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Title: New energetic epoxy binders

Abstract

A new class of epoxy resins having N{single_bond}N bonds in the backbone has been synthesized with a view to explore their properties as energetic binders. The N-epoxidation of bis-dicarbonylhydrazones of adipic, azelaic and sebacic dihydrazides results in the formation of viscous resins having epoxide end groups. The resins have been characterized by the elemental and end group analyses, IR and NMR spectra. Relevant properties for their use as binders in solid propellants, such as thermal stability, heat of combustion, burn rate and performance parameters of AP-based propellant systems, have been evaluated. A significant increase in the burn rate of AP-based propellants noticed, is perhaps related to the exothermicity of the binder decomposition and the reactivity of N{single_bond}N bonds with perchloric acid formed during the combustion of AP.

Authors:
;  [1]
  1. Indian Inst. of Science, Bangalore (India)
Publication Date:
OSTI Identifier:
248245
Report Number(s):
CONF-951155-
ISBN 1-55899-321-5; TRN: IM9628%%345
Resource Type:
Book
Resource Relation:
Conference: Fall meeting of the Materials Research Society (MRS), Boston, MA (United States), 27 Nov - 1 Dec 1995; Other Information: PBD: 1996; Related Information: Is Part Of Decomposition, combustion, and detonation chemistry of energetic materials; Brill, T.B. [ed.] [Univ. of Delaware, Newark, DE (United States)]; Russell, T.P. [ed.] [Naval Research Lab., Washington, DC (United States)]; Tao, W.C. [ed.] [Lawrence Livermore National Lab., CA (United States)]; Wardle, R.B. [ed.] [Thiokol Corp., Brigham City, UT (United States)]; PB: 469 p.; Materials Research Society symposium proceedings, Volume 418
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; BINDERS; SYNTHESIS; COMBUSTION KINETICS; EPOXIDES; PROPELLANTS; AMMONIUM PERCHLORATES; ABSORPTION SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE; THERMAL ANALYSIS; COMBUSTION HEAT; ROCKET ENGINES; EXPERIMENTAL DATA

Citation Formats

Jain, S.R., and Amanulla, S.. New energetic epoxy binders. United States: N. p., 1996. Web.
Jain, S.R., & Amanulla, S.. New energetic epoxy binders. United States.
Jain, S.R., and Amanulla, S.. Mon . "New energetic epoxy binders". United States. doi:.
@article{osti_248245,
title = {New energetic epoxy binders},
author = {Jain, S.R. and Amanulla, S.},
abstractNote = {A new class of epoxy resins having N{single_bond}N bonds in the backbone has been synthesized with a view to explore their properties as energetic binders. The N-epoxidation of bis-dicarbonylhydrazones of adipic, azelaic and sebacic dihydrazides results in the formation of viscous resins having epoxide end groups. The resins have been characterized by the elemental and end group analyses, IR and NMR spectra. Relevant properties for their use as binders in solid propellants, such as thermal stability, heat of combustion, burn rate and performance parameters of AP-based propellant systems, have been evaluated. A significant increase in the burn rate of AP-based propellants noticed, is perhaps related to the exothermicity of the binder decomposition and the reactivity of N{single_bond}N bonds with perchloric acid formed during the combustion of AP.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jul 01 00:00:00 EDT 1996},
month = {Mon Jul 01 00:00:00 EDT 1996}
}

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