics, Vol. 11, Issue 10; Other Information: PBD: Oct 1992
- Country of Publication:
- United States
- Language:
- English
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