Detailed Analysis of the Synthesis and Structure of MAX Phase (Mo 0.75 V 0.25 ) 5 AlC 4 and Its MXene Sibling (Mo 0.75 V 0.25 ) 5 C 4

Snyder, Rose M.; Juelsholt, Mikkel; Kalha, Curran; Holm, Jason; Mansfield, Elisabeth; Lee, Tien-Lin; Thakur, Pardeep K.; Riaz, Aysha A.; Moss, Benjamin; Regoutz, Anna; Birkel, Christina S.

doi:10.1021/acsnano.3c03395

Detailed Analysis of the Synthesis and Structure of MAX Phase (Mo _0.75 V _0.25 ) ₅ AlC ₄ and Its MXene Sibling (Mo _0.75 V _0.25 ) ₅ C ₄

Journal Article · 27 June 2023 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.3c03395· OSTI ID:2423375

^[1]; ^[2]; Kalha, Curran ^[3]; Holm, Jason ^[4]; ^[4]; Lee, Tien-Lin ^[5]; ^[5]; Riaz, Aysha A. ^[3]; ^[6]; ^[3]; ^[7]

School of Molecular Sciences, Arizona State University, Tempe, Arizona 85281, United States
Department of Materials, University of Oxford, Oxford, OX1 3PH, U.K.
Department of Chemistry, University College London, London, WC1H 0AJ, U.K.
Applied Chemicals and Materials Division, National Institute of Standards and Technology, Boulder, Colorado 80305, United States
Diamond Light Source, Harwell Science and Innovation Campus, Didcot, OX11 0DE, U.K.
Department of Chemistry, Molecular Science Research Hub, White City Campus, Imperial College London, London W12 0BZ, U.K.
School of Molecular Sciences, Arizona State University, Tempe, Arizona 85281, United States; Department of Chemistry and Biochemistry, Technische Universitaet Darmstadt, 64287 Darmstadt, Germany

Not provided.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2423375

Journal Information:: ACS Nano, Journal Name: ACS Nano Journal Issue: 13 Vol. 17; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (55)

