Effect of Chain Architecture on the Structure, Dynamics, and Rheology of Thermoresponsive Poloxamer Hydrogels and Associated Blends

White, Joanna M.; Crabtree, Adelyn A.; Bates, Frank S.; Calabrese, Michelle A.

doi:10.1021/acs.macromol.3c01107

Effect of Chain Architecture on the Structure, Dynamics, and Rheology of Thermoresponsive Poloxamer Hydrogels and Associated Blends

Journal Article · 23 August 2023 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.3c01107· OSTI ID:2423400

^[1]; Crabtree, Adelyn A. ^[1]; ^[1]; ^[1]

Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Ave. SE, Minneapolis, Minnesota 55455, United States

Not provided.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2423400

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 17 Vol. 56; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (97)

Cooperative association of diblock and triblock copolymers in aqueous solution. A study of mixed micelles of block-copoly(oxyethylene/oxybutylene) and block-copoly(oxybutylene/oxyethylene/oxybutylene) Yang, Zhuo; Yang, Yung-Wei; Zhou, Zu-Kang Journal of the Chemical Society, Faraday Transactions, Vol. 92, Issue 2 https://doi.org/10.1039/ft9969200257	journal	January 1996
Continuous transition of colloidal crystals through stable random orders Ahn, Juhong; Chen, Liwen; Underhill, Patrick T. Soft Matter, Vol. 19, Issue 18 https://doi.org/10.1039/d3sm00199g	journal	January 2023
A Monte Carlo simulation for the micellization of ABA- and BAB-type triblock copolymers in a selective solvent. II. Effects of the block composition Kim, Seung Hyun; Jo, Won Ho The Journal of Chemical Physics, Vol. 117, Issue 18 https://doi.org/10.1063/1.1512646	journal	November 2002
Development and characterisation of modified poloxamer 407 thermoresponsive depot systems containing cubosomes Kojarunchitt, Thunjiradasiree; Hook, Sarah; Rizwan, Shakila International Journal of Pharmaceutics, Vol. 408, Issue 1-2 https://doi.org/10.1016/j.ijpharm.2011.01.037	journal	April 2011
Superlattice Formation in Binary Mixtures of Block Copolymer Micelles Abbas, Sayeed; Lodge, Timothy P. Langmuir, Vol. 24, Issue 12 https://doi.org/10.1021/la8002367	journal	May 2008
Structure and Rheology of Self-Assembled Telechelic Associative Polymers in Aqueous Solution before and after Photo-Cross-Linking Kadam, Vijay; Nicolai, Taco; Nicol, Erwan Macromolecules, Vol. 44, Issue 20 https://doi.org/10.1021/ma201097s	journal	September 2011
Dynamics of Micelles of Poly(ethylene oxide)−Poly(propylene oxide)−Poly(ethylene oxide) Block Copolymers in Aqueous Solutions Michels, Bernard; Waton, Gilles; Zana, Raoul Langmuir, Vol. 13, Issue 12 https://doi.org/10.1021/la962084o	journal	June 1997
Tuning the thermodynamic, optical, and rheological properties of thermoresponsive polymer solutions via silica nanoparticle shape and concentration Neal, Christopher A. P.; León, Valeria; Quan, Michelle C. Journal of Colloid and Interface Science, Vol. 629 https://doi.org/10.1016/j.jcis.2022.08.139	journal	January 2023
Superlattice Formation in a Binary Mixture of Block Copolymer Micelles Abbas, Sayeed; Lodge, Timothy P. Physical Review Letters, Vol. 97, Issue 9 https://doi.org/10.1103/physrevlett.97.097803	journal	August 2006
