Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Phase Evolution and Crystallization Mechanism of Glass Ceramic Solid-State Electrolyte from In Situ Synchrotron X-ray Diffraction

Journal Article · · Journal of Physical Chemistry. C
 [1];  [1];  [1];  [1]
  1. Department of Materials Science and Engineering, University of North Texas, Denton, Texas 76203, United States

Not provided.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
OSTI ID:
2423553
Journal Information:
Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 34 Vol. 127; ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (84)

Recent Advancements in Li-Ion Conductors for All-Solid-State Li-Ion Batteries journal November 2017
Ceramic-glass pellet thickness and Li diffusion in NASICON-type LAGP (Li1.5Al0.5Ge1.5(PO4)3) studied by pulsed field gradient NMR spectroscopy journal July 2022
Water-stable lithium ion conducting solid electrolyte of iron and aluminum doped NASICON-type LiTi2(PO4)3 journal October 2014
Atomistic analysis of Li migration in Li1+AlTi2−(PO4)3 (LATP) solid electrolytes journal January 2021
Structure and thermal expansion of LiGe2(PO4)3 journal February 1991
The Gibbs Equation versus the Kelvin and the Gibbs-Thomson Equations to Describe Nucleation and Equilibrium of Nano-Materials journal March 2012
Recent Advances in Inorganic Solid Electrolytes for Lithium Batteries journal June 2014
Relationship between Activation Energy and Bottleneck Size for Li + Ion Conduction in NASICON Materials of Composition LiMM‘(PO 4 ) 3 ; M, M‘ = Ge, Ti, Sn, Hf journal January 1998
Crystallisation in oxide glasses – a tutorial review journal January 2014
Preparation, Structural Characterization, and Electrical Conductivity of Highly Ion-Conducting Glasses and Glass Ceramics in the System Li 1+ x Al x Sn y Ge 2-(x+y) (PO 4 ) 3 journal June 2016
Influence of lithium oxide excess and alumina on grain boundary resistance of Li6.75La3Zr1.75Nb0.25O12 solid electrolyte journal January 2017
Progress and Perspectives of Lithium Aluminum Germanium Phosphate‐Based Solid Electrolytes for Lithium Batteries journal April 2023
Low temperature performance of sodium–nickel chloride batteries with NaSICON solid electrolyte journal December 2015
Lithium Ion-Conducting Glass?Ceramics of Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 ?xLi 2 O (x=0.0?0.20) with Good Electrical and Electrochemical Properties journal September 2007
Challenges in the development of advanced Li-ion batteries: a review journal January 2011
On the estimation of average crystallite size of zeolites from the Scherrer equation: A critical evaluation of its application to zeolites with one-dimensional pore systems journal January 2009
Improved lithium-ion transport in NASICON-type lithium titanium phosphate by calcium and iron doping journal September 2014
Cost Projection of State of the Art Lithium-Ion Batteries for Electric Vehicles Up to 2030 journal September 2017
Estimation of lattice strain for zirconia nano-particles based on Williamson- Hall analysis journal June 2017
Effect of bottleneck size on lithium migration in lithium garnets Li7La3Zr2O12 (LLZO) journal May 2020
Flash sintering with concurrent crystallization of Li1.5Al0.5Ge1.5(PO4)3 glass journal January 2023
Issue and challenges facing rechargeable thin film lithium batteries journal August 2008
Crystallization behavior of Li1+xAlxGe2-x(PO4)3 glass-ceramics: Effect of composition and thermal treatment journal December 2019
On the sinterability of crystallizing glass powders journal October 2008
Size–strain study of NiO nanoparticles by X-ray powder diffraction line broadening journal April 2012
The role of Al+3 on the microstructural and electrical properties of Na1+Al Ti2-(PO4)3 NASICON glass-ceramics journal April 2020
Superionic Conductivity in a Lithium Aluminum Germanium Phosphate Glass–Ceramic journal January 2008
Enhanced lithium-ion conductivity in a LiZr 2 (PO 4 ) 3 solid electrolyte by Al doping journal August 2017
Isothermal evolution of phase composition, structural parameters, and ionic conductivity in Na1+Al Ge2-(PO4)3 glass-ceramics journal April 2020
Isothermal sintering with concurrent crystallization of polydispersed soda–lime–silica glass beads journal December 2003
The effects of crystallization parameters on the ionic conductivity of a lithium aluminum germanium phosphate glass–ceramic journal May 2010
An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na 3 MnTi(PO 4 ) 3 journal September 2016
Determination of crystallization kinetics parameters of a Li1.5Al0.5Ge1.5(PO4)3 (LAGP) glass by differential scanning calorimetry journal April 2013
Lithium batteries: Status, prospects and future journal May 2010
Comparative study of lithium ion conductors in the system Li1+xAlxA2−xIV (PO4)3 with AIV=Ti or Ge and 0≤x≤0·7 for use as Li+ sensitive membranes journal December 1999
Computational and Experimental Investigation of the Electrochemical Stability and Li-Ion Conduction Mechanism of LiZr 2 (PO 4 ) 3 journal October 2017
Improving the ionic conductivity of NASICON through aliovalent cation substitution of Na3Zr2Si2PO12 journal July 2015
Structural evolution of NASICON-type Li 1+x Al x Ge 2−x (PO 4 ) 3 using in situ synchrotron X-ray powder diffraction journal January 2016
High lithium ion conductivity solid electrolyte of chromium and aluminum co-doped NASICON-type LiTi2(PO4)3 journal April 2015
Mastering the interface for advanced all-solid-state lithium rechargeable batteries journal November 2016
Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system journal January 2013
Correlating Transport and Structural Properties in Li 1+ x Al x Ge 2– x (PO 4 ) 3 (LAGP) Prepared from Aqueous Solution journal March 2018
Kinetic study of crystallization of glass by differential thermal analysis—criterion on application of Kissinger plot journal May 1980
Lithium ion conductors in the system AB(IV)2(PO4)3 (B = Ti, Zr and Hf) journal January 1986
Correlation between micro-structural properties and ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3 ceramics journal August 2011
Sol–gel synthesis and room-temperature properties of α-LiZr2(PO4)3 journal January 2015
Lithium and potassium ion conduction in A3TiB′P3O12 (A=Li, K; B′=Zn, Cd) NASICON-type glasses journal February 2005
Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte journal August 2015
Lithium Ion Diffusion Mechanism and Associated Defect Behaviors in Crystalline Li 1+ x Al x Ge 2– x (PO 4 ) 3 Solid-State Electrolytes journal October 2019
Modeling Ti/Ge Distribution in LiTi 2– x Ge x (PO 4 ) 3 NASICON Series by 31 P MAS NMR and First-Principles DFT Calculations journal July 2016
Thin-film lithium and lithium-ion batteries journal November 2000
Stress changes in chemical vapor deposition tungsten silicide (polycide) film measured by x-ray diffraction journal May 2002
Gibbs?Thomson effects in phase transformations journal April 2005
High Li+ conduction in NASICON-type Li1+xYxZr2−x(PO4)3 at room temperature journal October 2013
High lithium ion conducting solid electrolytes based on NASICON Li 1+x Al x M 2−x (PO 4 ) 3 materials (M = Ti, Ge and 0 ≤ x ≤ 0.5) journal May 2015
Recent Advances in Energy Chemistry between Solid-State Electrolyte and Safe Lithium-Metal Anodes journal January 2019
Ionic conductivity enhancement in LiGe2(PO4)3 solid electrolyte journal October 1997
Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries journal January 2017
Lithium ion-conducting glass-ceramics in the system Li2O–TiO2–P2O5–Cr2O3–SiO2 journal February 2015
Influence of crystallization temperature on ionic conductivity of lithium aluminum germanium phosphate glass-ceramic journal September 2015
On the influence of the cation vacancy on lithium conductivity of Li1+xRxTi2−x(PO4)3 Nasicon type materials journal March 2015
NASICON-type Li1+2xZr2−xCax(PO4)3 with high ionic conductivity at room temperature journal January 2011
Sintering dense nanocrystalline ceramics without final-stage grain growth journal March 2000
A lithium superionic conductor journal July 2011
Glass-to-Crystal Transition in Li 1+ x Al x Ge 2– x (PO 4 ) 3 : Structural Aspects Studied by Solid State NMR journal April 2014
Lithium Exchange Processes in the Conduction Network of the Nasicon LiTi 2 - x Zr x (PO 4 ) 3 Series (0 ≤ x ≤ 2) journal April 2006
Photocatalytic activity of glass ceramics containing Nasicon-type crystals journal January 2013
Composite effect in superionically conducting lithium aluminium germanium phosphate based glass-ceramic journal October 2008
The applicability of Johnson-Mehl-Avrami model in the thermal analysis of the crystallization kinetics of glasses journal December 1995
Structure and lithium‐ion mobility in Li 1.5 M 0.5 Ge 1.5 (PO 4 ) 3 (M = Ga, Sc, Y) NASICON glass‐ceramics
  • d'Anciães Almeida Silva, Igor; Nieto‐Muñoz, Adriana M.; Rodrigues, Ana Candida M.
  • Journal of the American Ceramic Society, Vol. 103, Issue 7 https://doi.org/10.1111/jace.16998
journal January 2020
Fast Li+ Ion Conduction in Li2O-Al2O3-TiO2-SiO2-P2O2 Glass-Ceramics journal July 1997
Designing All-Solid-State Batteries by Theoretical Computation: A Review journal February 2023
Fast Na+-ion transport in skeleton structures journal February 1976
Lithium-Ion Trapping from Local Structural Distortions in Sodium Super Ionic Conductor (NASICON) Electrolytes journal August 2014
Crystal structures and crystal chemistry in the system Na1+xZr2SixP3−xO12 journal February 1976
Lithium−Air Battery: Promise and Challenges journal June 2010
Controlled crystallization and ionic conductivity of a nanostructured LiAlGePO4 glass–ceramic journal November 2009
A systematic study of annealing environment and Al dopant effect on NASICON-type LiZr2(PO4)3 solid electrolyte journal June 2020
Li-ion batteries: basics, progress, and challenges journal September 2015
New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries journal January 2004
The gibbs-thomson effect in dilute binary systems journal April 2002
Structure of crystalline and amorphous materials in the NASICON system Na1+xAlxGe2−x(PO4)3 journal August 2021
Improving the ionic conductivity of Li1+Al Ge2-(PO4)3 solid electrolyte for all-solid-state batteries using microstructural modifiers journal October 2020
Structural Factors That Enhance Lithium Mobility in Fast-Ion Li 1+ x Ti 2– x Al x (PO 4 ) 3 (0 ≤ x ≤ 0.4) Conductors Investigated by Neutron Diffraction in the Temperature Range 100–500 K journal August 2013

Similar Records

Nanophase evolution at semiconductor/electrolyte interface in situ probed by time-resolved high-energy synchrotron x-ray diffraction.
Journal Article · 2010 · Nano Lett. · OSTI ID:1018497

In Situ Synchrotron X-Ray Diffraction Studies of Lithium Oxygen Batteries
Journal Article · 2013 · Journal of Materials Chemistry A · OSTI ID:1086459

High-Energy Synchrotron X-ray Diffraction for In Situ Study of Phase Transformation in Shape-Memory Alloys
Journal Article · 2011 · JOM : the journal of the Minerals, Metals & Materials Society · OSTI ID:1090188