Preparation of the paramagnetic hydrides (Me{sub 5}C{sub 5}){sub 3}M{sub 3}({mu}{sub 3}-CH)({mu}-H) (M = Ni, Co)
- Lawrence Berkeley National Lab., CA (United States)
MeLi reacts with Me{sub 5}C{sub 5}M(acac) to give the trinuclear clusters (Me{sub 5}C{sub 5}){sub 3}M{sub 3}({mu}{sub 3}-CH)({mu}-H) (M = Co, Ni). The 49-electron nickel cluster is paramagnetic with one unpaired electron, and the 46-electron cobalt cluster is also paramagnetic; the latter reacts with dihydrogen to give diamagnetic (Me{sub 5}C{sub 5}){sub 3}Co{sub 3}({mu}{sub 3}-CH)({mu}-H){sub 3}. 10 refs., 2 figs.
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 263130
- Journal Information:
- Organometallics, Vol. 15, Issue 12; Other Information: PBD: 11 Jun 1996
- Country of Publication:
- United States
- Language:
- English
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