Promoting electrochemical rates by concurrent ionic-electronic conductivity enhancement in high mass loading cathode electrode

Wang, Ying; Mijailovic, Aleksandar S.; Ji, Tongtai; Cakmak, Ercan; Zhao, Xianhui; Huang, Luyao; Sheldon, Brian W.; Zhu, Hongli

doi:10.1016/j.ensm.2024.103546

Promoting electrochemical rates by concurrent ionic-electronic conductivity enhancement in high mass loading cathode electrode

Journal Article · Mon Jun 10 00:00:00 EDT 2024 · Energy Storage Materials

DOI:https://doi.org/10.1016/j.ensm.2024.103546· OSTI ID:2438749

^[1]; Mijailovic, Aleksandar S. ^[2]; Ji, Tongtai ^[1]; ^[3]; ^[3]; Huang, Luyao ^[1]; Sheldon, Brian W. ^[2]; ^[1]

Northeastern Univ., Boston, MA (United States)
Brown Univ., Providence, RI (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Enhancing the fast charging capacity of thick electrodes with high mass loading is imperative in expediting the widespread adoption of electric vehicles. Nonetheless, the insufficient charge transfer kinetics of thick electrodes hinder the movement of effective electrons and ions, hence diminishing capacity at high current rates. In this work, we applied sustainable and biodegradable cellulose nanocrystals (CNCs) as electrode additives. It is the first time to simultaneously improve the electronic conductivity by optimizing the carbon dispersion and establishing electron transfer networks, as well as boosting the ionic conductivity of electrodes by shortening the ion transfer pathway. Specifically, the LiNi_0.6Mn_0.2Co_0.2O₂ electrodes incorporating 1% dual functional CNCs additive exhibit improved effective electrical conductivity from 0.11 to 0.16 S/m and risen effective ionic conductivity from 0.36 to 0.62 S/m, in comparison to counterpart electrodes without CNCs. Therefore, the 1% CNC electrode with a high mass loading of 27.0 mg/cm² delivers a discharge capacity of 128 mAh/g at 1 C, which is superior to that of the CNC-free electrodes (95 mAh/g). In short, this study presents a novel environmentally friendly, economically viable, and dual-functional electrode additive that enhances both electronic and ionic conductivities with the aim of facilitating the widespread adoption of fast-charging high mass loading electrodes.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725; EE0009111

OSTI ID:: 2438749

Alternate ID(s):: OSTI ID: 2375567

Journal Information:: Energy Storage Materials, Journal Name: Energy Storage Materials Vol. 71; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (44)

