Experimental Study of the Adsorption and Decomposition of Sarin on Dry Copper(II) Oxide

Leonard, Matthew B.; Bruni, Eric; Hall, Morgan; Li, Tianyu; Rodriguez, Efrain E.; Durke, Erin M.

doi:10.1021/acs.jpclett.2c03187

Experimental Study of the Adsorption and Decomposition of Sarin on Dry Copper(II) Oxide

Journal Article · 11 December 2022 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.2c03187· OSTI ID:2425672

^[1]; Bruni, Eric ^[2]; Hall, Morgan ^[2]; ^[3]; ^[3]; Durke, Erin M. ^[2]

Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, United States; U.S. Army Combat Capabilities Development Command Chemical Biological Center, 8198 Blackhawk Road, Aberdeen Proving Ground, Maryland 21010, United States
U.S. Army Combat Capabilities Development Command Chemical Biological Center, 8198 Blackhawk Road, Aberdeen Proving Ground, Maryland 21010, United States
Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, United States

Not provided.

Research Organization:: Oak Ridge Institute for Science and Education (ORISE), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0014664

OSTI ID:: 2425672

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 50 Vol. 13; ISSN 1948-7185

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (20)

In situ FTIR spectra of pyridine adsorbed on SiO2–Al2O3, TiO2, ZrO2 and CeO2: general considerations for the identification of acid sites on surfaces of finely divided metal oxides Zaki, Mohamed I.; Hasan, Muhammad A.; Al-Sagheer, Fakhryia A. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 190, Issue 3 https://doi.org/10.1016/S0927-7757(01)00690-2	journal	October 2001
Tailoring the reducibility and catalytic activity of CuO nanoparticles for low temperature CO oxidation Zedan, Abdallah F.; Mohamed, Assem T.; El-Shall, M. Samy RSC Advances, Vol. 8, Issue 35 https://doi.org/10.1039/C8RA03623C	journal	January 2018
Dimethyl methylphosphonate adsorption and decomposition on MoO ₂ as studied by ambient pressure x-ray photoelectron spectroscopy and DFT calculations Head, Ashley R.; Tsyshevsky, Roman; Trotochaud, Lena Journal of Physics: Condensed Matter, Vol. 30, Issue 13 https://doi.org/10.1088/1361-648X/aab192	journal	March 2018
Titania Nanomaterials for Sarin Decomposition: Understanding Fundamentals Li, Tianyu; Tsyshevsky, Roman; McEntee, Monica ACS Applied Nano Materials, Vol. 5, Issue 5 https://doi.org/10.1021/acsanm.2c00693	journal	April 2022
Adsorption and Decomposition of Sarin on Dry and Wet Cu₂O(111) and CuO(111) Surfaces: Insight from First-Principles Calculations Ma, Denghui; Cao, Zexing The Journal of Physical Chemistry C, Vol. 125, Issue 44 https://doi.org/10.1021/acs.jpcc.1c07072	journal	October 2021
Spectroscopic studies of methyl paraoxon decomposition over mesoporous Ce-doped titanias for toxic chemical filtration Leonard, Matthew B.; Li, Tianyu; Kramer, Morgan J. Journal of Hazardous Materials, Vol. 438 https://doi.org/10.1016/j.jhazmat.2022.129536	journal	September 2022
Spectroscopic and Computational Investigation of Room-Temperature Decomposition of a Chemical Warfare Agent Simulant on Polycrystalline Cupric Oxide Trotochaud, Lena; Tsyshevsky, Roman; Holdren, Scott Chemistry of Materials, Vol. 29, Issue 17 https://doi.org/10.1021/acs.chemmater.7b02489	journal	August 2017
Understanding Dimethyl Methylphosphonate Adsorption and Decomposition on Mesoporous CeO₂ Li, Tianyu; Tsyshevsky, Roman; Algrim, Lucas ACS Applied Materials & Interfaces, Vol. 13, Issue 45 https://doi.org/10.1021/acsami.1c16668	journal	November 2021
