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The Role of Bismuth in Suppressing the CO Poisoning in Alkaline Methanol Electrooxidation: Switching the Reaction from the CO to Formate Pathway

Journal Article · · Nano Letters
 [1];  [2];  [3];  [4];  [2];  [2];  [5];  [6];  [2];  [7];  [3];  [2];  [5];  [2]
  1. Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, P. R. China; Department of Chemistry, and Soochow-Western Center for Synchrotron Radiation Research, University of Western Ontario, London, Ontario N6A5B7, Canada
  2. Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, P. R. China
  3. Key Laboratory of General Chemistry of National Ethnic Affairs Commission, School of Chemistry and Environment, Southwest Minzu University, Chengdu 610041, China
  4. National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan
  5. Department of Chemistry, and Soochow-Western Center for Synchrotron Radiation Research, University of Western Ontario, London, Ontario N6A5B7, Canada
  6. School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China
  7. Soochow Institute for Energy and Materials Innovations, College of Energy, Soochow University, Suzhou 215006, China
+ Show Author Affiliations

Not provided.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
OSTI ID:
2423697
Journal Information:
Nano Letters, Journal Name: Nano Letters Journal Issue: 2 Vol. 23; ISSN 1530-6984
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

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Pt Atomic Layers with Tensile Strain and Rich Defects Boost Ethanol Electrooxidation journal September 2022
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p–d Orbital Hybridization Induced by a Monodispersed Ga Site on a Pt3Mn Nanocatalyst Boosts Ethanol Electrooxidation journal January 2022
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Potential-Dependent Selectivity of Ethanol Complete Oxidation on Rh Electrode in Alkaline Media: A Synergistic Study of Electrochemical ATR-SEIRAS and IRAS journal March 2019
From HCOOH to CO at Pd Electrodes: A Surface-Enhanced Infrared Spectroscopy Study journal September 2011
High‐Performance Bismuth‐Doped Nickel Aerogel Electrocatalyst for the Methanol Oxidation Reaction journal June 2020
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Excavated RhNi alloy nanobranches enable superior CO-tolerance and CO2selectivity at low potentials toward ethanol electro-oxidation journal January 2019
Highly active and durable methanol oxidation electrocatalyst based on the synergy of platinum–nickel hydroxide–graphene journal November 2015
Efficient electrochemical ethanol-to-CO2 conversion at rhodium and bismuth hydroxide interfaces journal January 2022
Tuning Pt-skinned PtAg nanotubes in nanoscales to efficiently modify electronic structure for boosting performance of methanol electrooxidation journal May 2020
Realizing a CO-free pathway and enhanced durability in highly dispersed Cu-doped PtBi nanoalloys towards methanol full electrooxidation journal January 2020
Nickel hydroxide electrocatalysts for alcohol oxidation reactions: An evaluation by infrared spectroscopy and electrochemical methods journal November 1997

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