Amphipathic Binder Integrating Ultrathin and Highly Ion‐Conductive Sulfide Membrane for Cell‐Level High‐Energy‐Density All‐Solid‐State Batteries Cao, Daxian; Li, Qiang; Sun, Xiao Advanced Materials, Vol. 33, Issue 52 https://doi.org/10.1002/adma.202105505	journal	October 2021
Tuning Chiral Nematic Pitch of Bioresourced Photonic Films via Coupling Organic Acid Hydrolysis Cheng, Zheng; Ye, Huilin; Cheng, Feng Advanced Materials Interfaces, Vol. 6, Issue 7 https://doi.org/10.1002/admi.201802010	journal	February 2019
Tortuosity Anisotropy in Lithium-Ion Battery Electrodes Ebner, Martin; Chung, Ding-Wen; García, R. Edwin Advanced Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aenm.201301278	journal	October 2013
Thick Electrode Batteries: Principles, Opportunities, and Challenges Kuang, Yudi; Chen, Chaoji; Kirsch, Dylan Advanced Energy Materials, Vol. 9, Issue 33 https://doi.org/10.1002/aenm.201901457	journal	July 2019
A Review of the Design of Advanced Binders for High‐Performance Batteries Zou, Feng; Manthiram, Arumugam Advanced Energy Materials, Vol. 10, Issue 45 https://doi.org/10.1002/aenm.202002508	journal	October 2020
Versatile zero‐ to three‐dimensional carbon for electrochemical energy storage Zhao, Yuyue; Zhang, Yunlu; Wang, Ying Carbon Energy, Vol. 3, Issue 6 https://doi.org/10.1002/cey2.137	journal	August 2021
Manufacturing Water‐Based Low‐Tortuosity Electrodes for Fast‐Charge through Pattern Integrated Stamping Ren, Haoze; Wang, Ying; Cao, Daxian ENERGY & ENVIRONMENTAL MATERIALS, Vol. 6, Issue 4 https://doi.org/10.1002/eem2.12584	journal	February 2023
Influence of the Carbon Black Dispersing Process on the Microstructure and Performance of Li‐Ion Battery Cathodes Mayer, Julian Kristoffer; Almar, Laura; Asylbekov, Ermek Energy Technology, Vol. 8, Issue 2 https://doi.org/10.1002/ente.201900161	journal	June 2019
Ionic conductivity and ion transport mechanisms of solid‐state lithium‐ion battery electrolytes: A review Yang, Hui; Wu, Nianqiang Energy Science & Engineering, Vol. 10, Issue 5 https://doi.org/10.1002/ese3.1163	journal	April 2022
Designing Low Tortuosity Electrodes through Pattern Optimization for Fast‐Charging Wang, Ying; Zhang, Yuxuan; Cao, Daxian Small Methods, Vol. 7, Issue 4 https://doi.org/10.1002/smtd.202201344	journal	February 2023
Preparation and characterization of nanocrystalline cellulose via low-intensity ultrasonic-assisted sulfuric acid hydrolysis Tang, Yanjun; Yang, Shujie; Zhang, Nan Cellulose, Vol. 21, Issue 1 https://doi.org/10.1007/s10570-013-0158-2	journal	December 2013
Understanding limiting factors in thick electrode performance as applied to high energy density Li-ion batteries Du, Zhijia; Wood, D. L.; Daniel, C. Journal of Applied Electrochemistry, Vol. 47, Issue 3 https://doi.org/10.1007/s10800-017-1047-4	journal	February 2017
Aminosilane-grafted spherical cellulose nanocrystal aerogel with high CO2 adsorption capacity Zhang, Tianmeng; Zhang, Yang; Jiang, Hua Environmental Science and Pollution Research, Vol. 26, Issue 16 https://doi.org/10.1007/s11356-019-05068-3	journal	April 2019
Breakdown and buildup mechanisms of cellulose nanocrystal suspensions under shear and upon relaxation probed by SAXS and SALS Pignon, Frédéric; Challamel, Mathilde; De Geyer, Antoine Carbohydrate Polymers, Vol. 260 https://doi.org/10.1016/j.carbpol.2021.117751	journal	May 2021
Behavior of nanocelluloses at interfaces Capron, Isabelle; Rojas, Orlando J.; Bordes, Romain Current Opinion in Colloid & Interface Science, Vol. 29 https://doi.org/10.1016/j.cocis.2017.04.001	journal	May 2017
A theoretical analysis of the optimal electrode thickness and porosity Haverkort, J. W. Electrochimica Acta, Vol. 295 https://doi.org/10.1016/j.electacta.2018.10.065	journal	February 2019
