Role of Distance from Equilibrium in the Fragmentation Kinetics of Block Copolymer Micelles

Gupta, Supriya; Liberman, Lucy; Lodge, Timothy P.

doi:10.1021/acs.macromol.3c00580

Role of Distance from Equilibrium in the Fragmentation Kinetics of Block Copolymer Micelles

Journal Article · 23 June 2023 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.3c00580· OSTI ID:2423595

^[1]; Liberman, Lucy ^[1]; ^[2]

Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States
Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States; Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455-0431, United States

Not provided.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2423595

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 13 Vol. 56; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (58)

Measurement of surface and interfacial tension using pendant drop tensiometry Berry, Joseph D.; Neeson, Michael J.; Dagastine, Raymond R. Journal of Colloid and Interface Science, Vol. 454 https://doi.org/10.1016/j.jcis.2015.05.012	journal	September 2015
Determination of size distribution from small-angle scattering data for systems with effective hard-sphere interactions Pedersen, J. S. Journal of Applied Crystallography, Vol. 27, Issue 4 https://doi.org/10.1107/s0021889893013810	journal	August 1994
Adsorption of chain molecules with a polar head a scaling description Alexander, S. Journal de Physique, Vol. 38, Issue 8 https://doi.org/10.1051/jphys:01977003808098300	journal	January 1977
Directly Observing Micelle Fusion and Growth in Solution by Liquid-Cell Transmission Electron Microscopy Parent, Lucas R.; Bakalis, Evangelos; Ramírez-Hernández, Abelardo Journal of the American Chemical Society, Vol. 139, Issue 47 https://doi.org/10.1021/jacs.7b09060	journal	November 2017
1998 E.W.R. Steacie Award Lecture Asymmetric amphiphilic block copolymers in solution: a morphological wonderland Cameron, Neil S.; Corbierre, Muriel K.; Eisenberg, Adi Canadian Journal of Chemistry, Vol. 77, Issue 8 https://doi.org/10.1139/v99-141	journal	August 1999
Self-Assembly of Polymer Grafted Nanoparticles within Spherically Confined Diblock Copolymers Gupta, Supriya; Chokshi, Paresh The Journal of Physical Chemistry B, Vol. 124, Issue 51 https://doi.org/10.1021/acs.jpcb.0c08279	journal	December 2020
Effect of Solvent Selectivity on Chain Exchange Kinetics in Block Copolymer Micelles Wang, En; Zhu, Jiahao; Zhao, Dan Macromolecules, Vol. 53, Issue 1 https://doi.org/10.1021/acs.macromol.9b01877	journal	December 2019
Kinetic Pathway of the Cylinder-to-Sphere Transition in Block Copolymer Micelles Observed in Situ by Time-Resolved Neutron and Synchrotron Scattering Lund, Reidar; Willner, Lutz; Richter, Dieter ACS Macro Letters, Vol. 2, Issue 12 https://doi.org/10.1021/mz400521p	journal	November 2013
Effect of Changing Interfacial Tension on Fragmentation Kinetics of Block Copolymer Micelles Gupta, Supriya; Lodge, Timothy P. Macromolecules, Vol. 56, Issue 5 https://doi.org/10.1021/acs.macromol.2c02158	journal	February 2023
Self-organization of a 4-miktoarm star block copolymer induced by cylindrical confinement Gupta, Supriya; Chokshi, Paresh Soft Matter, Vol. 17, Issue 19 https://doi.org/10.1039/d1sm00149c	journal	January 2021
Remarkable Effect of Molecular Architecture on Chain Exchange in Triblock Copolymer Micelles Lu, Jie; Bates, Frank S.; Lodge, Timothy P. Macromolecules, Vol. 48, Issue 8 https://doi.org/10.1021/acs.macromol.5b00294	journal	April 2015
Time-resolved SANS for the determination of unimer exchange kinetics in block copolymer micelles Willner, L.; Poppe, A.; Allgaier, J. Europhysics Letters (EPL), Vol. 55, Issue 5 https://doi.org/10.1209/epl/i2001-00467-y	journal	September 2001
