Role of cobalt phthalocyanine on the formation of high-valent cobalt species revealed by in situ Raman spectroscopy

Jia, Jinzhi; Zhao, Xiaohua; Hu, Wenhui; Wang, Yantao; Huang, Junfeng; Huang, Jier; Li, Hua; Peng, Yong; Ma, Haiyan; Xu, Cailing

doi:10.1039/d2ta10063k

Role of cobalt phthalocyanine on the formation of high-valent cobalt species revealed by in situ Raman spectroscopy

Journal Article · 31 December 2022 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/d2ta10063k· OSTI ID:2423594

Jia, Jinzhi ^[1]; Zhao, Xiaohua ^[2]; Hu, Wenhui ^[3]; Wang, Yantao ^[1]; Huang, Junfeng ^[1]; ^[3]; Li, Hua ^[1]; ^[1]; Ma, Haiyan ^[1]; ^[1]

State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, College of Earth and Environmental Sciences, School of Materials and Energy, Lanzhou University, Lanzhou 730000, China
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, College of Earth and Environmental Sciences, School of Materials and Energy, Lanzhou University, Lanzhou 730000, China; School of Chemical Engineering, Lanzhou University of Arts and Sciences, Lanzhou 730000, China
Department of Chemistry, Marquette University, Milwaukee, Wisconsin 53201, USA

In situRaman spectroscopy reveals that CoPc facilitates the formation of disordered-CoOOH and high-valence-CoO₂, endowing Co-MOF-74@CoPc with outstanding OER performance.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2423594

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 15 Vol. 11; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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