Solution and Bulk Structures of Asymmetric PEP-PS-PEP′ Triblock Copolymers

Lodge, Timothy P.; Wang, En; Zhu, Jiahao; Bates, Frank S.

doi:10.1021/acs.macromol.3c00931

Solution and Bulk Structures of Asymmetric PEP-PS-PEP′ Triblock Copolymers

Journal Article · 02 August 2023 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.3c00931· OSTI ID:2423618

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Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, United States; Department of Chemical Engineering & Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, United States
Department of Chemical Engineering & Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, United States

Not provided.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2423618

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 16 Vol. 56; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (45)

Epitaxial Transitions among FCC, HCP, BCC, and Cylinder Phases in a Block Copolymer Solution Park, Moon Jeong; Bang, Joona; Harada, Tamotsu Macromolecules, Vol. 37, Issue 24 https://doi.org/10.1021/ma049285g	journal	November 2004
Temperature-dependent micellar structures in poly(styrene-b-isoprene) diblock copolymer solutions near the critical micelle temperature Bang, Joona; Viswanathan, Karthik; Lodge, Timothy P. The Journal of Chemical Physics, Vol. 121, Issue 22 https://doi.org/10.1063/1.1812753	journal	January 2004
Remarkable Effect of Molecular Architecture on Chain Exchange in Triblock Copolymer Micelles Lu, Jie; Bates, Frank S.; Lodge, Timothy P. Macromolecules, Vol. 48, Issue 8 https://doi.org/10.1021/acs.macromol.5b00294	journal	April 2015
Viscoelastic behavior of cubic phases in block copolymer melts Kossuth, M. B.; Morse, D. C.; Bates, F. S. Journal of Rheology, Vol. 43, Issue 1 https://doi.org/10.1122/1.550981	journal	January 1999
Micellization of a polystyrene-block-poly(ethylene/propylene) copolymer in n-alkanes. 2. Structural study Quintana, Jose R.; Villacampa, Manuel; Andrio, Arantza Macromolecules, Vol. 25, Issue 12 https://doi.org/10.1021/ma00038a017	journal	June 1992
Discovery of a Frank-Kasper Phase in Sphere-Forming Block Copolymer Melts Lee, S.; Bluemle, M. J.; Bates, F. S. Science, Vol. 330, Issue 6002 https://doi.org/10.1126/science.1195552	journal	October 2010
Polydispersity effects in poly(isoprene-b-styrene-b-ethylene oxide) triblock terpolymers Meuler, Adam J.; Ellison, Christopher J.; Qin, Jian The Journal of Chemical Physics, Vol. 130, Issue 23 https://doi.org/10.1063/1.3140205	journal	June 2009
σ Phase Formed in Conformationally Asymmetric AB-Type Block Copolymers Xie, Nan; Li, Weihua; Qiu, Feng ACS Macro Letters, Vol. 3, Issue 9 https://doi.org/10.1021/mz500445v	journal	August 2014
Melting of Ordered Arrays and Shape Transitions in Highly Concentrated Diblock Copolymer Solutions McConnell, Glen A.; Gast, Alice P. Macromolecules, Vol. 30, Issue 3 https://doi.org/10.1021/ma961241n	journal	February 1997
Morphology and Thermodynamics of Symmetric Poly(A-block-B-block-C) Triblock Copolymers Stadler, Reimund; Auschra, Clemens; Beckmann, Joerg Macromolecules, Vol. 28, Issue 9 https://doi.org/10.1021/ma00113a010	journal	April 1995
Existence of fcc-Packed Spherical Micelles in Diblock Copolymer Melt Huang, Yen-Yu; Hsu, Jen-Yung; Chen, Hsin-Lung Macromolecules, Vol. 40, Issue 3 https://doi.org/10.1021/ma062149m	journal	February 2007
Superlattice Structures in Morphologies of the ABC Triblock Copolymers Mogi, Yasuhiro; Nomura, Mahito; Kotsuji, Hiroyuki Macromolecules, Vol. 27, Issue 23 https://doi.org/10.1021/ma00101a013	journal	November 1994
Unexpected Consequences of Block Polydispersity on the Self-Assembly of ABA Triblock Copolymers Widin, Joan M.; Schmitt, Adam K.; Schmitt, Andrew L. Journal of the American Chemical Society, Vol. 134, Issue 8 https://doi.org/10.1021/ja210548e	journal	February 2012