A Two-Color Beamline for Electron Spectroscopies at Diamond Light Source Lee, Tien-Lin; Duncan, David A. Synchrotron Radiation News, Vol. 31, Issue 4 https://doi.org/10.1080/08940886.2018.1483653	journal	July 2018
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
ImageJ2: ImageJ for the next generation of scientific image data Rueden, Curtis T.; Schindelin, Johannes; Hiner, Mark C. BMC Bioinformatics, Vol. 18, Issue 1 https://doi.org/10.1186/s12859-017-1934-z	journal	November 2017
Intercalation and delamination of layered carbides and carbonitrides Mashtalir, Olha; Naguib, Michael; Mochalin, Vadym N. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2664	journal	April 2013
Novel MAX-phase Ti3AlC2 catalyst for improving the reversible hydrogen storage properties of MgH2 Wang, Ke; Du, Hufei; Wang, Zeyi International Journal of Hydrogen Energy, Vol. 42, Issue 7 https://doi.org/10.1016/j.ijhydene.2016.10.073	journal	February 2017
Synthesis of Two-Dimensional Materials by Selective Extraction Naguib, Michael; Gogotsi, Yury Accounts of Chemical Research, Vol. 48, Issue 1 https://doi.org/10.1021/ar500346b	journal	December 2014
Hot corrosion and low cycle fatigue of a Cr2AlC-coated superalloy Smialek, J. L.; Nesbitt, J. A.; Gabb, T. P. Materials Science and Engineering: A, Vol. 711 https://doi.org/10.1016/j.msea.2017.10.098	journal	January 2018
2D MXene-Based Materials for Electrocatalysis Liu, Jiapeng; Peng, Wenchao; Li, Yang Transactions of Tianjin University, Vol. 26, Issue 3 https://doi.org/10.1007/s12209-020-00235-x	journal	February 2020
Microstructures and Theoretical Bulk Modulus of Layered Ternary Tantalum Aluminum Carbides Lin, Zhijun; Zhuo, Mujin; Zhou, Yanchun Journal of the American Ceramic Society, Vol. 89, Issue 12 https://doi.org/10.1111/j.1551-2916.2006.01303.x	journal	December 2006
(Ti0.5Nb0.5)5AlC4: A New-Layered Compound Belonging to MAX Phases: Rapid Communications of the American Ceramic Society Zheng, Liya; Wang, Jiemin; Lu, Xinpo Journal of the American Ceramic Society, Vol. 93, Issue 10 https://doi.org/10.1111/j.1551-2916.2010.04056.x	journal	September 2010
Fluorination of carbon blacks: An X-ray photoelectron spectroscopy study: I. A literature review of XPS studies of fluorinated carbons. XPS investigation of some reference compounds Nansé, G.; Papirer, E.; Fioux, P. Carbon, Vol. 35, Issue 2 https://doi.org/10.1016/S0008-6223(96)00095-4	journal	January 1997
Polymorphism of newly discovered Ti4GaC3: A first-principles study He, Xiaodong; Bai, Yuelei; Zhu, Chuncheng Acta Materialia, Vol. 59, Issue 14 https://doi.org/10.1016/j.actamat.2011.05.025	journal	August 2011
PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions Juhás, P.; Davis, T.; Farrow, C. L. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813005190	journal	March 2013
The M_n+1AX_n phases: Materials science and thin-film processing Eklund, Per; Beckers, Manfred; Jansson, Ulf Thin Solid Films, Vol. 518, Issue 8, p. 1851-1878 https://doi.org/10.1016/j.tsf.2009.07.184	journal	February 2010
Calculations of electron inelastic mean free paths. X. Data for 41 elemental solids over the 50 eV to 200 keV range with the relativistic full Penn algorithm: Calculations of electron inelastic mean free paths. X Shinotsuka, H.; Tanuma, S.; Powell, C. J. Surface and Interface Analysis, Vol. 47, Issue 9 https://doi.org/10.1002/sia.5789	journal	July 2015
Strukturchemie einiger Verbindungen der Übergangsmetalle mit den elementen C, Si, Ge, Sn Nowotny, V. Progress in Solid State Chemistry, Vol. 5 https://doi.org/10.1016/0079-6786(71)90016-1	journal	January 1971
The Rise of MXenes Gogotsi, Yury; Anasori, Babak ACS Nano, Vol. 13, Issue 8 https://doi.org/10.1021/acsnano.9b06394	journal	July 2019
International Tables for Crystallography Aroyo, M. I. https://doi.org/10.1107/97809553602060000114	reference-book	January 2016
xPDFsuite: an end-to-end software solution for high throughput pair distribution function transformation, visualization and analysis Yang, Xiaohao; Juhas, Pavol; Farrow, Christopher L. arXiv https://doi.org/10.48550/arXiv.1402.3163	preprint	January 2014
Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution Seh, Zhi Wei; Fredrickson, Kurt D.; Anasori, Babak ACS Energy Letters, Vol. 1, Issue 3 https://doi.org/10.1021/acsenergylett.6b00247	journal	August 2016
