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Studying, Promoting, Exploiting, and Predicting Catalyst Dynamics: the Next Frontier in Heterogeneous Catalysis

Journal Article · · Journal of Physical Chemistry. C
 [1];  [1];  [2];  [3];  [4];  [1]
  1. Department of Chemical Engineering and SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, 94305 California, United States
  2. Department of Chemical Engineering, Stanford University, Stanford, 94305 California, United States
  3. Department of Materials Science and Engineering, University of Science and Technology of China, 230027 Hefei, China
  4. Massachussets Institute of Technology, Cambridge, 02139 Massachusetts, United States

Not provided.

Research Organization:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-76SF00515
OSTI ID:
2423847
Journal Information:
Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 5 Vol. 127; ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (103)

Dynamic restructuring drives catalytic activity on nanoporous gold–silver alloy catalysts journal December 2016
Dynamics of Surface Alloys: Rearrangement of Pd/Ag(111) Induced by CO and O 2 journal October 2018
Tuning Selectivity in Propylene Epoxidation by Plasmon Mediated Photo-Switching of Cu Oxidation State journal March 2013
Exceptional Activity for Methane Combustion over Modular Pd@CeO2 Subunits on Functionalized Al2O3 journal August 2012
Dynamical Observation and Detailed Description of Catalysts under Strong Metal–Support Interaction journal June 2016
Tracking the formation, fate and consequence for catalytic activity of Pt single sites on CeO2 journal September 2020
Negative Charging of Au Nanoparticles during Methanol Synthesis from CO 2 /H 2 on a Au/ZnO Catalyst: Insights from Operando IR and Near‐Ambient‐Pressure XPS and XAS Measurements journal July 2019
Theoretical Heterogeneous Catalysis: Scaling Relationships and Computational Catalyst Design journal June 2016
Toward Efficient Carbon and Water Cycles: Emerging Opportunities with Single‐Site Catalysts Made of 3d Transition Metals journal November 2019
In-situ and operando spectroscopies for the characterization of catalysts and of mechanisms of catalytic reactions journal December 2021
Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO2 Reduction to Formate journal February 2020
Operando Near-Ambient Pressure X-ray Photoelectron Spectroscopy Study of the CO Oxidation Reaction on the Oxide/Metal Model Catalyst ZnO/Pt(111) journal October 2019
Reversible loss of core–shell structure for Ni–Au bimetallic nanoparticles during CO2 hydrogenation journal March 2020
Oxidative Dehydrogenation of Cyclohexane by Cu vs Pd Clusters: Selectivity Control by Specific Cluster Dynamics journal January 2020
Functional Role of Fe-Doping in Co-Based Perovskite Oxide Catalysts for Oxygen Evolution Reaction journal March 2019
Shift of the Optimum Binding Energy at Higher Rates of Catalysis journal October 2019
Dynamic structural evolution of iron catalysts involving competitive oxidation and carburization during CO 2 hydrogenation journal February 2022
Grand Challenges in Computational Catalysis journal April 2021
Enhanced Stability of Pt-Cu Single-Atom Alloy Catalysts: In Situ Characterization of the Pt/Cu(111) Surface in an Ambient Pressure of CO journal February 2018
Dynamic Core–Shell and Alloy Structures of Multimetallic Nanomaterials and Their Catalytic Synergies journal November 2020
Resonance-Promoted Formic Acid Oxidation via Dynamic Electrocatalytic Modulation journal July 2020
Catalysis by Ceria and Related Materials book January 2002
The Catalytic Mechanics of Dynamic Surfaces: Stimulating Methods for Promoting Catalytic Resonance journal September 2020
Redirecting dynamic surface restructuring of a layered transition metal oxide catalyst for superior water oxidation journal March 2021
Fluoride-Induced Dynamic Surface Self-Reconstruction Produces Unexpectedly Efficient Oxygen-Evolution Catalyst journal December 2018
Interpretable machine learning for knowledge generation in heterogeneous catalysis journal March 2022
Variable Temperature and Pressure Operando MAS NMR for Catalysis Science and Related Materials journal January 2020
