d 6 versus d 10 , Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K 2 TGe 3 Ch 8 (T = Fe, Cd; Ch = S, Se)

Ji, Bingheng; Wang, Fei; Wu, Kui; Zhang, Bingbing; Wang, Jian

doi:10.1021/acs.inorgchem.2c03852

d ⁶ versus d ¹⁰ , Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K ₂ TGe ₃ Ch ₈ (T = Fe, Cd; Ch = S, Se)

Journal Article · 27 December 2022 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.2c03852· OSTI ID:2423360

Ji, Bingheng ^[1]; ^[2]; ^[3]; Zhang, Bingbing ^[3]; ^[1]

Department of Chemistry and Biochemistry, Wichita State University, Wichita, Kansas67260, United States
Department of Chemistry, Missouri State University, Springfield, Missouri65897, United States
Key Laboratory of Analytical Science and Technology of Hebei Province, College of Chemistry and Environmental Science, Hebei University, Baoding071002, China

Not provided.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2423360

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 1 Vol. 62; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (77)

Lone pair electron effect induced differences in linear and nonlinear optical properties of bismuth borates Cai, Wenbing; Jing, Qun; Zhang, Jun New Journal of Chemistry, Vol. 44, Issue 4 https://doi.org/10.1039/C9NJ05873G	journal	January 2020
Syntheses, structural variants and characterization of A2ZnSn3S8 (A = Cs, Rb) and A2CdSn3S8 (A = Cs, Rb, K, Na) compounds Pogu, Ashok; Vidyasagar, Kanamaluru Journal of Solid State Chemistry, Vol. 291 https://doi.org/10.1016/j.jssc.2020.121647	journal	November 2020
K ₂ ZnSn ₃ Se ₈ : A Non-Centrosymmetric Zinc Selenidostannate(IV) Featuring Interesting Covalently Bonded [ZnSn ₃ Se ₈ ] ²⁻ Layer and Exhibiting Intriguing Second Harmonic Generation Activity Zhou, Molin; Jiang, Xingxing; Yang, Yi Chemistry - An Asian Journal, Vol. 12, Issue 12 https://doi.org/10.1002/asia.201700426	journal	May 2017
A review on the recently developed promising infrared nonlinear optical materials Abudurusuli, Ailijiang; Li, Junjie; Pan, Shilie Dalton Transactions, Vol. 50, Issue 9 https://doi.org/10.1039/d1dt00054c	journal	January 2021
A Powder Technique for the Evaluation of Nonlinear Optical Materials Kurtz, S. K.; Perry, T. T. Journal of Applied Physics, Vol. 39, Issue 8 https://doi.org/10.1063/1.1656857	journal	July 1968
Synthesis and Crystal Structure of The New Selenogermanate, Cs₂CdGe₃Se₈ Hahn, Song-I; Kim, Pilsoo; Yun, Hoseop Bulletin of the Korean Chemical Society, Vol. 34, Issue 4 https://doi.org/10.5012/bkcs.2013.34.4.1250	journal	April 2013
Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials Li, Yan-Yan; Wang, Wen-Jing; Wang, Hui Crystal Growth & Design, Vol. 19, Issue 7 https://doi.org/10.1021/acs.cgd.9b00358	journal	June 2019
Lithium niobate: Summary of physical properties and crystal structure Weis, R. S.; Gaylord, T. K. Applied Physics A Solids and Surfaces, Vol. 37, Issue 4 https://doi.org/10.1007/BF00614817	journal	August 1985
Efficient second-harmonic generation in KTP crystals Driscoll, Thomas A.; Perkins, Patrick E.; Hoffman, Hanna J. Journal of the Optical Society of America B, Vol. 3, Issue 5 https://doi.org/10.1364/JOSAB.3.000683	journal	January 1986
Disconnection Enhances the Second Harmonic Generation Response: Synthesis and Characterization of Ba ₂₃ Ga ₈ Sb ₂ S ₃₈ Chen, Mei-Chun; Wu, Li-Ming; Lin, Hua Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja300249n	journal	March 2012