The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts Grason, G. Physics Reports, Vol. 433, Issue 1 https://doi.org/10.1016/j.physrep.2006.08.001	journal	October 2006
Chain Exchange Kinetics of Asymmetric B ₁ AB ₂ Linear Triblock and AB ₁ B ₂ Branched Triblock Copolymers Peters, Andrew J.; Lodge, Timothy P. Macromolecules, Vol. 50, Issue 16 https://doi.org/10.1021/acs.macromol.7b01046	journal	August 2017
Chain Architecture and Asymmetry in Copolymer Microphases Milner, Scott T. Macromolecules, Vol. 27, Issue 8 https://doi.org/10.1021/ma00086a057	journal	April 1994
Influence of Polydispersity on the Self-Assembly of Diblock Copolymers Lynd, Nathaniel A.; Hillmyer, Marc A. Macromolecules, Vol. 38, Issue 21 https://doi.org/10.1021/ma051025r	journal	October 2005
Effective interactions in soft condensed matter physics Likos, Christos N. Physics Reports, Vol. 348, Issue 4-5 https://doi.org/10.1016/s0370-1573(00)00141-1	journal	July 2001
Photonic Polyethylene from Self-Assembled Mesophases of Polydisperse Olefin Block Copolymers Hustad, Phillip D.; Marchand, Gary R.; Garcia-Meitin, Eddy I. Macromolecules, Vol. 42, Issue 11 https://doi.org/10.1021/ma9002819	journal	June 2009
Branched Block Copolymers for Tuning of Morphology and Feature Size in Thin Film Nanolithography Minehara, Hiroki; Pitet, Louis M.; Kim, Sangwon Macromolecules, Vol. 49, Issue 6 https://doi.org/10.1021/acs.macromol.5b02649	journal	March 2016
Scattering Form Factor of Block Copolymer Micelles Pedersen, Jan Skov; Gerstenberg, Michael C. Macromolecules, Vol. 29, Issue 4 https://doi.org/10.1021/ma9512115	journal	January 1996
Regularized Positive Exponential Sum (REPES) Program - A Way of Inverting Laplace Transform Data Obtained by Dynamic Light Scattering Jakeš, Jaromír Collection of Czechoslovak Chemical Communications, Vol. 60, Issue 11 https://doi.org/10.1135/cccc19951781	journal	January 1995
Thermoreversible, Epitaxial f c c ↔ b c c Transitions in Block Copolymer Solutions Bang, Joona; Lodge, Timothy P.; Wang, Xiaohui Physical Review Letters, Vol. 89, Issue 21 https://doi.org/10.1103/physrevlett.89.215505	journal	October 2002
A Noncubic Triply Periodic Network Morphology in Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers Bailey, Travis S.; Hardy, Cordell M.; Epps, Thomas H. Macromolecules, Vol. 35, Issue 18 https://doi.org/10.1021/ma011716x	journal	August 2002
Phase Behavior of Styrene−Isoprene Diblock Copolymers in Strongly Selective Solvents Lai, Chiajen; Russel, William B.; Register, Richard A. Macromolecules, Vol. 35, Issue 3 https://doi.org/10.1021/ma011696z	journal	January 2002
Reevaluation of Poly(ethylene- alt -propylene)- block -Polydimethylsiloxane Phase Behavior Uncovers Topological Close-Packing and Epitaxial Quasicrystal Growth Lindsay, Aaron P.; Jayaraman, Ashish; Peterson, Austin J. ACS Nano, Vol. 15, Issue 6 https://doi.org/10.1021/acsnano.1c02420	journal	April 2021
Well-Defined Organic Nanotubes from Multicomponent Bottlebrush Copolymers Huang, Kun; Rzayev, Javid Journal of the American Chemical Society, Vol. 131, Issue 19 https://doi.org/10.1021/ja901936g	journal	May 2009
Stability of the A15 phase in diblock copolymer melts Bates, Morgan W.; Lequieu, Joshua; Barbon, Stephanie M. Proceedings of the National Academy of Sciences, Vol. 116, Issue 27 https://doi.org/10.1073/pnas.1900121116	journal	June 2019
Phase Behavior of a Block Copolymer in Solvents of Varying Selectivity Hanley, Kenneth J.; Lodge, Timothy P.; Huang, Ching-I Macromolecules, Vol. 33, Issue 16 https://doi.org/10.1021/ma000318b	journal	August 2000