Phase Behavior of Poly(propylene oxide)-Poly(ethylene oxide)-Poly(propylene oxide) Triblock Copolymer Melt and Aqueous Solutions Mortensen, Kell; Brown, Wyn; Joergensen, Erling Macromolecules, Vol. 27, Issue 20 https://doi.org/10.1021/ma00098a020	journal	September 1994
Ordered phases of diblock copolymers in selective solvent Grason, Gregory M. The Journal of Chemical Physics, Vol. 126, Issue 11 https://doi.org/10.1063/1.2709646	journal	March 2007
Remarkable Effect of Molecular Architecture on Chain Exchange in Triblock Copolymer Micelles Lu, Jie; Bates, Frank S.; Lodge, Timothy P. Macromolecules, Vol. 48, Issue 8 https://doi.org/10.1021/acs.macromol.5b00294	journal	April 2015
Pre‐clinical and clinical applications of thermoreversible hydrogels in biomedical engineering: a review Constantinou, Anna P.; Georgiou, Theoni K. Polymer International, Vol. 70, Issue 10 https://doi.org/10.1002/pi.6266	journal	June 2021
Micellization of Binary Diblock Co-polymer Mixtures in an Ionic Liquid Zhao, Dan; Ma, Yuanchi; Wang, En Macromolecules, Vol. 52, Issue 12 https://doi.org/10.1021/acs.macromol.9b00613	journal	June 2019
Treatment of otitis media by transtympanic delivery of antibiotics Yang, Rong; Sabharwal, Vishakha; Okonkwo, Obiajulu S. Science Translational Medicine, Vol. 8, Issue 356 https://doi.org/10.1126/scitranslmed.aaf4363	journal	September 2016
Dual-functional transdermal drug delivery system with controllable drug loading based on thermosensitive poloxamer hydrogel for atopic dermatitis treatment Wang, Wenyi; Wat, Elaine; Hui, Patrick C. L. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep24112	journal	April 2016
Impact of small molecule and reverse poloxamer addition on the micellization and gelation mechanisms of poloxamer hydrogels White, Joanna M.; Calabrese, Michelle A. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 638 https://doi.org/10.1016/j.colsurfa.2021.128246	journal	April 2022
Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions Wanka, G.; Hoffmann, H.; Ulbricht, W. Macromolecules, Vol. 27, Issue 15 https://doi.org/10.1021/ma00093a016	journal	July 1994
Formation of homogeneous gel-like phases by mixed triblock copolymer micelles in aqueous solution: FCC to BCC phase transition Liu, T.; Chu, B. Journal of Applied Crystallography, Vol. 33, Issue 3 https://doi.org/10.1107/s0021889899013369	journal	June 2000
Gelation and long-time relaxation of aqueous solutions of Pluronic F127 Hopkins, Cameron C.; de Bruyn, John R. Journal of Rheology, Vol. 63, Issue 1 https://doi.org/10.1122/1.5054598	journal	January 2019
Complex Self-Assembly of Reverse Poly(butylene oxide)-Poly(ethylene oxide)-Poly(butylene oxide) Triblock Copolymers with Long Hydrophobic and Extremely Lengthy Hydrophilic Blocks Cambón, Adriana; Figueroa-Ochoa, Edgar; Juárez, Josué The Journal of Physical Chemistry B, Vol. 118, Issue 19 https://doi.org/10.1021/jp500426k	journal	May 2014
Effect of Molecular Architecture and Symmetry on Self-Assembly: A Quantitative Revisit Using Discrete ABA Triblock Copolymers Cai, Dong; Li, Jinbin; Ma, Zhuang ACS Macro Letters, Vol. 11, Issue 4 https://doi.org/10.1021/acsmacrolett.1c00788	journal	April 2022
Disorder-order transitions in soft sphere polymer micelles McConnell, Glen A.; Gast, Alice P.; Huang, John S. Physical Review Letters, Vol. 71, Issue 13 https://doi.org/10.1103/physrevlett.71.2102	journal	September 1993