Unprecedented mid-infrared nonlinear optical materials achieved by crystal structure engineering, a case study of (KX)P₂S₆ (X = Sb, Bi, Ba) Nguyen, Vivian; Ji, Bingheng; Wu, Kui Chemical Science, Vol. 13, Issue 9 https://doi.org/10.1039/D1SC06849K	journal	January 2022
Cs ₂ M ^II M ^IV ₃ Q ₈ (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps Morris, Collin D.; Li, Hao; Jin, Hosub Chemistry of Materials, Vol. 25, Issue 16 https://doi.org/10.1021/cm401817r	journal	August 2013
Distortions in Octahedrally Coordinated d ⁰ Transition Metal Oxides: A Continuous Symmetry Measures Approach Ok, Kang Min; Halasyamani, P. Shiv; Casanova, David Chemistry of Materials, Vol. 18, Issue 14 https://doi.org/10.1021/cm0604817	journal	July 2006
A review on the recently developed promising infrared nonlinear optical materials Abudurusuli, Ailijiang; Li, Junjie; Pan, Shilie Dalton Transactions, Vol. 50, Issue 9 https://doi.org/10.1039/D1DT00054C	journal	January 2021
K ₂ FeGe ₃ Se ₈ : A New Antiferromagnetic Iron Selenide Feng, Kai; Wang, Wendong; He, Ran Inorganic Chemistry, Vol. 52, Issue 4 https://doi.org/10.1021/ic302394e	journal	January 2013
Centrosymmetric or Noncentrosymmetric? Transition Metals Talking in K ₂ TGe ₃ S ₈ (T = Co, Fe) Ji, Bingheng; Pandey, Krishna; Harmer, Colin P. Inorganic Chemistry, Vol. 60, Issue 14 https://doi.org/10.1021/acs.inorgchem.1c01149	journal	June 2021
Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship Liang, Fei; Kang, Lei; Lin, Zheshuai Crystal Growth & Design, Vol. 17, Issue 4 https://doi.org/10.1021/acs.cgd.7b00214	journal	March 2017
First-Principles Design and Simulations Promote the Development of Nonlinear Optical Crystals Kang, Lei; Liang, Fei; Jiang, Xingxing Accounts of Chemical Research, Vol. 53, Issue 1 https://doi.org/10.1021/acs.accounts.9b00448	journal	October 2019
Three-in-One Strategy Constructing a Series of Hybrid Tetrahedral Motif-Based Selenides with Balanced Second-Order Nonlinear Optical Performance Li, Xiao-Hui; Yao, Wen-Dong; Wei, Yu-Long Inorganic Chemistry, Vol. 60, Issue 9 https://doi.org/10.1021/acs.inorgchem.1c00441	journal	April 2021
Design and synthesis of an ultraviolet-transparent nonlinear optical crystal Sr2Be2B2O7 Chen, Chuangtian; Wang, Yebin; Wu, Baichang Nature, Vol. 373, Issue 6512 https://doi.org/10.1038/373322a0	journal	January 1995
Influence of the exchange screening parameter on the performance of screened hybrid functionals Krukau, Aliaksandr V.; Vydrov, Oleg A.; Izmaylov, Artur F. The Journal of Chemical Physics, Vol. 125, Issue 22 https://doi.org/10.1063/1.2404663	journal	December 2006
Second-order nonlinear optical materials with a benzene-like conjugated π system Liu, Hongkun; Zhang, Bingbing; Wang, Ying Chemical Communications, Vol. 56, Issue 89 https://doi.org/10.1039/D0CC05821A	journal	January 2020
Triclinic Layered A₂ZnSi₃S₈ (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A₂M^IIBM^IV₃Q₈ Family Gao, Lihua; Yang, Ya; Zhang, Bingbing Inorganic Chemistry, Vol. 60, Issue 16 https://doi.org/10.1021/acs.inorgchem.1c01886	journal	July 2021
Rational design of infrared nonlinear optical chalcogenides by chemical substitution Lin, Hua; Wei, Wen-Bo; Chen, Hong Coordination Chemistry Reviews, Vol. 406 https://doi.org/10.1016/j.ccr.2019.213150	journal	March 2020
