Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Single-Atom Cobalt Catalysts Coupled with Peroxidase Biocatalysis for C–H Bond Oxidation

Journal Article · · ACS Applied Materials and Interfaces
 [1];  [1];  [1];  [2];  [3];  [4];  [5];  [6];  [6];  [7];  [8];  [9]
  1. Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269, United States
  2. Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York 11790, United States
  3. Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269, United States
  4. Department of Materials Science and Engineering, University of Connecticut, Storrs, Connecticut 06269, United States
  5. Department of Chemistry, University of New Hampshire, Durham, New Hampshire 03824, United States
  6. Department of Materials Science and Engineering, University of Connecticut, Storrs, Connecticut 06269, United States; Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269, United States
  7. Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269, United States; Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269, United States; Department of Surgery and Neag Cancer Center, Uconn Health, Farmington, Connecticut 06030, United States; School of Chemistry, National University of Ireland at Galway, Galway H91 TK33, Ireland
  8. Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York 11790, United States; Division of Chemistry, Brookhaven National Laboratory, Upton, New York 11973-5000, United States
  9. Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269, United States; Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269, United States

Not provided.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0012704
OSTI ID:
2425498
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 34 Vol. 15; ISSN 1944-8244
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (58)

Tailoring 2-electron oxygen reduction reaction selectivity on h-BN-based single-atom catalysts from superoxide dismutase: A DFT investigation journal August 2022
A density functional theory study of oxygen reduction reaction on Me–N4 (Me = Fe, Co, or Ni) clusters between graphitic pores journal January 2013
Fabrication and application of electrochemical sensor for analyzing hydrogen peroxide in food system and biological samples journal August 2022
Strategies and challenges on selective electrochemical hydrogen peroxide production: Catalyst and reaction medium design journal August 2022
Thermostable Peroxidase−Polylysine Films for Biocatalysis at 90 °C journal July 2007
Heterogeneous Molecular Catalysts of Metal Phthalocyanines for Electrochemical CO2 Reduction Reactions journal August 2021
Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO2 reduction conditions using in situ X-Ray absorption spectroscopy journal January 2020
In-situ ECSTM investigation of H2O2 production in cobalt—porphyrin-catalyzed oxygen reduction reaction journal December 2022
Design of novel substituted phthalocyanines; synthesis and fluorescence, DFT, photovoltaic properties journal December 2020
Recent Advances in Electrochemical Sensing of Hydrogen Peroxide (H2O2) Released from Cancer Cells journal April 2022
Tuning Two‐Electron Oxygen‐Reduction Pathways for H 2 O 2 Electrosynthesis via Engineering Atomically Dispersed Single Metal Site Catalysts journal April 2022
Selective CO 2 Reduction Catalyzed by Single Cobalt Sites on Carbon Nitride under Visible-Light Irradiation journal October 2018
A hierarchical monolithic cobalt-single-atom electrode for efficient hydrogen peroxide production in acid journal January 2022
Biocatalytic Nitration of Phenols in Microemulsions at Elevated Temperatures Using Enzymes Stabilized on Magnetic Beads journal June 2023
Spectrophotometric determination of H2O2 in marine waters with leuco crystal violet journal December 1994
Highly Selective O2 Reduction to H2O2 Catalyzed by Cobalt Nanoparticles Supported on Nitrogen-Doped Carbon in Alkaline Solution journal April 2021
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts journal August 2016
An Adjacent Atomic Platinum Site Enables Single‐Atom Iron with High Oxygen Reduction Reaction Performance journal July 2021
Absorptiometric determination of hydrogen peroxide in submicrogram amounts with leuco crystal violet and peroxidase as catalyst journal March 1970
Solubility Properties of Unsubstituted Metal Phthalocyanines in Different Types of Solvents journal December 2011
N-Heterocyclic Carbene Modified Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide journal August 2022
Solving the structure of “single-atom” catalysts using machine learning – assisted XANES analysis journal January 2022
Defining roles of specific reactive oxygen species (ROS) in cell biology and physiology journal February 2022
Constructing ultrahigh-loading unsymmetrically coordinated Zn-N3O single-atom sites with efficient oxygen reduction for H2O2 production journal January 2023
Atomic-level tuning of Co–N–C catalyst for high-performance electrochemical H2O2 production journal January 2020