Encapsulation of Hydrophobic Drugs in Pluronic F127 Micelles: Effects of Drug Hydrophobicity, Solution Temperature, and pH Basak, Rajib; Bandyopadhyay, Ranjini Langmuir, Vol. 29, Issue 13 https://doi.org/10.1021/la304836e	journal	February 2013
Phase Behaviour of Poly(ethylene oxide)-Poly(propylene oxide)-Poly(ethylene oxide) Triblock-Copolymer Dissolved in Water Mortensen, K. Europhysics Letters (EPL), Vol. 19, Issue 7 https://doi.org/10.1209/0295-5075/19/7/006	journal	August 1992
Yield stress fluids and ageing Joshi, Yogesh M.; Petekidis, George Rheologica Acta, Vol. 57, Issue 6-7 https://doi.org/10.1007/s00397-018-1096-6	journal	June 2018
On the selection of FCC and BCC lattices in poly(styrene-b-isoprene) copolymer micelles Bang, Joona; Lodge, Timothy P. Macromolecular Research, Vol. 16, Issue 1 https://doi.org/10.1007/bf03218960	journal	January 2008
Poloxamer Hydrogels for Biomedical Applications Russo, Eleonora; Villa, Carla Pharmaceutics, Vol. 11, Issue 12 https://doi.org/10.3390/pharmaceutics11120671	journal	December 2019
Structure, rheology and shear alignment of Pluronic block copolymer mixtures Newby, Gemma E.; Hamley, Ian W.; King, Stephen M. Journal of Colloid and Interface Science, Vol. 329, Issue 1 https://doi.org/10.1016/j.jcis.2008.09.054	journal	January 2009
Effects of Poly(Propylene Oxide)–Poly(Ethylene Oxide)–Poly(Propylene Oxide) Triblock Copolymer on the Gelation of Poly(Ethylene Oxide)–Poly(Propylene Oxide)–Poly(Ethylene Oxide) Aqueous Solutions Xie, Yu; Tang, Jiankai; Lu, Zhongyuan Journal of Macromolecular Science, Part B, Vol. 52, Issue 9 https://doi.org/10.1080/00222348.2012.758524	journal	December 2012
Micellar structure changes in aqueous mixtures of nonionic surfactants Guo, Liang; Colby, Ralph H.; Lin, Min Y. Journal of Rheology, Vol. 45, Issue 5 https://doi.org/10.1122/1.1389315	journal	September 2001
Enhancement of the Mechanical and Drug-Releasing Properties of Poloxamer 407 Hydrogels with Casein Tundisi, Louise Lacalendola; Yang, Rong; Borelli, Luiz Phellipe Pozzuto Pharmaceutical Research, Vol. 38, Issue 3 https://doi.org/10.1007/s11095-021-03017-9	journal	February 2021
Improved Network Development in Bidisperse AB/ABA Block Copolymer Gels Spontak, Richard J.; Wilder, Elizabeth A.; Smith, Steven D. Langmuir, Vol. 17, Issue 8 https://doi.org/10.1021/la0015819	journal	March 2001
Laboratory‐scale setup for anionic polymerization under inert atmosphere Ndoni, Sokol; Papadakis, Christine M.; Bates, Frank S. Review of Scientific Instruments, Vol. 66, Issue 2 https://doi.org/10.1063/1.1146052	journal	February 1995
Micellization of Poly(ethylene oxide)-Poly(propylene oxide)-Poly(ethylene oxide) Triblock Copolymers in Aqueous Solutions: Thermodynamics of Copolymer Association Alexandridis, Paschalis; Holzwarth, Josef F.; Hatton, T. Alan Macromolecules, Vol. 27, Issue 9 https://doi.org/10.1021/ma00087a009	journal	April 1994
Micellar Dynamics in Aqueous Solutions of PEO−PPO−PEO Block Copolymers ^† Goldmints, Isabella; Holzwarth, Josef F.; Smith, Kenneth A. Langmuir, Vol. 13, Issue 23 https://doi.org/10.1021/la970534m	journal	November 1997