Renewable power surges as pandemic scrambles global energy outlook, new report finds journal April 2020
Perovskites in catalysis and electrocatalysis journal November 2017
Three-Dimensional Quantification of the Facet Evolution of Pt Nanoparticles in a Variable Gaseous Environment journal December 2018
Genesis and Stability of Hydronium Ions in Zeolite Channels journal January 2019
Dynamic co-catalysis of Au single atoms and nanoporous Au for methane pyrolysis journal April 2020
Temperature Effects on the Catalytic Efficiency, Rate Enhancement, and Transition State Affinity of Cytidine Deaminase, and the Thermodynamic Consequences for Catalysis of Removing a Substrate “Anchor” journal July 2000
Effects of the Catalyst Dynamic Changes and Influence of the Reaction Environment on the Performance of Electrochemical CO2 Reduction journal October 2021
Catalysts by Design: The Power of Theory journal March 2017
Dynamic Phase Diagram of Catalytic Surface of Hexagonal Boron Nitride under Conditions of Oxidative Dehydrogenation of Propane journal December 2018
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts journal September 2016
Investigating the dynamic structural changes on Cu/CeO2 catalysts observed during CO2 hydrogenation journal January 2020
Principles of Dynamic Heterogeneous Catalysis: Surface Resonance and Turnover Frequency Response journal May 2019
Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction journal February 2021
Reactions at Surfaces: From Atoms to Complexity (Nobel Lecture) journal April 2008
Interplay of electrochemical and electrical effects induces structural transformations in electrocatalysts journal June 2021
Engineering of Ruthenium–Iron Oxide Colloidal Heterostructures: Improved Yields in CO 2 Hydrogenation to Hydrocarbons journal November 2019
Reaction-driven surface reconstruction of ZnAl2O4 boosts the methanol selectivity in CO2 catalytic hydrogenation journal May 2021
Future Challenges in Heterogeneous Catalysis: Understanding Catalysts under Dynamic Reaction Conditions journal November 2016
Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts journal March 2021
Atomic-Scale Observations of Catalyst Structures under Reaction Conditions and during Catalysis journal March 2016
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts journal April 2012
Structural changes in noble metal nanoparticles during CO oxidation and their impact on catalyst activity journal May 2020
Dynamic restructuring of supported metal nanoparticles and its implications for structure insensitive catalysis journal December 2021
Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide journal April 2020
Uncovering near-free platinum single-atom dynamics during electrochemical hydrogen evolution reaction journal February 2020
Insights of the Dynamic Copper Active Sites in Ethylene Oxychlorination Studied by the Multivariate UV–vis–NIR Resolution Kinetic Approach journal June 2021
Unveiling the Activity Origin of Iron Nitride as Catalytic Material for Efficient Hydrogenation of CO2 to C2+ Hydrocarbons journal January 2021
Evolution of Isolated Atoms and Clusters in Catalysis journal April 2020
The concept of active site in heterogeneous catalysis journal January 2022
A‐Site Management Prompts the Dynamic Reconstructed Active Phase of Perovskite Oxide OER Catalysts journal February 2021
Following the structure of copper-zinc-alumina across the pressure gap in carbon dioxide hydrogenation journal June 2021
Reversible catalysis journal April 2021
Operando unraveling photothermal-promoted dynamic active-sites generation in NiFe 2 O 4 for markedly enhanced oxygen evolution journal February 2021
Catalytically Active and Spectator Ce 3+ in Ceria-Supported Metal Catalysts journal June 2015
Bridging the Gap between the X-ray Absorption Spectroscopy and the Computational Catalysis Communities in Heterogeneous Catalysis: A Perspective on the Current and Future Research Directions journal October 2022
Recent Advances in the Application of Electron Tomography to Materials Chemistry journal August 2012
Structural Rearrangements of Subnanometer Cu Oxide Clusters Govern Catalytic Oxidation journal April 2020