Rapid-acquisition pair distribution function (RA-PDF) analysis Chupas, Peter J.; Qiu, Xiangyun; Hanson, Jonathan C. Journal of Applied Crystallography, Vol. 36, Issue 6, p. 1342-1347 https://doi.org/10.1107/S0021889803017564	journal	November 2003
On the Chemical Diversity of the MAX Phases Sokol, Maxim; Natu, Varun; Kota, Sankalp Trends in Chemistry, Vol. 1, Issue 2 https://doi.org/10.1016/j.trechm.2019.02.016	journal	May 2019
Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes) Anasori, Babak; Xie, Yu; Beidaghi, Majid ACS Nano, Vol. 9, Issue 10 https://doi.org/10.1021/acsnano.5b03591	journal	August 2015
MXene Nanofibers as Highly Active Catalysts for Hydrogen Evolution Reaction Yuan, Wenyu; Cheng, Laifei; An, Yurong ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 7 https://doi.org/10.1021/acssuschemeng.8b01348	journal	May 2018
HCl‐Based Hydrothermal Etching Strategy toward Fluoride‐Free MXenes Wang, Changda; Shou, Hongwei; Chen, Shuangming Advanced Materials, Vol. 33, Issue 27 https://doi.org/10.1002/adma.202101015	journal	May 2021
Sustainable Hydrogen Production Turner, J. A. Science, Vol. 305, Issue 5686 https://doi.org/10.1126/science.1103197	journal	August 2004
Synthesis of Mo 4 VAlC 4 MAX Phase and Two-Dimensional Mo 4 VC 4 MXene with Five Atomic Layers of Transition Metals Deysher, Grayson; Shuck, Christopher Eugene; Hantanasirisakul, Kanit ACS Nano, Vol. 14, Issue 1 https://doi.org/10.1021/acsnano.9b07708	journal	December 2019
Size-induced amorphous structure in tungsten oxide nanoparticles Juelsholt, Mikkel; Anker, Andy S.; Christiansen, Troels Lindahl Nanoscale, Vol. 13, Issue 47 https://doi.org/10.1039/D1NR05991B	journal	January 2021
Predictive theoretical screening of phase stability for chemical order and disorder in quaternary 312 and 413 MAX phases Dahlqvist, Martin; Rosen, Johanna Nanoscale, Vol. 12, Issue 2 https://doi.org/10.1039/C9NR08675G	journal	January 2020
Ab initio study of polymorphism in layered ternary carbide M4AlC3 (M=V, Nb and Ta) Wang, Jingyang; Wang, Jiemin; Zhou, Yanchun Scripta Materialia, Vol. 58, Issue 12 https://doi.org/10.1016/j.scriptamat.2008.01.058	journal	June 2008
The experimental physics and industrial control system architecture: past, present, and future Dalesio, Leo R.; Hill, Jeffrey O.; Kraimer, Martin Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 352, Issue 1-2 https://doi.org/10.1016/0168-9002(94)91493-1	journal	December 1994
Experimental and DFT investigation of (Cr,Ti) ₃ AlC ₂ MAX phases stability Burr, Patrick A.; Horlait, Denis; Lee, William E. Materials Research Letters, Vol. 5, Issue 3 https://doi.org/10.1080/21663831.2016.1222598	journal	September 2016
The M_N+1AX_N phases: A new class of solids: Thermodynamically stable nanolaminates Barsoum, Michel W. Progress in Solid State Chemistry, Vol. 28, Issue 1-4, p. 201-281 https://doi.org/10.1016/S0079-6786(00)00006-6	journal	January 2000
Copper-MAX-phase composite coatings obtained by electro-co-deposition: A promising material for electrical contacts Grieseler, R.; Camargo, M. K.; Hopfeld, M. Surface and Coatings Technology, Vol. 321 https://doi.org/10.1016/j.surfcoat.2017.04.060	journal	July 2017
From MAX Phase Carbides to Nitrides: Synthesis of V₂GaC, V₂GaN, and the Carbonitride V₂GaC_1–xN_x Kubitza, Niels; Reitz, Andreas; Zieschang, Anne-Marie Inorganic Chemistry, Vol. 61, Issue 28 https://doi.org/10.1021/acs.inorgchem.2c00200	journal	July 2022
Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers Anasori, Babak; Shi, Chenyang; Moon, Eun Ju Nanoscale Horizons, Vol. 1, Issue 3 https://doi.org/10.1039/C5NH00125K	journal	January 2016
Elastic and Mechanical Properties of the MAX Phases Barsoum, Michel W.; Radovic, Miladin Annual Review of Materials Research, Vol. 41, Issue 1 https://doi.org/10.1146/annurev-matsci-062910-100448	journal	August 2011
Progress in research and development on MAX phases: a family of layered ternary compounds Sun, Z. M. International Materials Reviews, Vol. 56, Issue 3 https://doi.org/10.1179/1743280410Y.0000000001	journal	May 2011
Enhanced Electrocatalytic Hydrogen Evolution Activity in Single-Atom Pt-Decorated VS ₂ Nanosheets Zhu, Jingting; Cai, Lejuan; Yin, Xinmao ACS Nano, Vol. 14, Issue 5 https://doi.org/10.1021/acsnano.9b10048	journal	April 2020
ESCA Studies of MoO2 and MoO3 Brox, B.; Olefjord, I. Surface and Interface Analysis, Vol. 13, Issue 1 https://doi.org/10.1002/sia.740130103	journal	October 1988