Towards high-energy-density lithium-ion batteries: Strategies for developing high-capacity lithium-rich cathode materials Zhao, Shuoqing; Guo, Ziqi; Yan, Kang Energy Storage Materials, Vol. 34 https://doi.org/10.1016/j.ensm.2020.11.008	journal	January 2021
Opening twisted polymer chains for simultaneously high printability and battery fast-charge Wang, Ying; He, Jinlong; Cao, Daxian Energy Storage Materials, Vol. 55 https://doi.org/10.1016/j.ensm.2022.11.025	journal	January 2023
Characterization of the calendering process for compaction of electrodes for lithium-ion batteries Meyer, Chris; Bockholt, Henrike; Haselrieder, Wolfgang Journal of Materials Processing Technology, Vol. 249 https://doi.org/10.1016/j.jmatprotec.2017.05.031	journal	November 2017
Optimizing the surfactant for the aqueous processing of LiFePO₄ composite electrodes Porcher, W.; Lestriez, B.; Jouanneau, S. Journal of Power Sources, Vol. 195, Issue 9, p. 2835-2843 https://doi.org/10.1016/j.jpowsour.2009.11.088	journal	May 2010
Nanocellulose as green dispersant for two-dimensional energy materials Li, Yuanyuan; Zhu, Hongli; Shen, Fei Nano Energy, Vol. 13 https://doi.org/10.1016/j.nanoen.2015.02.015	journal	April 2015
Hydroxyl on the filler surface promotes Li+ conduction in PEO all-solid-state electrolyte Wang, Xin; Hua, Haiming; Xie, Xiaohua Solid State Ionics, Vol. 372 https://doi.org/10.1016/j.ssi.2021.115768	journal	December 2021
Electron and Ion Transport in Lithium and Lithium-Ion Battery Negative and Positive Composite Electrodes Quilty, Calvin D.; Wu, Daren; Li, Wenzao Chemical Reviews, Vol. 123, Issue 4 https://doi.org/10.1021/acs.chemrev.2c00214	journal	February 2023
Cellulose-Based Ionic Conductor: An Emerging Material toward Sustainable Devices Ye, Yuhang; Yu, Le; Lizundia, Erlantz Chemical Reviews, Vol. 123, Issue 15 https://doi.org/10.1021/acs.chemrev.2c00618	journal	July 2023
Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices Chen, Hao; Ling, Min; Hencz, Luke Chemical Reviews, Vol. 118, Issue 18 https://doi.org/10.1021/acs.chemrev.8b00241	journal	August 2018
Stable and Highly Ion-Selective Membrane Made from Cellulose Nanocrystals for Aqueous Redox Flow Batteries Mukhopadhyay, Alolika; Cheng, Zheng; Natan, Avi Nano Letters, Vol. 19, Issue 12 https://doi.org/10.1021/acs.nanolett.9b03964	journal	November 2019
Sulfonic Groups Originated Dual-Functional Interlayer for High Performance Lithium–Sulfur Battery Lu, Yang; Gu, Sui; Guo, Jing ACS Applied Materials & Interfaces, Vol. 9, Issue 17 https://doi.org/10.1021/acsami.7b02142	journal	April 2017
Processing Strategies to Improve Cell-Level Energy Density of Metal Sulfide Electrolyte-Based All-Solid-State Li Metal Batteries and Beyond Cao, Daxian; Zhao, Yuyue; Sun, Xiao ACS Energy Letters, Vol. 5, Issue 11 https://doi.org/10.1021/acsenergylett.0c01905	journal	October 2020
Lithiation Gradients and Tortuosity Factors in Thick NMC111-Argyrodite Solid-State Cathodes Stavola, Alyssa M.; Sun, Xiao; Guida, Dominick P. ACS Energy Letters, Vol. 8, Issue 2 https://doi.org/10.1021/acsenergylett.2c02699	journal	February 2023
The Critical Roles of Water in the Processing, Structure, and Properties of Nanocellulose Jing, Shuangshuang; Wu, Lianping; Siciliano, Amanda P. ACS Nano, Vol. 17, Issue 22 https://doi.org/10.1021/acsnano.3c06773	journal	November 2023
Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications Habibi, Youssef; Lucia, Lucian A.; Rojas, Orlando J. Chemical Reviews, Vol. 110, Issue 6 https://doi.org/10.1021/cr900339w	journal	June 2010