Block Copolymer Micelles Gohy, Jean-François Block Copolymers II https://doi.org/10.1007/12_048	book	January 2005
Determination of the Rate Constant for Chain Insertion into Poly(methyl methacrylate)- block -poly(methacrylic acid) Micelles by a Fluorescence Method Smith, Carl K.; Liu, Guojun Macromolecules, Vol. 29, Issue 6 https://doi.org/10.1021/ma951338u	journal	January 1996
Direct Observation of Micelle Fragmentation via In Situ Liquid-Phase Transmission Electron Microscopy Early, Julia T.; Yager, Kevin G.; Lodge, Timothy P. ACS Macro Letters, Vol. 9, Issue 5 https://doi.org/10.1021/acsmacrolett.0c00273	journal	May 2020
Functional block copolymer assemblies responsive to tumor and intracellular microenvironments for site-specific drug delivery and enhanced imaging performance Ge, Zhishen; Liu, Shiyong Chemical Society Reviews, Vol. 42, Issue 17 https://doi.org/10.1039/c3cs60048c	journal	January 2013
Detection of the rate of exchange of chains between micelles formed by diblock copolymers in aqueous solution Wang, Yongmei; Balaji, R.; Quirk, Roderic P. Polymer Bulletin, Vol. 28, Issue 3 https://doi.org/10.1007/bf00294831	journal	May 1992
Length of the Core Forming Block Effect on Fusion and Fission Dynamics at Equilibrium in PEO–PPO–PEO Triblock Copolymer Micelles in the Spherical Regime Landazuri, G.; Fernandez, V. V. A.; Soltero, J. F. A. Macromolecules, Vol. 54, Issue 5 https://doi.org/10.1021/acs.macromol.0c01520	journal	February 2021
MATERIALS SCIENCE: Enhancing Drug Function Hubbell, J. A. Science, Vol. 300, Issue 5619 https://doi.org/10.1126/science.1083625	journal	April 2003
Diblock Copolymer Micelles in a Dilute Solution Zhulina, Ekaterina B.; Adam, Mireile; LaRue, Isaac Macromolecules, Vol. 38, Issue 12 https://doi.org/10.1021/ma048102n	journal	June 2005
Tuning of the Exchange Dynamics of Unimers between Block Copolymer Micelles with Temperature, Cosolvents, and Cosurfactants van Stam, Jan; Creutz, Serge; De Schryver, Frans C. Macromolecules, Vol. 33, Issue 17 https://doi.org/10.1021/ma992174a	journal	August 2000
Chain Exchange Kinetics in Diblock Copolymer Micelles in Ionic Liquids: The Role of χ Ma, Yuanchi; Lodge, Timothy P. Macromolecules, Vol. 49, Issue 24 https://doi.org/10.1021/acs.macromol.6b02212	journal	December 2016
Nanopatterned Self‐Assembled Monolayers by Using Diblock Copolymer Micelles as Nanometer‐Scale Adsorption and Etch Masks Krishnamoorthy, Sivashankar; Pugin, Raphael; Brugger, Juergen Advanced Materials, Vol. 20, Issue 10 https://doi.org/10.1002/adma.200702005	journal	May 2008
50th Anniversary Perspective : Functional Nanoparticles from the Solution Self-Assembly of Block Copolymers Tritschler, Ulrich; Pearce, Sam; Gwyther, Jessica Macromolecules, Vol. 50, Issue 9 https://doi.org/10.1021/acs.macromol.6b02767	journal	April 2017
Micellization Kinetics in Block Copolymer Solutions: Scaling Model Dormidontova, Elena E. Macromolecules, Vol. 32, Issue 22 https://doi.org/10.1021/ma9809029	journal	November 1999
Path-Dependent Morphology and Relaxation Kinetics of Highly Amphiphilic Diblock Copolymer Micelles in Ionic Liquids Meli, Luciana; Santiago, Jessica M.; Lodge, Timothy P. Macromolecules, Vol. 43, Issue 4 https://doi.org/10.1021/ma902366c	journal	February 2010
Formation of micelles of diblock and triblock copolymers in a selective solvent Izzo, D.; Marques, C. M. Macromolecules, Vol. 26, Issue 26 https://doi.org/10.1021/ma00078a012	journal	December 1993
