Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Electrochemical Reduction of N 2 O with a Molecular Copper Catalyst

Journal Article · · ACS Catalysis

Not provided.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
OSTI ID:
2423408
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 19 Vol. 13; ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (62)

Impact of Electronic and Steric Changes of Ligands on the Assembly, Stability, and Redox Activity of Cu 44 -S) Model Compounds of the Cu Z Active Site of Nitrous Oxide Reductase (N 2 OR) journal April 2020
Mechanism of N 2 O Reduction by the μ 4 -S Tetranuclear Cu Z Cluster of Nitrous Oxide Reductase journal January 2006
A Structurally Characterized Nitrous Oxide Complex of Vanadium journal February 2011
Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex journal April 2017
Imidazole for Pyridine Substitution Leads to Enhanced Activity Under Milder Conditions in Cobalt Water Oxidation Electrocatalysis journal December 2018
Spectroscopic Definition of the Cu Z ° Intermediate in Turnover of Nitrous Oxide Reductase and Molecular Insight into the Catalytic Mechanism journal March 2017
N2O Reduction by theμ4-Sulfide-Bridged Tetranuclear CuZ Cluster Active Site journal August 2004
N2O binding at a [4Cu:2S] copper–sulphur cluster in nitrous oxide reductase journal August 2011
A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms journal January 2017
Metalloenzymes of the denitrification pathway journal December 2006
Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction journal January 2018
A One-Hole Cu 4 S Cluster with N 2 O Reductase Activity: A Structural and Functional Model for Cu Z * journal September 2016
Tetrahedral vs Octahedral Zinc Complexes with Ligands of Biological Interest:  A DFT/CDM Study journal November 2000
Coordination chemistry of the CuZ site in nitrous oxide reductase and its synthetic mimics journal February 2021
Binding and Activation of N 2 O at Transition-Metal Centers: Recent Mechanistic Insights journal February 2010
Side‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel journal February 2021
Cyclic Voltammetric Evaluation of Rate Constants for Conformational Transitions Accompanying Electron Transfer. Effect of Varying Structural Constraints in Copper(II/I) Complexes with Dicyclohexanediyl-Substituted Macrocyclic Tetrathiaethers journal September 1997
Co-designing Electrocatalytic Systems with Separations To Improve the Sustainability of Reactive Nitrogen Management journal April 2023
Electrocatalysis of nitrous oxide reduction journal July 1981
A Cu 4 S model for the nitrous oxide reductase active sites supported only by nitrogen ligands journal January 2015
Assembly, Structure, and Reactivity of Cu 4 S and Cu 3 S Models for the Nitrous Oxide Reductase Active Site, Cu Z * journal September 2014
Homogeneous molecular catalysis of the electrochemical reduction of N2O to N2: redox vs. chemical catalysis journal January 2021
Explosion behaviors of hydrogen-nitrous oxide mixtures at reduced initial pressures journal September 2021
Mitigating release of the potent greenhouse gas N2O from the nitrogen cycle – could enzymic regulation hold the key? journal July 2009
Phosphorylation of 1-alkylmidazoles and 1-alkylbenzimidazoles with phosphorus(III) halides in the presence of bases journal January 1999
Nature’s way of handling a greenhouse gas: the copper-sulfur cluster of purple nitrous oxide reductase journal October 2012
N 2 O Reductase Activity of a [Cu 4 S] Cluster in the 4Cu I Redox State Modulated by Hydrogen Bond Donors and Proton Relays in the Secondary Coordination Sphere journal November 2019
Nitrous oxide reductase journal January 2013
Isolation of a stable pyridine radical anion journal January 2019
Electrocatalytic reduction of nitrous oxide to dinitrogen at a mercury electrode using niii complexes of macrocyclic polyamines journal January 1990
Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water journal June 2011
Formation and reactions of [(NH3)5RuN2O2+] journal November 1969