Orientation mapping of graphene using 4D STEM-in-SEM Caplins, Benjamin W.; Holm, Jason D.; White, Ryan M. Ultramicroscopy, Vol. 219 https://doi.org/10.1016/j.ultramic.2020.113137	journal	December 2020
A twelve-analyzer detector system for high-resolution powder diffraction Lee, Peter L.; Shu, Deming; Ramanathan, Mohan Journal of Synchrotron Radiation, Vol. 15, Issue 5 https://doi.org/10.1107/S0909049508018438	journal	July 2008
Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti ₃ C ₂ T _x MXene) Alhabeb, Mohamed; Maleski, Kathleen; Anasori, Babak Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b02847	journal	September 2017
Predicted Surface Composition and Thermodynamic Stability of MXenes in Solution Ashton, Michael; Mathew, Kiran; Hennig, Richard G. The Journal of Physical Chemistry C, Vol. 120, Issue 6 https://doi.org/10.1021/acs.jpcc.5b11887	journal	February 2016
MXene‐Based Anodes for Metal‐Ion Batteries Greaves, Michael; Barg, Suelen; Bissett, Mark A. Batteries & Supercaps, Vol. 3, Issue 3 https://doi.org/10.1002/batt.201900165	journal	January 2020
A novel nitrite biosensor based on the direct electrochemistry of hemoglobin immobilized on MXene-Ti3C2 Liu, Hui; Duan, Congyue; Yang, Chenhui Sensors and Actuators B: Chemical, Vol. 218 https://doi.org/10.1016/j.snb.2015.04.090	journal	October 2015
A dedicated powder diffraction beamline at the Advanced Photon Source: Commissioning and early operational results Wang, Jun; Toby, Brian H.; Lee, Peter L. Review of Scientific Instruments, Vol. 79, Issue 8 https://doi.org/10.1063/1.2969260	journal	August 2008
Adding a New Member to the MXene Family: Synthesis, Structure, and Electrocatalytic Activity for the Hydrogen Evolution Reaction of V ₄ C ₃ T _x Tran, Minh H.; Schäfer, Timo; Shahraei, Ali ACS Applied Energy Materials, Vol. 1, Issue 8 https://doi.org/10.1021/acsaem.8b00652	journal	July 2018
The X-ray photoelectron spectra of inorganic molecules. XI1. Fluorine 1s binding energies in metal fluorides Ebner, J. R.; McFadden, D. L.; Walton, R. A. Journal of Solid State Chemistry, Vol. 17, Issue 4 https://doi.org/10.1016/S0022-4596(76)80016-3	journal	January 1976
Intercomparison of surface analysis of thin aluminium oxide films Olefjord, I.; Mathieu, H. J.; Marcus, P. Surface and Interface Analysis, Vol. 15, Issue 11 https://doi.org/10.1002/sia.740151108	journal	November 1990
PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals Farrow, C. L.; Juhas, P.; Liu, J. W. Journal of Physics: Condensed Matter, Vol. 19, Issue 33 https://doi.org/10.1088/0953-8984/19/33/335219	journal	July 2007
Biogas as a Renewable Energy Source—A Review Balat, M.; Balat, H. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, Vol. 31, Issue 14 https://doi.org/10.1080/15567030802089565	journal	August 2009
Progression in the Oxidation Stability of MXenes Soomro, Razium A.; Zhang, Peng; Fan, Baomin Nano-Micro Letters, Vol. 15, Issue 1 https://doi.org/10.1007/s40820-023-01069-7	journal	April 2023
Hydrofluoric Acid: Burns and Systemic Toxicity, Protective Measures, Immediate and Hospital Medical Treatment Bajraktarova-Valjakova, Emilija; Korunoska-Stevkovska, Vesna; Georgieva, Silvana Open Access Macedonian Journal of Medical Sciences, Vol. 6, Issue 11 https://doi.org/10.3889/oamjms.2018.429	journal	November 2018
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration Prescher, Clemens; Prakapenka, Vitali B. High Pressure Research, Vol. 35, Issue 3 https://doi.org/10.1080/08957959.2015.1059835	journal	May 2015

Similar Records

Non-conventional synthesis and magnetic properties of MAX phases (Cr/Mn) ₂ AlC and (Cr/Fe) ₂ AlC

Journal Article · 2016 · Journal of Materials Chemistry. C · OSTI ID:1368324

Synthesis of Mo₄VAlC₄ MAX Phase and Two-Dimensional Mo₄VC₄ MXene with Five Atomic Layers of Transition Metals

Journal Article · 2019 · ACS Nano · OSTI ID:1774171

Detailed study of the magnetic ordering in FeMnP{sub 0.75}Si{sub 0.25}

Journal Article · 2015 · Journal of Solid State Chemistry · OSTI ID:22443503

Related Subjects

Chemistry
Materials Science
Science & Technology - Other Topics

Detailed Analysis of the Synthesis and Structure of MAX Phase (Mo 0.75 V 0.25 ) 5 AlC 4 and Its MXene Sibling (Mo 0.75 V 0.25 ) 5 C 4

Citation Formats

References (55)

Similar Records

Related Subjects

Detailed Analysis of the Synthesis and Structure of MAX Phase (Mo _0.75 V _0.25 ) ₅ AlC ₄ and Its MXene Sibling (Mo _0.75 V _0.25 ) ₅ C ₄