Cornucopia of Nanoscale Ordered Phases in Sphere-Forming Tetrablock Terpolymers Chanpuriya, Siddharth; Kim, Kyungtae; Zhang, Jingwen ACS Nano, Vol. 10, Issue 5 https://doi.org/10.1021/acsnano.6b00495	journal	April 2016
Formation of a C15 Laves Phase with a Giant Unit Cell in Salt-Doped A/B/AB Ternary Polymer Blends Xie, Shuyi; Lindsay, Aaron P.; Bates, Frank S. ACS Nano, Vol. 14, Issue 10 https://doi.org/10.1021/acsnano.0c06071	journal	August 2020
Origins of low-symmetry phases in asymmetric diblock copolymer melts Kim, Kyungtae; Arora, Akash; Lewis, Ronald M. Proceedings of the National Academy of Sciences, Vol. 115, Issue 5 https://doi.org/10.1073/pnas.1717850115	journal	January 2018
Effect of Corona Block Length on the Structure and Chain Exchange Kinetics of Block Copolymer Micelles Wang, En; Lu, Jie; Bates, Frank S. Macromolecules, Vol. 51, Issue 10 https://doi.org/10.1021/acs.macromol.7b02732	journal	May 2018
Analysis of Macromolecular Polydispersity in Intensity Correlation Spectroscopy: The Method of Cumulants Koppel, Dennis E. The Journal of Chemical Physics, Vol. 57, Issue 11 https://doi.org/10.1063/1.1678153	journal	December 1972
Scattering from block copolymer micelles Pedersen, Jan Skov; Svaneborg, Carsten Current Opinion in Colloid & Interface Science, Vol. 7, Issue 3-4 https://doi.org/10.1016/S1359-0294(02)00044-4	journal	August 2002
Multiblock Polymers: Panacea or Pandora's Box? Bates, F. S.; Hillmyer, M. A.; Lodge, T. P. Science, Vol. 336, Issue 6080 https://doi.org/10.1126/science.1215368	journal	April 2012
Mechanism of Molecular Exchange in Diblock Copolymer Micelles: Hypersensitivity to Core Chain Length Choi, Soo-Hyung; Lodge, Timothy P.; Bates, Frank S. Physical Review Letters, Vol. 104, Issue 4 https://doi.org/10.1103/physrevlett.104.047802	journal	January 2010
Morphology of miktoarm star block copolymers of styrene and isoprene Tselikas, Y.; Iatrou, H.; Hadjichristidis, N. The Journal of Chemical Physics, Vol. 105, Issue 6 https://doi.org/10.1063/1.472113	journal	August 1996
Complex Phase Behavior in Particle-Forming AB/AB′ Diblock Copolymer Blends with Variable Core Block Lengths Lindsay, Aaron P.; Cheong, Guo Kang; Peterson, Austin J. Macromolecules, Vol. 54, Issue 15 https://doi.org/10.1021/acs.macromol.1c01290	journal	July 2021
50th Anniversary Perspective : Block Polymers—Pure Potential Bates, Christopher M.; Bates, Frank S. Macromolecules, Vol. 50, Issue 1 https://doi.org/10.1021/acs.macromol.6b02355	journal	December 2016
Structure of Poly(styrene- b -ethylene- alt -propylene) Diblock Copolymer Micelles in Squalane ^† Choi, Soo-Hyung; Bates, Frank S.; Lodge, Timothy P. The Journal of Physical Chemistry B, Vol. 113, Issue 42 https://doi.org/10.1021/jp8111149	journal	October 2009
Micellization of a polystyrene-block-poly(ethylene/propylene) copolymer in n-alkanes. 1. Thermodynamic study Quintana, Jose R.; Villacampa, Manuel; Munoz, Marta Macromolecules, Vol. 25, Issue 12 https://doi.org/10.1021/ma00038a016	journal	June 1992
Mechanisms and Epitaxial Relationships between Close-Packed and BCC Lattices in Block Copolymer Solutions Bang, Joona; Lodge, Timothy P. The Journal of Physical Chemistry B, Vol. 107, Issue 44 https://doi.org/10.1021/jp035065d	journal	October 2003
The Full Phase Behavior for Block Copolymers in Solvents of Varying Selectivity Lodge, Timothy P.; Pudil, Bryant; Hanley, Kenneth J. Macromolecules, Vol. 35, Issue 12 https://doi.org/10.1021/ma0200975	journal	June 2002
Tuning Diblock Copolymer Particle Packing Symmetry with Variable Molecular Weight Core-Homopolymers Mueller, Andreas J.; Lindsay, Aaron P.; Jayaraman, Ashish Macromolecules, Vol. 55, Issue 18 https://doi.org/10.1021/acs.macromol.2c01267	journal	September 2022

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