Peroxide-utilizing biocatalysts: structural and functional diversity of heme-containing enzymes journal April 2004
Highly Crystalline Mesoporous Titania Loaded with Monodispersed Gold Nanoparticles: Controllable Metal–Support Interaction in Porous Materials journal January 2020
Rotating ring-disk electrode analysis of CO2 reduction electrocatalyzed by a cobalt tetramethylpyridoporphyrazine on the disk and detected as CO on a platinum ring journal February 1996
Electrogeneration of hydrogen peroxide in acidic medium using gas diffusion electrodes modified with cobalt (II) phthalocyanine journal August 2013
Steady/transient state spectral researches on the solvent-triggered and photo-induced novel properties of metal-coordinated phthalocyanines journal January 2022
Trends in the Electrochemical Synthesis of H 2 O 2 : Enhancing Activity and Selectivity by Electrocatalytic Site Engineering journal February 2014
Enabling direct H2O2 production through rational electrocatalyst design journal November 2013
Current state and future perspectives of engineered and artificial peroxygenases for the oxyfunctionalization of organic molecules journal September 2020
Thermostable Biocatalytic Films of Enzymes and Polylysine on Electrodes and Nanoparticles in Microemulsions journal August 2008
Bioinspired Design of Hybrid Polymer Catalysts with Multicopper Sites for Oxygen Reduction journal September 2020
Single-atom-sized Ni–N4 sites anchored in three-dimensional hierarchical carbon nanostructures for the oxygen reduction reaction journal January 2020
Kinetically restrained oxygen reduction to hydrogen peroxide with nearly 100% selectivity journal May 2022
Cobalt single atom catalysts for the efficient electrosynthesis of hydrogen peroxide journal January 2021
Oxygen reduction on a high-surface area Pt/Vulcan carbon catalyst: a thin-film rotating ring-disk electrode study journal January 2001
Approaching a high-rate and sustainable production of hydrogen peroxide: oxygen reduction on Co–N–C single-atom electrocatalysts in simulated seawater journal January 2021
Coordination Engineering of Single‐Atom Catalysts for the Oxygen Reduction Reaction: A Review journal November 2020
Ultrasmall Au nanocatalysts supported on nitrided carbon for electrocatalytic CO 2 reduction: the role of the carbon support in high selectivity journal January 2018
Enabling Direct H2O2 Production in Acidic Media through Rational Design of Transition Metal Single Atom Catalyst journal March 2020
Hydrogen Peroxide in Biocatalysis. A Dangerous Liaison journal November 2012
Tuning the atomic configuration of Co-N-C electrocatalyst enables highly-selective H2O2 production in acidic media journal August 2022
Influence of Different Dye Substances on the Effectiveness of Bleaching and H2O2 Diffusion journal October 2022
Revealing the Structure of Single Cobalt Sites in Carbon Nitride for Photocatalytic CO2 Reduction journal May 2022
Absorption and Electrochemical Properties of Cobalt and Iron Phthalocyanines and Their Quaternized Derivatives: Aggregation Equilibrium and Oxygen Reduction Electrocatalysis journal August 2013
A Polymer Solution To Prevent Nanoclustering and Improve the Selectivity of Metal Nanoparticles for Electrocatalytic CO 2 Reduction journal September 2019
Linking Enzymatic Oxidative Degradation of Lignin to Organics Detoxification journal October 2018
Synthetic Polymers To Promote Cooperative Cu Activity for O 2 Activation: Poly vs Mono journal February 2019
Hollow Mesoporous Carbon Sphere Loaded Ni–N4 Single‐Atom: Support Structure Study for CO2 Electrocatalytic Reduction Catalyst journal September 2020
Impact of Anion Exchange Ionomers on the Electrocatalytic Performance for the Oxygen Reduction Reaction of B-N Co-doped Carbon Quantum Dots on Activated Carbon journal October 2022
ABTS as an electron shuttle to accelerate the degradation of diclofenac with horseradish peroxidase-catalyzed hydrogen peroxide oxidation journal December 2021
Cobalt phthalocyanine tetracarboxylic acid modified reduced graphene oxide: a sensitive matrix for the electrocatalytic detection of peroxynitrite and hydrogen peroxide journal January 2015
Au–Carbon Electronic Interaction Mediated Selective Oxidation of Styrene journal April 2017
Activity Increase of Horseradish Peroxidase in the Presence of Magnetic Particles journal February 2008
Enhanced Rates of Electrolytic Styrene Epoxidation Catalyzed by Cross-Linked Myoglobin-Poly(l-lysine) Films in Bicontinuous Microemulsions journal November 2004

Similar Records

C–C Coupling on Single-Atom-Based Heterogeneous Catalyst
Journal Article · 2018 · Journal of the American Chemical Society · OSTI ID:1539655

Cobalt single-atom catalyst as a multifunctional electrocatalyst for boosting radical generation
Journal Article · 2024 · Chemical Engineering Journal · OSTI ID:2580886

Single-Atom Pt Catalyst for Effective C–F Bond Activation via Hydrodefluorination
Journal Article · 2018 · ACS Catalysis · OSTI ID:1476272