Effects of block architecture and composition on the association properties of poly(oxyalkylene) copolymers in aqueous solution Booth, Colin; Attwood, David Macromolecular Rapid Communications, Vol. 21, Issue 9 https://doi.org/10.1002/1521-3927(20000601)21:9<501::aid-marc501>3.0.co;2-r	journal	June 2000
Structural characterization using SAXS and rheological behaviors of pluronic F127 and methylcellulose blends Boonrat, Onpreeya; Tantishaiyakul, Vimon; Hirun, Namon Polymer Bulletin, Vol. 78, Issue 3 https://doi.org/10.1007/s00289-020-03154-y	journal	March 2020
New Monte Carlo method to compute the free energy of arbitrary solids. Application to the fcc and hcp phases of hard spheres Frenkel, Daan; Ladd, Anthony J. C. The Journal of Chemical Physics, Vol. 81, Issue 7 https://doi.org/10.1063/1.448024	journal	October 1984
Micellization and Gelation of Mixed Copolymers P123 and F127 in Aqueous Solution Chaibundit, Chiraphon; Ricardo, Nágila M. P. S.; Costa, Flávia de M. L. L. Langmuir, Vol. 23, Issue 18 https://doi.org/10.1021/la701157j	journal	August 2007
Self-assembly of the triblock copolymer 17R4 poly(propylene oxide)14–poly(ethylene oxide)24–poly(propylene oxide)14 in D2O Kumi, Bryna C.; Hammouda, Boualem; Greer, Sandra C. Journal of Colloid and Interface Science, Vol. 434 https://doi.org/10.1016/j.jcis.2014.07.049	journal	November 2014
Rheological signatures of gel–glass transition and a revised phase diagram of an aqueous triblock copolymer solution of Pluronic F127 Suman, Khushboo; Sourav, Sagar; Joshi, Yogesh M. Physics of Fluids, Vol. 33, Issue 7 https://doi.org/10.1063/5.0057090	journal	July 2021
Effect of ethanol on the gelation of aqueous solutions of Pluronic F127 Chaibundit, Chiraphon; Ricardo, Nágila M. P. S.; Ricardo, Nádja M. P. S. Journal of Colloid and Interface Science, Vol. 351, Issue 1 https://doi.org/10.1016/j.jcis.2010.07.023	journal	November 2010
Anomalous rheological aging of a model thermoreversible colloidal gel following a thermal quench Suman, Khushboo; Wagner, Norman J. The Journal of Chemical Physics, Vol. 157, Issue 2 https://doi.org/10.1063/5.0094237	journal	July 2022
A Generalized Mechano-statistical Transient Network Model for Unravelling the Network Topology and Elasticity of Hydrophobically Associating Multiblock Copolymers in Aqueous Solutions Huysecom, An-Sofie; Thielemans, Wim; Moldenaers, Paula Macromolecules, Vol. 56, Issue 2 https://doi.org/10.1021/acs.macromol.2c01500	journal	January 2023
Association Behavior of a Triblock Copolymer of Oxyethylene (E) and Oxybutylene (B). A Study of B₅E₉₁B₅ in Aqueous Solution Zhou, Zukang; Chu, Benjamin; Nace, V. Mark Langmuir, Vol. 12, Issue 21 https://doi.org/10.1021/la9601768	journal	January 1996
Equilibrium behavior of symmetric ABA triblock copolymer melts Matsen, M. W.; Thompson, R. B. The Journal of Chemical Physics, Vol. 111, Issue 15 https://doi.org/10.1063/1.480006	journal	October 1999
Fractal-like structures in colloid science Lazzari, S.; Nicoud, L.; Jaquet, B. Advances in Colloid and Interface Science, Vol. 235 https://doi.org/10.1016/j.cis.2016.05.002	journal	September 2016
Cryo-TEM and SANS Microstructural Study of Pluronic Polymer Solutions Mortensen, Kell; Talmon, Yeshayahu Macromolecules, Vol. 28, Issue 26 https://doi.org/10.1021/ma00130a016	journal	December 1995