Dynamic interplay between metal nanoparticles and oxide support under redox conditions journal May 2022
Exploring the environmental transmission electron microscope journal November 2012
In Situ Infrared Spectroscopy as a Tool for Monitoring Molecular Catalyst for Hydroformylation in Continuous Processes journal April 2019
Local Fluxionality of Surface-Deposited Cluster Catalysts: The Case of Pt 7 on Al 2 O 3 journal March 2018
Dynamic structure evolution of free-standing S-doped porous Co-Fe microspheres with enhanced oxygen evolution electrocatalysis in alkaline media journal November 2020
Dynamic Systems, Process and Development journal January 2019
Effect of Temperature and Catalyst Concentration on Polyglycerol during Synthesis journal January 2015
Heterogeneous single-atom catalysis journal May 2018
Single-Atom Alloys as a Reductionist Approach to the Rational Design of Heterogeneous Catalysts journal December 2018
Structural evolution of Cu2O nanocube electrocatalysts for the CO2 reduction reaction journal February 2023
Nonlinear Chemical Dynamics:  Oscillations, Patterns, and Chaos journal January 1996
Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting journal January 2015
Grand challenges for catalysis in the Science and Technology Roadmap on Catalysis for Europe: moving ahead for a sustainable future journal January 2017
New Challenges in Heterogeneous Catalysis for the 21st Century journal March 2012
Towards the computational design of solid catalysts journal April 2009
Quick-scanning x-ray absorption spectroscopy system with a servo-motor-driven channel-cut monochromator with a temporal resolution of 10 ms journal August 2012
Understanding of K and Mg co-promoter effect in ethylene oxychlorination by operando UV–vis-NIR spectroscopy journal June 2021
Reaction-Mediated Transformation of Working Catalysts journal June 2022
The Impact of Nanoscience on Heterogeneous Catalysis journal March 2003
Quick-EXAFS setup at the SuperXAS beamline for in situ X-ray absorption spectroscopy with 10 ms time resolution journal January 2016
Dynamic evolution and reversibility of single-atom Ni(II) active site in 1T-MoS2 electrocatalysts for hydrogen evolution journal August 2020
In-situ characterization of water–gas shift catalysts using time-resolved X-ray diffraction journal July 2009
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis journal April 2013
Direct observation of charge separation in an organic light harvesting system by femtosecond time-resolved XPS journal February 2021
From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis journal August 2015
Highly Active and Stable CeO2-Promoted CuCl2/Al2O3 Oxychlorination Catalysts Developed by Rational Design Using a Rate Diagram of the Catalytic Cycle journal September 2016
Dynamic Control of Elementary Step Energetics via Pulsed Illumination Enhances Photocatalysis on Metal Nanoparticles journal October 2020
Voltage cycling process for the electroconversion of biomass-derived polyols journal October 2021
Dynamic Surface Reconstruction of Single-Atom Bimetallic Alloy under Operando Electrochemical Conditions journal October 2020
Exploration of Dynamic Structure–Activity Relationship of a Platinum Nanoparticle in the CO Oxidation Reaction journal September 2021
Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses journal April 2022
Sabatier Principle for Interfacial (Heterogeneous) Enzyme Catalysis journal October 2018
A Theory of the Catalytic Surface journal May 1925
Operando X-ray Photoelectron Spectroscopy for High-Pressure Catalysis Research Using the POLARIS Endstation journal May 2022
Fischer–Tropsch Synthesis to Olefins: Catalytic Performance and Structure Evolution of Co 2 C-Based Catalysts under a CO 2 Environment journal September 2019
Ensembles of Metastable States Govern Heterogeneous Catalysis on Dynamic Interfaces journal January 2020
Molecules at Solid Surfaces: A Personal Reminiscence journal May 2017
Heterogeneous Catalysis: Understanding for Designing, and Designing for Applications journal April 2016
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts journal August 2003

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