Sb ₆ O ₇ (SO ₄ ) ₂ : A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by Sb ^III Lone‐Pair Stereoactivity Wei, Qi; He, Chao; Wang, Kui Chemistry – A European Journal, Vol. 27, Issue 19 https://doi.org/10.1002/chem.202004859	journal	January 2021
Hybrid functionals based on a screened Coulomb potential Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias The Journal of Chemical Physics, Vol. 118, Issue 18 https://doi.org/10.1063/1.1564060	journal	May 2003
SrZnSnSe4: Synthesis, crystal structure and nonlinear optical properties Pang, Xin; Wang, Ruiqi; Che, Xiangli Journal of Solid State Chemistry, Vol. 297 https://doi.org/10.1016/j.jssc.2021.122092	journal	May 2021
Deep Ultraviolet Nonlinear Optical Materials Tran, T. Thao; Yu, Hongwei; Rondinelli, James M. Chemistry of Materials, Vol. 28, Issue 15 https://doi.org/10.1021/acs.chemmater.6b02366	journal	July 2016
Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A ₃ B ₃ CD ₂ O ₁₄ Family Yu, Hongwei; Young, Joshua; Wu, Hongping Journal of the American Chemical Society, Vol. 138, Issue 14 https://doi.org/10.1021/jacs.6b02203	journal	March 2016
Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks Chen, Man‐Man; Zhou, Sheng‐Hua; Wei, Wen‐Bo Advanced Optical Materials, Vol. 10, Issue 5 https://doi.org/10.1002/adom.202102123	journal	December 2021
Rational design of a new chalcogenide with good infrared nonlinear optical performance: SrZnSnS₄ Zhang, Yiling; Mei, Dajiang; Yang, Yi Journal of Materials Chemistry C, Vol. 7, Issue 28 https://doi.org/10.1039/c9tc01713e	journal	January 2019
A₂P₂S₆ (A = Ba and Pb): a good platform to study the polymorph effect and lone pair effect to form an acentric structure Ji, Bingheng; Sarkar, Arka; Wu, Kui Dalton Transactions, Vol. 51, Issue 11 https://doi.org/10.1039/D1DT04317J	journal	January 2022
Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide Guo, Sheng‐Ping; Cheng, Xiyue; Sun, Zong‐Dong Angewandte Chemie, Vol. 131, Issue 24 https://doi.org/10.1002/ange.201902839	journal	May 2019
Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials Chen, Hong; Wei, Wen-Bo; Lin, Hua Coordination Chemistry Reviews, Vol. 448 https://doi.org/10.1016/j.ccr.2021.214154	journal	December 2021
Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds Li, Shu-Fang; Jiang, Xiao-Ming; Liu, Bin-Wen Chemistry of Materials, Vol. 29, Issue 4 https://doi.org/10.1021/acs.chemmater.6b05405	journal	February 2017
Strong Second Harmonic Generation from the Tantalum Thioarsenates A ₃ Ta ₂ AsS ₁₁ (A = K and Rb) Bera, Tarun K.; Jang, Joon I.; Ketterson, John B. Journal of the American Chemical Society, Vol. 131, Issue 1 https://doi.org/10.1021/ja807928d	journal	December 2008
Rb2FeGe3S8 and Cs2FeGe3S8: New layered chalcogenides in A2MIIMIV3Q8 family with antiferromagnetic property Wang, Weikang; Cao, Wangzhu; Zhang, Lingyun Journal of Solid State Chemistry, Vol. 313 https://doi.org/10.1016/j.jssc.2022.123276	journal	September 2022
Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO ₃ ) ₂ F ₂ Luo, Min; Liang, Fei; Hao, Xia Chemistry of Materials, Vol. 32, Issue 6 https://doi.org/10.1021/acs.chemmater.0c00196	journal	March 2020
Non‐centrosymmetric Selenides AZn₄In₅Se₁₂ (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties Lin, Hua; Zheng, Yu‐Jun; Hu, Xiao‐Ning Chemistry – An Asian Journal, Vol. 12, Issue 4 https://doi.org/10.1002/asia.201601548	journal	December 2016