Use of crown ether in the anionic polymerization of propylene oxide—3. Preparation and micellization of diblock-copoly(oxypropylene/oxyethylene) Ding, Jifeng; Attwood, David; Price, Colin European Polymer Journal, Vol. 27, Issue 9 https://doi.org/10.1016/0014-3057(91)90030-r	journal	January 1991
Two step yielding in attractive colloids: transition from gels to attractive glasses Koumakis, N.; Petekidis, G. Soft Matter, Vol. 7, Issue 6 https://doi.org/10.1039/c0sm00957a	journal	January 2011
Preparation and properties of stat-copoly-(oxyethylene-oxypropylene)-block-poly (oxyethylene): 1. Use of crown ether in the anionic copolymerization of propylene oxide and ethylene oxide Deng, Yulin; Ding, Jifeng; Yu, Gaer Polymer, Vol. 33, Issue 9 https://doi.org/10.1016/0032-3861(92)90500-v	journal	January 1992
Effect of sodium chloride on the gelation temperature, gel strength and bioadhesive force of poloxamer gels containing diclofenac sodium Yong, Chul Soon; Choi, Jin Suck; Quan, Qi-Zhe International Journal of Pharmaceutics, Vol. 226, Issue 1-2 https://doi.org/10.1016/s0378-5173(01)00809-2	journal	September 2001
Structure and rheology of aqueous micellar solutions and gels formed from an associative poly(oxybutylene)–poly(oxyethylene)–poly(oxybutylene) triblock copolymer Castelletto, V.; Hamley, I. W.; Yuan, X. -F. Soft Matter, Vol. 1, Issue 2 https://doi.org/10.1039/b419103j	journal	January 2005
Rheology of associative polymer solutions Chassenieux, Christophe; Nicolai, Taco; Benyahia, Lazhar Current Opinion in Colloid & Interface Science, Vol. 16, Issue 1 https://doi.org/10.1016/j.cocis.2010.07.007	journal	February 2011
The rheology of solutions of associating polymers: Comparison of experimental behavior with transient network theory Annable, Tom; Buscall, Richard; Ettelaie, Rammile Journal of Rheology, Vol. 37, Issue 4 https://doi.org/10.1122/1.550391	journal	July 1993
Interactions between Poloxamers in Aqueous Solutions: Micellization and Gelation Studied by Differential Scanning Calorimetry, Small Angle X-ray Scattering, and Rheology Artzner, Franck; Geiger, Sandrine; Olivier, Audrey Langmuir, Vol. 23, Issue 9 https://doi.org/10.1021/la062622p	journal	April 2007
Aqueous Assembly and Hydrogel Rheology of Sustainable Glyoxylate-Based Copolymers Yin, Xuechen; Hewitt, David R. O.; Zheng, Bingqian ACS Applied Polymer Materials, Vol. 4, Issue 8 https://doi.org/10.1021/acsapm.2c00542	journal	July 2022
Origin of the Thermoreversible fcc-bcc Transition in Block Copolymer Solutions Lodge, Timothy P.; Bang, Joona; Park, Moon Jeong Physical Review Letters, Vol. 92, Issue 14 https://doi.org/10.1103/physrevlett.92.145501	journal	April 2004
Close-packed block copolymer micelles induced by temperature quenching Chen, Liwen; Lee, Han Seung; Lee, Sangwoo Proceedings of the National Academy of Sciences, Vol. 115, Issue 28 https://doi.org/10.1073/pnas.1801682115	journal	June 2018
Power law viscoelasticity of a fractal colloidal gel Aime, S.; Cipelletti, L.; Ramos, L. Journal of Rheology, Vol. 62, Issue 6 https://doi.org/10.1122/1.5025622	journal	November 2018
Self-Assembly of Copolymer Micelles: Higher-Level Assembly for Constructing Hierarchical Structure Lu, Yingqing; Lin, Jiaping; Wang, Liquan Chemical Reviews, Vol. 120, Issue 9 https://doi.org/10.1021/acs.chemrev.9b00774	journal	March 2020
