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Stabilizing Cationic Perylene Dimers through Pancake Bonding and Equal Charge Share

Journal Article · · Crystal Growth and Design
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  1. Department of Chemistry, University at Albany, State University of New York, 1400 Washington Avenue, Albany, New York 12222, United States
  2. Chemistry Department and Institute of Soft Matter, Georgetown University, 37th and O Streets, NW, Washington, D.C. 20057-1227, United States
+ Show Author Affiliations
Not provided.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
OSTI ID:
2423621
Journal Information:
Crystal Growth and Design, Journal Name: Crystal Growth and Design Journal Issue: 10 Vol. 23; ISSN 1528-7483
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (34)

Functionalized Acenes and Heteroacenes for Organic Electronics journal December 2006
Rectifying organic junctions of molecular assemblies based on perylene ion salts journal December 1995
New conducting radical salts based upon Keggin-type polyoxometalates and perylene journal January 2004
Efficient deep-blue and white organic light-emitting diodes based on triphenylsilane-substituted anthracene derivatives journal January 2011
Stable Free Radicals. II. The Reduction of 1-Methyl-4-cyanopyridinium Ion to Methylviologen Cation Radical journal December 1964
The Peierls transition of Perylene radical cation salts with 2:1 stoichiometry containing tetrahydrofuran journal December 1995
Intermolecular Covalent π−π Bonding Interaction Indicated by Bond Distances, Energy Bands, and Magnetism in Biphenalenyl Biradicaloid Molecular Crystal journal February 2007
Thermochromism in an organic crystal based on the coexistence of σ- and π-dimers journal December 2007
Organic/inorganic molecular conductors based upon perylene and Lindquist-type polyoxometalates journal January 2001
A Stable Neutral Hydrocarbon Radical:  Synthesis, Crystal Structure, and Physical Properties of 2,5,8-Tri- tert -butyl-phenalenyl journal February 1999
Low-dimensional molecular metals bis(maleonitriledithiolato)bis(perylene)metal, metal = iron and cobalt journal June 1992
Rotational Barrier in Phenalenyl Neutral Radical Dimer: Separating Pancake and van der Waals Interactions journal April 2014
Parent B2N2‐Perylenes with Different BN Orientations journal September 2021
Synthesis, structure and preliminary results on electrical and magnetic properties of (Perylene)2 [Pt(mnt)2] journal September 1980
Resonating Valence Bond Ground State in Oxygen-Functionalized Phenalenyl-Based Neutral Radical Molecular Conductors journal January 2006
Intermolecular π-to-π Bonding between Stacked Aromatic Dyads. Experimental and Theoretical Binding Energies and Near-IR Optical Transitions for Phenalenyl Radical/Radical versus Radical/Cation Dimerizations journal October 2004
The Solid Solutions (Per)2[PtxAu(1−x)(mnt)2]; Alloying Para- and Diamagnetic Anions in Two-Chain Compounds journal June 2017
Unexpected Charge Effects Strengthen π–Stacking Pancake Bonding journal August 2021
Formation and stabilization of persistent free radicals journal January 2007
Electrocrystallization, crystal structure and physical properties of hexaperylene hexafluorophosphate, (C20H12)6 .+.PF6 − journal December 1994
Pyrene fused perylene diimides: synthesis, characterization and applications in organic field-effect transistors and optical limiting with high performance journal January 2015
Aromaticity on the Pancake-Bonded Dimer of Neutral Phenalenyl Radical as Studied by MS and NMR Spectroscopies and NICS Analysis journal March 2006
Photovoltaic Universal Joints: Ball‐and‐Socket Interfaces in Molecular Photovoltaic Cells journal March 2010
Crystalline structure/transport properties relationship in the (perylene)2M(mnt)2 family M=Au, Pd, Pt, Ni) journal December 1988
Pancake Bonding: An Unusual Pi-Stacking Interaction journal November 2018
Isolation and oxidation-reduction of methylviologen cation radicals. Novel disproportionation in charge-transfer salts by x-ray crystallography journal June 1990
Concave or convex π-dimers: the role of the pancake bond in substituted phenalenyl radical dimers journal January 2015
Electrically conducting metal dithiolate-perylene complexes journal January 1974
The rise of graphene journal March 2007
Pancake Bonding in π-Stacked Trimers in a Salt of Tetrachloroquinone Anion journal May 2018
Exceptionally Long (≥2.9 Å) C−C Bonds between [TCNE]− Ions: Two-Electron, Four-Center π*-π* C−C Bonding in π-[TCNE]22− journal July 2001
Radical Cation Salts of Simple Arenes—A New Family of “Organic Metals” journal November 1980
π-Bonded molecular wires: self-assembly of mixed-valence cation-radical stacks within the nanochannels formed by inert tetrakis[3,5-bis(trifluoromethyl)phenyl]borate anions journal January 2013
Magnetic properties of some electrically conducting perylene-metal dithiolate complexes journal August 1976

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Related Subjects

Chemistry
Crystallography
Materials Science