Thermal Decomposition of a Chemical Warfare Agent Simulant (DMMP) on TiO 2 : Adsorbate Reactions with Lattice Oxygen as Studied by Infrared Spectroscopy Panayotov, Dimitar A.; Morris, John R. The Journal of Physical Chemistry C, Vol. 113, Issue 35 https://doi.org/10.1021/jp9036233	journal	August 2009
Photoenhanced Degradation of Sarin at Cu/TiO₂ Composite Aerogels: Roles of Bandgap Excitation and Surface Plasmon Excitation DeSario, Paul A.; Gordon, Wesley O.; Balboa, Alex ACS Applied Materials & Interfaces, Vol. 13, Issue 10 https://doi.org/10.1021/acsami.0c21988	journal	March 2021
Novichoks: The Dangerous Fourth Generation of Chemical Weapons Franca, Tanos; Kitagawa, Daniel; Cavalcante, Samir International Journal of Molecular Sciences, Vol. 20, Issue 5 https://doi.org/10.3390/ijms20051222	journal	March 2019
Spectroscopically Resolved Binding Sites for the Adsorption of Sarin Gas in a Metal–Organic Framework: Insights beyond Lewis Acidity Harvey, Jacob A.; McEntee, Monica L.; Garibay, Sergio J. The Journal of Physical Chemistry Letters, Vol. 10, Issue 17 https://doi.org/10.1021/acs.jpclett.9b01867	journal	August 2019
How Useful Are Common Simulants of Chemical Warfare Agents at Predicting Adsorption Behavior? Agrawal, Mayank; Sava Gallis, Dorina F.; Greathouse, Jeffery A. The Journal of Physical Chemistry C, Vol. 122, Issue 45 https://doi.org/10.1021/acs.jpcc.8b08856	journal	October 2018
Degradation of Fatal Toxic Nerve Agents on Dry TiO ₂ Tsyshevsky, Roman; McEntee, Monica; Durke, Erin M. ACS Applied Materials & Interfaces, Vol. 13, Issue 1 https://doi.org/10.1021/acsami.0c19261	journal	December 2020
Experimental Study on Adsorption and Photocatalytic Decomposition of Isopropyl Methylphosphonofluoridate at Surface of TiO ₂ Photocatalyst Hirakawa, Tsutomu; Sato, Keita; Komano, Asuka The Journal of Physical Chemistry C, Vol. 114, Issue 5 https://doi.org/10.1021/jp910911x	journal	January 2010
In Situ Probes of Capture and Decomposition of Chemical Warfare Agent Simulants by Zr-Based Metal Organic Frameworks Plonka, Anna M.; Wang, Qi; Gordon, Wesley O. Journal of the American Chemical Society, Vol. 139, Issue 2 https://doi.org/10.1021/jacs.6b11373	journal	January 2017
Aerobic Copper-Catalyzed Organic Reactions Allen, Scott E.; Walvoord, Ryan R.; Padilla-Salinas, Rosaura Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300527g	journal	June 2013
Vibrational Signatures of Sarin Adsorption on Anatase Surfaces Le, Nam Q.; Bazargan, Gloria; Schweigert, Igor V. Surface Science, Vol. 705 https://doi.org/10.1016/j.susc.2020.121765	journal	March 2021
Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate, in presence of metal oxides Mukhopadhyay, Shomik; Schoenitz, Mirko; Dreizin, Edward L. Defence Technology, Vol. 17, Issue 4 https://doi.org/10.1016/j.dt.2020.08.010	journal	August 2021
Battling Chemical Weapons with Zirconium Hydroxide Nanoparticle Sorbent: Impact of Environmental Contaminants on Sarin Sequestration and Decomposition Balow, Robert B.; McEntee, Monica; Schweigert, Igor V. Langmuir, Vol. 37, Issue 23 https://doi.org/10.1021/acs.langmuir.1c00380	journal	June 2021

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Experimental Study of the Adsorption and Decomposition of Sarin on Dry Copper(II) Oxide

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