Micellization and gelation of PEO-PPO-PEO binary mixture with non-identical PPO block lengths in aqueous solution Pragatheeswaran, Abhinav Maheswaran; Chen, Shing Bor; Chen, Chi-Fan Polymer, Vol. 55, Issue 20 https://doi.org/10.1016/j.polymer.2014.08.031	journal	September 2014
Engineering the Structure and Rheological Properties of P407 Hydrogels via Reverse Poloxamer Addition White, Joanna M.; Garza, Ally; Griebler, James J. Langmuir, Vol. 39, Issue 14 https://doi.org/10.1021/acs.langmuir.3c00088	journal	March 2023
Concentration Dependence of Loop Fraction in Styrene−Isoprene−Styrene Triblock Copolymer Solutions and Corresponding Changes in Equilibrium Elasticity Watanabe, Hiroshi; Sato, Tomohiro; Osaki, Kunihiro Macromolecules, Vol. 33, Issue 7 https://doi.org/10.1021/ma991979f	journal	April 2000
Dominant Factors on the Micellization of B_nE_mB_n-Type Triblock Copolymers in Aqueous Solution Liu, Tianbo; Zhou, Zukang; Wu, Chunhung The Journal of Physical Chemistry B, Vol. 102, Issue 16 https://doi.org/10.1021/jp980139k	journal	March 1998
Thermosensitive Hydrogels of BAB Triblock Copolymers Exhibiting Gradually Slower Exchange Dynamics and an Unexpected Critical Reorganization Temperature Upon Heating Coudert, Noémie; Debrie, Clément; Rieger, Jutta Macromolecules, Vol. 55, Issue 23 https://doi.org/10.1021/acs.macromol.2c01573	journal	December 2022
Block copolymer micelles for drug delivery: design, characterization and biological significance Kataoka, Kazunori; Harada, Atsushi; Nagasaki, Yukio Advanced Drug Delivery Reviews, Vol. 47, Issue 1 https://doi.org/10.1016/s0169-409x(00)00124-1	journal	March 2001
Role of PPO–PEO–PPO triblock copolymers in phase transitions of a PEO–PPO–PEO triblock copolymer in aqueous solution Liu, Sijun; Bao, Hongqian; Li, Lin European Polymer Journal, Vol. 71 https://doi.org/10.1016/j.eurpolymj.2015.08.016	journal	October 2015
Rheological characterization of Poloxamer 407 lidocaine hydrochloride gels Ricci, E. J.; Bentley, M. V. L. B.; Farah, M. European Journal of Pharmaceutical Sciences, Vol. 17, Issue 3 https://doi.org/10.1016/s0928-0987(02)00166-5	journal	November 2002
Molecular interactions between PEO–PPO–PEO and PPO–PEO–PPO triblock copolymers in aqueous solution Liu, Sijun; Li, Lin Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 484 https://doi.org/10.1016/j.colsurfa.2015.08.034	journal	November 2015
A micro-mechanical study of coarsening and rheology of colloidal gels: Cage building, cage hopping, and Smoluchowski's ratchet Zia, Roseanna N.; Landrum, Benjamin J.; Russel, William B. Journal of Rheology, Vol. 58, Issue 5 https://doi.org/10.1122/1.4892115	journal	September 2014
In situ-forming hydrogels—review of temperature-sensitive systems Ruel-Gariépy, Eve; Leroux, Jean-Christophe European Journal of Pharmaceutics and Biopharmaceutics, Vol. 58, Issue 2 https://doi.org/10.1016/j.ejpb.2004.03.019	journal	September 2004
Synergy between chemical permeation enhancers and drug permeation across the tympanic membrane Yang, Rong; Okonkwo, Obiajulu S.; Zurakowski, David Journal of Controlled Release, Vol. 289 https://doi.org/10.1016/j.jconrel.2018.06.019	journal	November 2018
Strategies to improve micelle stability for drug delivery Lu, Yang; Zhang, Ershuai; Yang, Jianhai Nano Research, Vol. 11, Issue 10 https://doi.org/10.1007/s12274-018-2152-3	journal	August 2018