Theory of the kinetics of micellar equilibria and quantitative interpretation of chemical relaxation studies of micellar solutions of ionic surfactants Aniansson, E. A. G.; Wall, S. N.; Almgren, M. The Journal of Physical Chemistry, Vol. 80, Issue 9 https://doi.org/10.1021/j100550a001	journal	April 1976
Block copolymer self‐assembly in selective solvents: Spherical micelles with segregated cores Nagarajan, R.; Ganesh, K. The Journal of Chemical Physics, Vol. 90, Issue 10 https://doi.org/10.1063/1.456390	journal	May 1989
Self-Assembly of Block Copolymer Micelles in an Ionic Liquid He, Yiyong; Li, Zhibo; Simone, Peter Journal of the American Chemical Society, Vol. 128, Issue 8 https://doi.org/10.1021/ja058091t	journal	March 2006
Polymeric micelles: a star model Halperin, A. Macromolecules, Vol. 20, Issue 11 https://doi.org/10.1021/ma00177a051	journal	November 1987
Block Copolymers—Designer Soft Materials Bates, Frank S.; Fredrickson, Glenn H. Physics Today, Vol. 52, Issue 2 https://doi.org/10.1063/1.882522	journal	February 1999
Kinetics of step-wise micelle association Aniansson, E. A. G.; Wall, S. N. The Journal of Physical Chemistry, Vol. 78, Issue 10 https://doi.org/10.1021/j100603a016	journal	May 1974
On Micellar Exchange: The Role of the Insertion Penalty Halperin, A. Macromolecules, Vol. 44, Issue 13 https://doi.org/10.1021/ma200811x	journal	July 2011
Molecular Exchange in PEO−PB Micelles in Water Won, You-Yeon; Davis, H. Ted; Bates, Frank S. Macromolecules, Vol. 36, Issue 3 https://doi.org/10.1021/ma021439+	journal	January 2003
Equilibrium Chain Exchange Kinetics of Diblock Copolymer Micelles: Tuning and Logarithmic Relaxation Lund, Reidar; Willner, Lutz; Richter, Dieter Macromolecules, Vol. 39, Issue 13 https://doi.org/10.1021/ma060328y	journal	June 2006
Fluorescence studies of amphiphilic poly(methacrylic acid)-block-polystyrene-block-poly(methacrylic acid) micelles Cao, T.; Munk, P.; Ramireddy, C. Macromolecules, Vol. 24, Issue 23 https://doi.org/10.1021/ma00023a036	journal	November 1991
Self-assembly of block copolymers Mai, Yiyong; Eisenberg, Adi Chemical Society Reviews, Vol. 41, Issue 18 https://doi.org/10.1039/c2cs35115c	journal	January 2012
MATERIALS SCIENCE: A Unique Platform for Materials Design Lodge, T. P. Science, Vol. 321, Issue 5885 https://doi.org/10.1126/science.1159652	journal	July 2008
Exchange Kinetics for a Single Block Copolymer in Micelles of Two Different Sizes Zhao, Dan; Ma, Yuanchi; Lodge, Timothy P. Macromolecules, Vol. 51, Issue 6 https://doi.org/10.1021/acs.macromol.7b02550	journal	March 2018
Molecular Weight Dependence of Block Copolymer Micelle Fragmentation Kinetics Early, Julia T.; Block, Alison; Yager, Kevin G. Journal of the American Chemical Society, Vol. 143, Issue 20 https://doi.org/10.1021/jacs.1c02147	journal	May 2021
Mechanism of Molecular Exchange in Diblock Copolymer Micelles: Hypersensitivity to Core Chain Length Choi, Soo-Hyung; Lodge, Timothy P.; Bates, Frank S. Physical Review Letters, Vol. 104, Issue 4 https://doi.org/10.1103/physrevlett.104.047802	journal	January 2010
Tethered chains in polymer microstructures Halperin, A.; Tirrell, M.; Lodge, T. P. Macromolecules: Synthesis, Order and Advanced Properties https://doi.org/10.1007/BFb0051635	book	January 2006
Preparation and characterization of a star-shaped polystyrene-b-poly(ethylene-co-propylene) block copolymer as a viscosity index improver of lubricant Wang, Tseng-Yeong; Tsiang, Raymond Chien-Chao; Liou, Jin-Shang Journal of Applied Polymer Science, Vol. 79, Issue 10 https://doi.org/10.1002/1097-4628(20010307)79:10<1838::aid-app120>3.0.co;2-h	journal	January 2001