Phase-Change Materials Exhibiting Tristability: Interconverting Forms of Crystalline α-, β-, and Glassy K ₂ ZnSn ₃ S ₈ Fard, Zohreh Hassanzadeh; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 51, Issue 15 https://doi.org/10.1021/ic301276y	journal	July 2012
Dimensional reduction in II-VI materials: A2Cd3Q4 (A = K, Q = S, Se, Te; A = Rb, Q = S, Se), novel ternary low-dimensional cadmium chalcogenides produced by incorporation of A2Q in CdQ Axtell, Enos A.; Liao, Ju-Hsiou; Pikramenou, Zoe Chemistry - A European Journal, Vol. 2, Issue 6 https://doi.org/10.1002/chem.19960020609	journal	June 1996
Ba₆(Cu_xZ_y)Sn₄S₁₆ (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties Ji, Bingheng; Wu, Kui; Chen, Yunhua Inorganic Chemistry, Vol. 61, Issue 5 https://doi.org/10.1021/acs.inorgchem.1c03773	journal	January 2022
K ₂ ZnGe ₃ S ₈ : A Congruent-Melting Infrared Nonlinear-Optical Material with a Large Band Gap Luo, Xiaoyu; Liang, Fei; Zhou, Molin Inorganic Chemistry, Vol. 57, Issue 15 https://doi.org/10.1021/acs.inorgchem.8b01437	journal	July 2018
A review on the development of infrared nonlinear optical materials with triangular anionic groups Chu, Yu; Li, Guangmao; Su, Xin Journal of Solid State Chemistry, Vol. 271 https://doi.org/10.1016/j.jssc.2018.10.051	journal	March 2019
K ₂ MnGe ₃ S ₈ : a new multifunctional semiconductor featuring [MnGe ₃ S ₈ ] ²⁻ layers and demonstrating interesting nonlinear optical response and antiferromagnetic properties Li, Zhuang; Jiang, Xingxing; Yi, Changjiang Journal of Materials Chemistry C, Vol. 6, Issue 37 https://doi.org/10.1039/c8tc03694b	journal	January 2018
KBiMS4 (M=Si, Ge): Synthesis, structure, and electronic structure Mei, Dajiang; Lin, Zheshuai; Bai, Lei Journal of Solid State Chemistry, Vol. 183, Issue 7 https://doi.org/10.1016/j.jssc.2010.05.003	journal	July 2010
Noncentrosymmetric quaternary selenide Ba23Ga8Sb2Se38: Synthesis, structure, and optical properties Yin, Wenlong; Zhou, Molin; Iyer, Abishek K. Journal of Alloys and Compounds, Vol. 729 https://doi.org/10.1016/j.jallcom.2017.09.127	journal	December 2017
Phase-Matching in Nonlinear Optical Compounds: A Materials Perspective Zhang, Weiguo; Yu, Hongwei; Wu, Hongping Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.7b00243	journal	March 2017
New nonlinear-optical crystal: LiB_3O_5 Chen, Chuangtian; Wu, Yicheng; Jiang, Aidong Journal of the Optical Society of America B, Vol. 6, Issue 4 https://doi.org/10.1364/JOSAB.6.000616	journal	January 1989
Lone pair effects on ternary infrared nonlinear optical materials Yin, Ruonan; Hu, Cong; Lei, Bing-Hua Physical Chemistry Chemical Physics, Vol. 21, Issue 9 https://doi.org/10.1039/C8CP07894G	journal	January 2019
Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn ₂ Se ₆ and RbInSn ₂ Se ₆ Lin, Hua; Chen, Hong; Zheng, Yu-Jun Dalton Transactions, Vol. 46, Issue 24 https://doi.org/10.1039/c7dt01384a	journal	January 2017
First Examples of Gold Thiocadmates: A2Au2Cd2S4 (A=Rb, Cs) and K2Au4CdS4: Bright Photoluminescence from New Alkali Metal/Gold Thiocadmates Axtell III, Enos A.; Kanatzidis, Mercouri G. Chemistry - A European Journal, Vol. 4, Issue 12 https://doi.org/10.1002/(sici)1521-3765(19981204)4:12<2435::aid-chem2435>3.0.co;2-v	journal	December 1998
Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis Kang, Lei; Zhou, Molin; Yao, Jiyong Journal of the American Chemical Society, Vol. 137, Issue 40 https://doi.org/10.1021/jacs.5b07920	journal	September 2015
Inorganic planar π-conjugated groups in nonlinear optical crystals: review and outlook Gong, Pifu; Liu, Xiaomeng; Kang, Lei Inorganic Chemistry Frontiers, Vol. 7, Issue 4 https://doi.org/10.1039/C9QI01589B	journal	January 2020
Second-Harmonic Generation and Crystal Structure of the Diamond-like Semiconductors Li ₂ CdGeS ₄ and Li ₂ CdSnS ₄ Lekse, Jonathan W.; Moreau, Meghann A.; McNerny, Katie L. Inorganic Chemistry, Vol. 48, Issue 16 https://doi.org/10.1021/ic9010339	journal	July 2009
Rational designviadual-site aliovalent substitution leads to an outstanding IR nonlinear optical material with well-balanced comprehensive properties Yang, He-Di; Ran, Mao-Yin; Zhou, Sheng-Hua Chemical Science, Vol. 13, Issue 36 https://doi.org/10.1039/D2SC03760B	journal	January 2022
AgGaSe₂-Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury Gao, Lihua; Xu, Jingjing; Tian, Xinyu Chemistry of Materials, Vol. 34, Issue 13 https://doi.org/10.1021/acs.chemmater.2c01011	journal	June 2022
Synthesis and Structures of the Quaternary Chalcogenides of the Type KLnMQ4 (Ln = La, Nd, Gd, Y; M = Si, Ge; Q = S, Se) Wu, Ping; Ibers, James A. Journal of Solid State Chemistry, Vol. 107, Issue 2 https://doi.org/10.1006/jssc.1993.1357	journal	December 1993
Alignment of Lone Pairs in a New Polar Material: Synthesis, Characterization, and Functional Properties of Li ₂ Ti(IO ₃ ) ₆ Chang, Hong-Young; Kim, Sang-Hwan; Halasyamani, P. Shiv Journal of the American Chemical Society, Vol. 131, Issue 7 https://doi.org/10.1021/ja808469a	journal	February 2009
Pb ₁₇ O ₈ Cl ₁₈ : A Promising IR Nonlinear Optical Material with Large Laser Damage Threshold Synthesized in an Open System Zhang, Hui; Zhang, Min; Pan, Shilie Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b03986	journal	June 2015
Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures Ok, Kang Min Accounts of Chemical Research, Vol. 49, Issue 12 https://doi.org/10.1021/acs.accounts.6b00452	journal	November 2016
Relaxation of Crystals with the Quasi-Newton Method Pfrommer, Bernd G.; Côté, Michel; Louie, Steven G. Journal of Computational Physics, Vol. 131, Issue 1 https://doi.org/10.1006/jcph.1996.5612	journal	February 1997
Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd₄Ga₅S₁₂ (A = K, Rb, Cs) Lin, Hua; Zhou, Liu-Jiang; Chen, Ling Chemistry of Materials, Vol. 24, Issue 17 https://doi.org/10.1021/cm301550a	journal	August 2012
The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe2 Clark, Daniel J.; Zhang, Jian-Han; Craig, Andrew J. Journal of Alloys and Compounds, Vol. 917 https://doi.org/10.1016/j.jallcom.2022.165381	journal	October 2022
Six New Members of the A ₂ M ^II M ^IV ₃ Q ₈ Family and Their Structural Relationship Hu, Xiao-Ning; Xiong, Lin; Wu, Li-Ming Crystal Growth & Design, Vol. 18, Issue 5 https://doi.org/10.1021/acs.cgd.8b00247	journal	March 2018
Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles Liu, Youchao; Shen, Yaoguo; Zhao, Sangen Coordination Chemistry Reviews, Vol. 407 https://doi.org/10.1016/j.ccr.2019.213152	journal	March 2020
Crystal structure and twinning of KCd₄Ga₅S¹² and some isotypic AB₄C₅X₁₂ compounds Schwer, H.; Keller, E.; Krämer, V. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 204, Issue 1-2 https://doi.org/10.1524/zkri.1993.204.12.203	journal	July 1993
Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe₃Se₈, K₃Ga₃Ge₇S₂₀, and K₃Ga₃Ge₇Se₂₀ Li, Xiaoshuang; Li, Chao; Gong, Pifu Dalton Transactions, Vol. 45, Issue 2 https://doi.org/10.1039/c5dt03682h	journal	January 2016
Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AX ^II ₄ X ^III ₅ Se ₁₂ Lin, Hua; Chen, Ling; Zhou, Liu-Jiang Journal of the American Chemical Society, Vol. 135, Issue 34 https://doi.org/10.1021/ja4074084	journal	August 2013
Strong SHG Response via High Orientation of Tetrahedral Functional Motifs in Polyselenide A₂Ge₄Se₁₀ (A = Rb, Cs) Liu, Bin‐Wen; Hu, Chun‐Li; Zeng, Hui‐Yi Advanced Optical Materials, Vol. 6, Issue 13 https://doi.org/10.1002/adom.201800156	journal	May 2018
High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence Dong, Xuehua; Huang, Ling; Zeng, Hongmei Angewandte Chemie International Edition, Vol. 61, Issue 10 https://doi.org/10.1002/anie.202116790	journal	January 2022
Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation Morris, Collin D.; Chung, In; Park, Sungoh Journal of the American Chemical Society, Vol. 134, Issue 51 https://doi.org/10.1021/ja309386e	journal	December 2012
Li ₂ CdGeSe ₄ and Li ₂ CdSnSe ₄ : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence Zhang, Jian-Han; Clark, Daniel J.; Weiland, Ashley Inorganic Chemistry Frontiers, Vol. 4, Issue 9 https://doi.org/10.1039/c7qi00004a	journal	January 2017
Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La₄Ge₃Se_xS_12−x (x = 0, 2, 4, 6, 8, 10) Cicirello, Gary; Wu, Kui; Zhang, Bing Bing Inorganic Chemistry Frontiers, Vol. 8, Issue 22 https://doi.org/10.1039/d1qi00879j	journal	January 2021
Development of nonlinear optical materials promoted by density functional theory simulations Jiang, Xingxing; Kang, Lei; Luo, Siyang International Journal of Modern Physics B, Vol. 28, Issue 27 https://doi.org/10.1142/S0217979214300187	journal	October 2014
Mild Solvothermal Syntheses of Thioargentates A–Ag–S (A = K, Rb, Cs) and A–Ag–Ge–S (A = Na, Rb): Crucial Role of Excess Sulfur Zhang, Chi; Wang, Kai-Ni; Ji, Min Inorganic Chemistry, Vol. 52, Issue 21 https://doi.org/10.1021/ic402092r	journal	October 2013
Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials Chung, In; Kanatzidis, Mercouri G. Chemistry of Materials, Vol. 26, Issue 1 https://doi.org/10.1021/cm401737s	journal	August 2013

Similar Records

Centrosymmetric or Noncentrosymmetric? Transition Metals Talking in K₂TGe₃S₈(T = Co, Fe)

Journal Article · 2021 · Inorganic Chemistry · OSTI ID:1810574

Phase Transition, Conformational Exchange, and Nonlinear Optical Third Harmonic Generation of A CsP ₂ Se ₈ ( A = K, Rb, Cs)

Journal Article · 2016 · Chemistry of Materials · OSTI ID:1352633

Revisiting two thiophosphate compounds constituting d⁰ transition metal HfP₂S₆and d¹⁰ transition metal α-Ag₄P₂S₆ as multifunctional materials for combining second harmonic generation response and photocurrent response

Journal Article · 2023 · CrystEngComm · OSTI ID:2423591

Related Subjects

Chemistry

d 6 versus d 10 , Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K 2 TGe 3 Ch 8 (T = Fe, Cd; Ch = S, Se)

Citation Formats

References (77)

Similar Records

Related Subjects

d ⁶ versus d ¹⁰ , Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K ₂ TGe ₃ Ch ₈ (T = Fe, Cd; Ch = S, Se)