Effects of a PPO−PEO−PPO Triblock Copolymer on Micellization and Gelation of a PEO−PPO−PEO Triblock Copolymer in Aqueous Solution Wang, Qiqiang; Li, Lin; Jiang, Sanping Langmuir, Vol. 21, Issue 20 https://doi.org/10.1021/la051537z	journal	August 2005
Nanostructured fluids from pluronic® mixtures Zhang, Min; Djabourov, Madeleine; Bourgaux, Claudie International Journal of Pharmaceutics, Vol. 454, Issue 2 https://doi.org/10.1016/j.ijpharm.2013.01.043	journal	October 2013
Random hcp and fcc structures in thermoresponsive microgel crystals Brijitta, J.; Tata, B. V. R.; Joshi, R. G. The Journal of Chemical Physics, Vol. 131, Issue 7 https://doi.org/10.1063/1.3210765	journal	August 2009
Lipid Membrane Binding and Cell Protection Efficacy of Poly(1,2-butylene oxide)-b-poly(ethylene oxide) Copolymers Van Zee, Nicholas J.; Peroutka, Amanda S.; Crabtree, Adelyn Biomacromolecules, Vol. 23, Issue 3 https://doi.org/10.1021/acs.biomac.1c01661	journal	February 2022
Temperature-Dependent Hydration/Dehydration Behavior of Poly(ethylene oxide)s in Aqueous Solution Shikata, Toshiyuki; Okuzono, Misumi; Sugimoto, Natsuki Macromolecules, Vol. 46, Issue 5 https://doi.org/10.1021/ma3026282	journal	February 2013
The aggregation behavior of poly-(oxyethylene)-poly-(oxypropylene)-poly-(oxyethylene)-block-copolymers in aqueous solution Wanka, G.; Hoffmann, H.; Ulbricht, W. Colloid & Polymer Science, Vol. 268, Issue 2 https://doi.org/10.1007/bf01513189	journal	February 1990
Diffuse scattering in random-stacking hexagonal close-packed crystals of colloidal hard spheres Byelov, Dmytro V.; Hilhorst, Jan; Leferink op Reinink, Anke B. G. M. Phase Transitions, Vol. 83, Issue 2 https://doi.org/10.1080/01411590903586452	journal	February 2010
Aqueous micellar solutions of a triblock copolymer of ethylene oxide and 1,2-butylene oxide, B12E114B12. Scaling the viscoelasticity of fluid and gel Kelarakis, Antonis; Yuan, Xue-Feng; Mai, Shao-Min Physical Chemistry Chemical Physics, Vol. 5, Issue 12 https://doi.org/10.1039/b300214d	journal	January 2003
PEO–PPO Diblock Copolymers Protect Myoblasts from Hypo-Osmotic Stress In Vitro Dependent on Copolymer Size, Composition, and Architecture Kim, Mihee; Haman, Karen J.; Houang, Evelyne M. Biomacromolecules, Vol. 18, Issue 7 https://doi.org/10.1021/acs.biomac.7b00419	journal	June 2017
Time–connectivity superposition and the gel/glass duality of weak colloidal gels Keshavarz, Bavand; Rodrigues, Donatien Gomes; Champenois, Jean-Baptiste Proceedings of the National Academy of Sciences, Vol. 118, Issue 15 https://doi.org/10.1073/pnas.2022339118	journal	April 2021
Concentration Threshold for Membrane Protection by PEO–PPO Block Copolymers with Variable Molecular Architectures Crabtree, Adelyn A.; Bates, Frank S.; Hackel, Benjamin J. ACS Applied Polymer Materials, Vol. 4, Issue 5 https://doi.org/10.1021/acsapm.1c01807	journal	April 2022
Chain architecture and micellization: A mean-field coarse-grained model for poly(ethylene oxide) alkyl ether surfactants García Daza, Fabián A.; Colville, Alexander J.; Mackie, Allan D. The Journal of Chemical Physics, Vol. 142, Issue 11 https://doi.org/10.1063/1.4913960	journal	March 2015