Equilibrium vs Metastability: High-Temperature Annealing of Spherical Block Copolymer Micelles in an Ionic Liquid Meli, Luciana; Lodge, Timothy P. Macromolecules, Vol. 42, Issue 3 https://doi.org/10.1021/ma802020a	journal	February 2009
Fusion and Fragmentation Dynamics at Equilibrium in Triblock Copolymer Micelles Rharbi, Y. Macromolecules, Vol. 45, Issue 24 https://doi.org/10.1021/ma3018298	journal	December 2012
Polymeric Nanostructures for Imaging and Therapy Elsabahy, Mahmoud; Heo, Gyu Seong; Lim, Soon-Mi Chemical Reviews, Vol. 115, Issue 19 https://doi.org/10.1021/acs.chemrev.5b00135	journal	April 2015
Fragmentation of 1,2-Polybutadiene- block -Poly(ethylene oxide) Micelles in Imidazolium-Based Ionic Liquids Early, Julia T.; Lodge, Timothy P. Macromolecules, Vol. 52, Issue 18 https://doi.org/10.1021/acs.macromol.9b01530	journal	August 2019
Modern Room Temperature Ionic Liquids, a Simple Guide to Understanding Their Structure and How It May Relate to Dynamics Araque, Juan C.; Hettige, Jeevapani J.; Margulis, Claudio J. The Journal of Physical Chemistry B, Vol. 119, Issue 40 https://doi.org/10.1021/acs.jpcb.5b05506	journal	August 2015
Block Copolymers: Long-Term Growth with Added Value Lodge, Timothy P. Macromolecules, Vol. 53, Issue 1 https://doi.org/10.1021/acs.macromol.9b02069	journal	January 2020
Rayleigh Instability Induced Cylinder-to-Sphere Transition in Block Copolymer Micelles: Direct Visualization of the Kinetic Pathway Wang, Lulu; Huang, Haiying; He, Tianbai ACS Macro Letters, Vol. 3, Issue 5 https://doi.org/10.1021/mz500158f	journal	April 2014
Theory of block copolymer micelles in solution Noolandi, Jaan; Hong, Kin Ming Macromolecules, Vol. 16, Issue 9 https://doi.org/10.1021/ma00243a007	journal	September 1983
Free Energy Trajectory for Escape of a Single Chain from a Diblock Copolymer Micelle Seeger, Sarah C.; Dorfman, Kevin D.; Lodge, Timothy P. ACS Macro Letters, Vol. 10, Issue 12 https://doi.org/10.1021/acsmacrolett.1c00508	journal	November 2021
Scaling theory of polymer adsorption De Gennes, P. G. Journal de Physique, Vol. 37, Issue 12 https://doi.org/10.1051/jphys:0197600370120144500	journal	January 1976
Dynamics and Equilibration Mechanisms in Block Copolymer Particles Lodge, Timothy P.; Seitzinger, Claire L.; Seeger, Sarah C. ACS Polymers Au, Vol. 2, Issue 6 https://doi.org/10.1021/acspolymersau.2c00033	journal	August 2022
Role of Interfacial Tension for the Structure of PEP−PEO Polymeric Micelles. A Combined SANS and Pendant Drop Tensiometry Investigation Lund, Reidar; Willner, Lutz; Stellbrink, Jörg Macromolecules, Vol. 37, Issue 26 https://doi.org/10.1021/ma035633n	journal	December 2004
Stable and unstable phases of a diblock copolymer melt Matsen, M. W.; Schick, M. Physical Review Letters, Vol. 72, Issue 16 https://doi.org/10.1103/physrevlett.72.2660	journal	April 1994
Polymeric micelles: their relaxation kinetics Halperin, A.; Alexander, S. Macromolecules, Vol. 22, Issue 5 https://doi.org/10.1021/ma00195a069	journal	September 1989

Similar Records

Fragmentation Kinetics of Block Copolymer Micelles: Effect of Core and Corona Block Lengths

Journal Article · 2024 · Macromolecules · OSTI ID:2581580

Molecular Weight Dependence of Block Copolymer Micelle Fragmentation Kinetics

Journal Article · 2021 · J. Am. Chem. Soc. · OSTI ID:1812084

Molecular Weight Dependence of Block Copolymer Micelle Fragmentation Kinetics

Journal Article · 2021 · J. Am. Chem. Soc. · OSTI ID:1798362

Related Subjects

Polymer Science

Role of Distance from Equilibrium in the Fragmentation Kinetics of Block Copolymer Micelles

Citation Formats

References (58)

Similar Records

Related Subjects