Tin Anode for Sodium-Ion Batteries Using Natural Wood Fiber as a Mechanical Buffer and Electrolyte Reservoir Zhu, Hongli; Jia, Zheng; Chen, Yuchen Nano Letters, Vol. 13, Issue 7 https://doi.org/10.1021/nl400998t	journal	June 2013
Promise and reality of post-lithium-ion batteries with high energy densities Choi, Jang Wook; Aurbach, Doron Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.13	journal	March 2016
Copper-coordinated cellulose ion conductors for solid-state batteries Yang, Chunpeng; Wu, Qisheng; Xie, Weiqi Nature, Vol. 598, Issue 7882 https://doi.org/10.1038/s41586-021-03885-6	journal	October 2021
Fast charging of energy-dense lithium-ion batteries Wang, Chao-Yang; Liu, Teng; Yang, Xiao-Guang Nature, Vol. 611, Issue 7936 https://doi.org/10.1038/s41586-022-05281-0	journal	October 2022
A gravure printed antenna on shape-stable transparent nanopaper Zhu, Hongli; Narakathu, Binu Baby; Fang, Zhiqiang Nanoscale, Vol. 6, Issue 15 https://doi.org/10.1039/C4NR02036G	journal	June 2014
Enhancing composite electrode performance: insights into interfacial interactions Ren, Haoze; Takeuchi, Esther S.; Marschilok, Amy C. Chemical Communications, Vol. 60, Issue 15 https://doi.org/10.1039/D3CC05608B	journal	January 2024
Multi-scale computation methods: Their applications in lithium-ion battery research and development Shi, Siqi; Gao, Jian; Liu, Yue Chinese Physics B, Vol. 25, Issue 1 https://doi.org/10.1088/1674-1056/25/1/018212	journal	January 2016
Relationship of Chemical Composition and Moisture Sensitivity in LiNixMnyCo1−X−YO2 for Lithium-Ion Batteries Choi, Junbin; Dong, Liang; Yu, Chan-Yeop Journal of Electrochemical Energy Conversion and Storage, Vol. 18, Issue 4 https://doi.org/10.1115/1.4051208	journal	June 2021
Analytical and Numerical Analysis of Lithium Plating Onset in Single and Bilayer Graphite Electrodes during Fast Charging Mijailovic, Aleksandar S.; Wang, Guanyi; Li, Yejing Journal of The Electrochemical Society, Vol. 169, Issue 6 https://doi.org/10.1149/1945-7111/ac73bb	journal	June 2022
A “Master Curve” Describing Reaction Inhomogeneity and Plating Onset during Fast-Charging of Graphite Electrodes Mijailovic, Aleksandar S.; Wang, Guanyi; Luo, Mei Journal of The Electrochemical Society, Vol. 170, Issue 7 https://doi.org/10.1149/1945-7111/acd963	journal	July 2023
Characterization and Cellular Internalization of Spherical Cellulose Nanocrystals (CNC) into Normal and Cancerous Fibroblasts Shazali, Nur; Zaidi, Noorzaileen; Ariffin, Hidayah Materials, Vol. 12, Issue 19 https://doi.org/10.3390/ma12193251	journal	October 2019
Electrical and Electrochemical Properties of Conducting Polymers Le, Thanh-Hai; Kim, Yukyung; Yoon, Hyeonseok Polymers, Vol. 9, Issue 12 https://doi.org/10.3390/polym9040150	journal	April 2017
An Effective Mixing for Lithium Ion Battery Slurries Liu, Darjen; Chen, Li-Chun; Liu, Ta-Jo Advances in Chemical Engineering and Science, Vol. 04, Issue 04 https://doi.org/10.4236/aces.2014.44053	journal	January 2014

Similar Records

Designing Low Tortuosity Electrodes through Pattern Optimization for Fast-Charging

Journal Article · Sun Feb 19 19:00:00 EST 2023 · Small Methods · OSTI ID:1959580

Opening twisted polymer chains for simultaneously high printability and battery fast-charge

Journal Article · Mon Nov 14 19:00:00 EST 2022 · Energy Storage Materials · OSTI ID:1901640

Related Subjects

25 ENERGY STORAGE
Cellulose nanocrystals
Electrode additive
Electronic conductivity
Ionic conductivity
Kinetics
Lithium-ion battery

Promoting electrochemical rates by concurrent ionic-electronic conductivity enhancement in high mass loading cathode electrode

Citation Formats

References (44)

Similar Records

Related Subjects