A Comparison of the Contribution of Various Gases to the Greenhouse Effect journal June 1990
A Stable Crystalline Copper(I)-N 2 O Complex Stabilized as the Salt of a Weakly Coordinating Anion journal August 2018
Rhodium(I) Pincer Complexes of Nitrous Oxide journal September 2019
Side-On Coordination of Nitrous Oxide to a Mononuclear Cobalt Center journal September 2019
Biological sources and sinks of nitrous oxide and strategies to mitigate emissions
  • Thomson, Andrew J.; Giannopoulos, Georgios; Pretty, Jules
  • Philosophical Transactions of the Royal Society B: Biological Sciences, Vol. 367, Issue 1593 https://doi.org/10.1098/rstb.2011.0415
journal May 2012
Non-CO2 greenhouse gases and climate change journal August 2011
High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes journal March 2010
Explosion characteristics of H2/N2O and CH4/N2O diluted with N2 journal January 2020
Importance of Ligand Exchange in the Modulation of Molecular Catalysis: Mechanism of the Electrochemical Reduction of Nitrous Oxide with Rhenium Bipyridyl Carbonyl Complexes journal June 2023
Effective Homogeneous Catalysis of Electrochemical Reduction of Nitrous Oxide to Dinitrogen at Rhenium Carbonyl Catalysts journal May 2021
Interaction of palladium( II ) acetate with substituted pyridines, including a cyclometallation reaction and the structure of [Pd{meso-[(py)PhMeC] 2 C 5 H 3 N}(O 2 CMe)][O 2 CMe]·3H 2 O journal January 1986
Metal–Ligand Cooperativity via Exchange Coupling Promotes Iron- Catalyzed Electrochemical CO 2 Reduction at Low Overpotentials journal November 2020
Determination of the Active Form of the Tetranuclear Copper Sulfur Cluster in Nitrous Oxide Reductase journal January 2014
Matrix isolation infrared spectroscopic and theoretical study of the copper (I) and silver (I)–nitrous oxide complexes journal March 2006
Recent advances in cooperative activation of CO2 and N2O by bimetallic coordination complexes or binuclear reaction pathways journal January 2022
Reduction of Nitrogen Oxides by Hydrogen with Rhodium(I)–Platinum(II) Olefin Complexes as Catalysts journal October 2021
Synthetic chemistry with nitrous oxide journal January 2015
A novel type of catalytic copper cluster in nitrous oxide reductase journal March 2000
Interpretation of the Data on the Thermal Decomposition of Nitrous Oxide journal June 1951
Spectroscopic Properties and Electronic Structure of Pentammineruthenium(II) Dinitrogen Oxide and Corresponding Nitrosyl Complexes:  Binding Mode of N 2 O and Reactivity journal November 2004
Nitrous Oxide (N2O): The Dominant Ozone-Depleting Substance Emitted in the 21st Century journal August 2009
A Periodic Walk:  A Series of First-Row Transition Metal Complexes with the Pentadentate Ligand PY5 journal September 2002
The coordination chemistry of acyclic pentadentate pentaamine ligands journal March 2019
Catalytic Nitrous Oxide Reduction with H2 Mediated by Pincer Ir Complexes journal November 2022
Slow Magnetic Relaxation and Charge-Transfer in Cyano-Bridged Coordination Clusters Incorporating [Re(CN) 7 ] 3−/4− journal October 2010
Cobalt Tetraphenylporphine Electrocatalyzed N2O Reduction in DMF Solution journal October 1998
Electrochemical reduction of nitrous oxide (N2O) catalysed by tetraaminophthalocyanatocobalt(II) adsorbed on a graphite electrode in aqueous solution journal October 1997
Reduction of Nitrous Oxide by Light Alcohols Catalysed by a Low‐Valent Ruthenium Diazadiene Complex journal March 2023
Molecular Catalysis of Electrochemical Reactions: Competition between Reduction of the Substrate and Deactivation of the Catalyst by a Cosubstrate Application to N2O Reduction journal October 2021
Probing the electronic and mechanistic roles of the μ4-sulfur atom in a synthetic CuZ model system journal January 2020

Similar Records

Electrochemical Reductive N-Methylation with CO 2 Enabled by a Molecular Catalyst
Journal Article · 2021 · Journal of the American Chemical Society · OSTI ID:1978450

Recent progress in electrochemical reduction of CO2 by oxide-derived copper catalysts
Journal Article · 2020 · Materials Today Nano · OSTI ID:1769146

Related Subjects