Gelation behavior, drug solubilization capacity and release kinetics of poloxamer 407 aqueous solutions: The combined effect of copolymer, cosolvent and hydrophobic drug Djekic, Ljiljana; Čalija, Bojan; Medarević, Đorđe Journal of Molecular Liquids, Vol. 303 https://doi.org/10.1016/j.molliq.2020.112639	journal	April 2020
Effects of PEO−PPO Diblock Impurities on the Cubic Structure of Aqueous PEO−PPO−PEO Pluronics Micelles: fcc and bcc Ordered Structures in F127 Mortensen, Kell; Batsberg, Walther; Hvidt, Søren Macromolecules, Vol. 41, Issue 5 https://doi.org/10.1021/ma702269c	journal	March 2008
Universal Scaling for the Exit Dynamics of Block Copolymers from Micelles at Short and Long Time Scales Pantelidou, Maria S.; García Daza, Fabián A.; Avalos, Josep Bonet Macromolecules, Vol. 55, Issue 3 https://doi.org/10.1021/acs.macromol.1c02387	journal	January 2022
Dynamics and Equilibration Mechanisms in Block Copolymer Particles Lodge, Timothy P.; Seitzinger, Claire L.; Seeger, Sarah C. ACS Polymers Au, Vol. 2, Issue 6 https://doi.org/10.1021/acspolymersau.2c00033	journal	August 2022
The micellar properties of the poly(oxyethylene) - poly(oxypropylene) copolymer Pluronic F127 in water and electrolyte solution Attwood, D.; Collett, J.; Tait, C. International Journal of Pharmaceutics, Vol. 26, Issue 1-2 https://doi.org/10.1016/0378-5173(85)90197-8	journal	September 1985
Poly(ethylene oxide)poly(propylene oxide)poly(ethylene oxide) block copolymer surfactants in aqueous solutions and at interfaces: thermodynamics, structure, dynamics, and modeling Alexandridis, Paschalis; Alan Hatton, T. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 96, Issue 1-2 https://doi.org/10.1016/0927-7757(94)03028-x	journal	March 1995
Associating polymers: Equilibrium and linear viscoelasticity Semenov, A. N.; Joanny, J. -F.; Khokhlov, A. R. Macromolecules, Vol. 28, Issue 4 https://doi.org/10.1021/ma00108a038	journal	July 1995
Self-Assembly of Mixtures of Telechelic and Monofunctional Amphiphilic Polymers in Water: From Clusters to Flowerlike Micelles Zinn, Thomas; Willner, Lutz; Knudsen, Kenneth D. Macromolecules, Vol. 50, Issue 18 https://doi.org/10.1021/acs.macromol.7b01501	journal	September 2017
Pluronic® block-copolymers in medicine: from chemical and biological versatility to rationalisation and clinical advances Pitto-Barry, Anaïs; Barry, Nicolas P. E. Polym. Chem., Vol. 5, Issue 10 https://doi.org/10.1039/c4py00039k	journal	January 2014
Phase Behavior and Association Properties of Poly(oxypropylene)-Poly(oxyethylene)-Poly(oxypropylene) Triblock Copolymer in Aqueous Solution Zhou, Zukang; Chu, Benjamin Macromolecules, Vol. 27, Issue 8 https://doi.org/10.1021/ma00086a008	journal	April 1994

Similar Records

Engineering the Structure and Rheological Properties of P407 Hydrogels via Reverse Poloxamer Addition

Journal Article · 2023 · Langmuir · OSTI ID:2423414

Influence of End-Block Dynamics on Deformation Behavior of Thermoresponsive Elastin-like Polypeptide Hydrogels

Journal Article · 2018 · Macromolecules · OSTI ID:1434753

Structure and rheology of dual-associative protein hydrogels under nonlinear shear flow

Journal Article · 2016 · Soft Matter · OSTI ID:1478081

Related Subjects

Polymer Science

Effect of Chain Architecture on the Structure, Dynamics, and Rheology of Thermoresponsive Poloxamer Hydrogels and Associated Blends

Citation Formats

References (97)

Similar Records

Related Subjects