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Graphite-like Charge Storage Mechanism in a 2D π–d Conjugated Metal–Organic Framework Revealed by Stepwise Magnetic Monitoring

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c10650· OSTI ID:2423750
 [1];  [2];  [2];  [3];  [4]
  1. Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan
  2. Department of Chemistry, Wayne State University, Detroit, Michigan 48202, United States
  3. Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan
  4. Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan; Integrated Research Consortium on Chemical Sciences, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan

Not provided.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
OSTI ID:
2423750
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 2 Vol. 145; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (53)

Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal–Organic Framework journal September 2018
2D Copper Tetrahydroxyquinone Conductive Metal–Organic Framework for Selective CO 2 Electrocatalysis at Low Overpotentials journal February 2021
Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications journal February 2021
Immobilizing Redox‐Active Tricycloquinazoline into a 2D Conductive Metal–Organic Framework for Lithium Storage journal October 2021
Conductive two-dimensional metal–organic frameworks as multifunctional materials journal January 2018
Cu2+ probe of metal-ion binding sites in melanin using electron paramagnetic resonance spectroscopy journal June 1980
Advanced capabilities for materials modelling with Quantum ESPRESSO journal October 2017
Pauli Paramagnetism of Stable Analogues of Pernigraniline Salt Featuring Ladder-Type Constitution journal December 2019
Successive Storage of Cations and Anions by Ligands of π–d‐Conjugated Coordination Polymers Enabling Robust Sodium‐Ion Batteries journal July 2021
New Porous Crystals of Extended Metal-Catecholates journal August 2012
First-Principles Theory of the EPR g Tensor in Solids: Defects in Quartz journal February 2002
Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing journal February 2015
Delocalized Metal–Oxygen π-Redox Is the Origin of Anomalous Nonhysteretic Capacity in Li-Ion and Na-Ion Cathode Materials journal January 2021
Robust and conductive two-dimensional metal−organic frameworks with exceptionally high volumetric and areal capacitance journal January 2018
Sodium Storage Behavior in Natural Graphite using Ether-based Electrolyte Systems journal November 2014
Unpaired 3d Electrons on Atomically Dispersed Cobalt Centres in Coordination Polymers Regulate both Oxygen Reduction Reaction (ORR) Activity and Selectivity for Use in Zinc–Air Batteries journal November 2019
Optimized norm-conserving Vanderbilt pseudopotentials journal August 2013
Tuning Ground States of Bis(triarylamine) Dications: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State journal February 2014
Highly Conductive Two-Dimensional Metal–Organic Frameworks for Resilient Lithium Storage with Superb Rate Capability journal August 2020
Exotic Topological Bands and Quantum States in Metal–Organic and Covalent–Organic Frameworks journal January 2021
Host–Guest Interactions and Redox Activity in Layered Conductive Metal–Organic Frameworks journal July 2020
Paramagnetic susceptibility of highly conducting polyaniline: Disordered metal with weak electron-electron interactions (Fermi glass) journal March 1994
Electrochemical Tuning-Induced Magnetic Transitions in Geometrically Frustrated Spinel LixMn2O4 (0.07 ≤ x ≤ 0.93) journal March 2021
2D Conductive Metal‐Organic Frameworks: An Emerging Platform for Electrochemical Energy Storage journal May 2020
Making large single crystals of 2D MOFs journal January 2021
Electron spin resonance studies in the doped polyaniline PANI-AMPSA: Evidence for local ordering from linewidth features journal July 2005
Crystal-to-crystal transformation in solid-state electrochemical doping of Cl ions to the nanoporous neutral radical lithium phthalocyanine: revelation of electron–electron correlations in the 1D half-filled system journal January 2014
A Three-Dimensional Synthetic Metallic Crystal Composed of Single-Component Molecules journal January 2001
Thiophene and its sulfur inhibit indenoindenodibenzothiophene diradicals from low-energy lying thermal triplets journal September 2018
o-Benzosemiquinone and its metal chelates. Electron spin resonance investigation of radicals from the photolysis of catechol in the presence of complexing metal ions journal March 1982
Resonating Valence-Bond Ground State in a Phenalenyl-Based Neutral Radical Conductor journal July 2005
Extraordinary electrochemical stability and extended polaron delocalization of ladder-type polyaniline-analogous polymers journal January 2020
Line graph theory reveals hidden spin frustration and bond frustration in molecular crystals with strong isotropy journal January 2022
Diamagnetic Corrections and Pascal's Constants journal April 2008
Pro-aromatic and anti-aromatic π-conjugated molecules: an irresistible wish to be diradicals journal January 2015
Intercalation chemistry of graphite: alkali metal ions and beyond journal January 2019
Recent Progress in Graphite Intercalation Compounds for Rechargeable Metal (Li, Na, K, Al)-Ion Batteries journal June 2017
Two-Dimensional π-Conjugated Frameworks as a Model System to Unveil a Multielectron-Transfer-Based Energy Storage Mechanism journal May 2021
Ultrathin two-dimensional conjugated metal–organic framework single-crystalline nanosheets enabled by surfactant-assisted synthesis journal January 2020
Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries journal October 2019
Quantum Spin Liquid State in a Two-Dimensional Semiconductive Metal–Organic Framework journal July 2020
A magnetic susceptibility study of emeraldine base polyaniline journal February 2004
Stabilization of Hexaaminobenzene in a 2D Conductive Metal–Organic Framework for High Power Sodium Storage journal July 2018
High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue journal April 2014
Electron Paramagnetic Resonance Study of Copper–Ethylenediamine Complex Ion Intercalated in Bentonite journal October 2013
Electrochemistry of graphite intercalation compounds journal March 1998
Enhancement of Second Hyperpolarizabilities in Open-Shell Singlet Slipped-Stack Dimers Composed of Square Planar Nickel Complexes Involving o-Semiquinonato Type Ligands journal January 2011
Generalized Gradient Approximation Made Simple journal October 1996
Multielectron-Transfer-based Rechargeable Energy Storage of Two-Dimensional Coordination Frameworks with Non-Innocent Ligands journal May 2018
Optimization algorithm for the generation of ONCV pseudopotentials journal November 2015
Toward Stable Superbenzoquinone Diradicaloids journal March 2017
Quinoidal conjugated polymers with open-shell character journal January 2021
A Redox‐Active 2D Metal–Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity journal March 2020

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