Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Origin of Surface Amorphization and Catalytic Stability of Ca 2–x IrO 4 Nanocrystals for Acidic Oxygen Evolution: Critical Roles of Acid Anions

Journal Article · · ACS Catalysis
 [1];  [2];  [3];  [1];  [1];  [1];  [1];  [1];  [4];  [1]
  1. National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China
  2. Department of Physics, National University of Singapore, Singapore 117542, Singapore
  3. MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter, Shaanxi Province Key Laboratory of Advanced Functional Materials and Mesoscopic Physics, School of Physics, Xi’an Jiaotong University, Xi’an, Shaanxi 710049, P. R. China
  4. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
Not provided.
Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-05CH11231
OSTI ID:
2422616
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 21 Vol. 12; ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (27)

XANES and EXAFS Studies on the Ir-O Bond Covalency in Ionic Iridium Perovskites journal August 1995
A Dissolution/Precipitation Equilibrium on the Surface of Iridium‐Based Perovskites Controls Their Activity as Oxygen Evolution Reaction Catalysts in Acidic Media journal February 2019
Lattice site–dependent metal leaching in perovskites toward a honeycomb-like water oxidation catalyst journal December 2021
Electrolysis of water on oxide surfaces journal September 2007
Efficient acidic oxygen evolution reaction electrocatalyzed by iridium-based 12L-perovskites comprising trinuclear face-shared IrO6 octahedral strings journal August 2020
Understanding Degradation Mechanisms in SrIrO 3 Oxygen Evolution Electrocatalysts: Chemical and Structural Microscopy at the Nanoscale journal June 2021
Iridium-based double perovskites for efficient water oxidation in acid media journal August 2016
A unique oxygen ligand environment facilitates water oxidation in hole-doped IrNiOx core–shell electrocatalysts journal October 2018
Dissolution-Induced Surface Roughening and Oxygen Evolution Electrocatalysis of Alkaline-Earth Iridates in Acid journal December 2019
The Stability Challenges of Oxygen Evolving Catalysts: Towards a Common Fundamental Understanding and Mitigation of Catalyst Degradation journal May 2017
A highly active and stable IrO x /SrIrO 3 catalyst for the oxygen evolution reaction journal September 2016
Synthesis and Activities of Rutile IrO 2 and RuO 2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions journal January 2012
Identification of the Active-Layer Structures for Acidic Oxygen Evolution from 9R-BaIrO3 Electrocatalyst with Enhanced Iridium Mass Activity journal October 2021
Discovery of crystal structure–stability correlation in iridates for oxygen evolution electrocatalysis in acid journal January 2020
Recent Development of Oxygen Evolution Electrocatalysts in Acidic Environment journal March 2021
Constant Change: Exploring Dynamic Oxygen Evolution Reaction Catalysis and Material Transformations in Strontium Zinc Iridate Perovskite in Acid journal June 2021
Efficient oxygen evolution electrocatalysis in acid by a perovskite with face-sharing IrO6 octahedral dimers journal December 2018
The stability number as a metric for electrocatalyst stability benchmarking journal June 2018
Exceptionally active iridium evolved from a pseudo-cubic perovskite for oxygen evolution in acid journal February 2019
Amorphization mechanism of SrIrO 3 electrocatalyst: How oxygen redox initiates ionic diffusion and structural reorganization journal January 2021
Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction journal December 2016
Molecular Insight in Structure and Activity of Highly Efficient, Low-Ir Ir–Ni Oxide Catalysts for Electrochemical Water Splitting (OER) journal September 2015
Electron Correlations Engineer Catalytic Activity of Pyrochlore Iridates for Acidic Water Oxidation journal December 2018
Considerations for the scaling-up of water splitting catalysts journal May 2019
Using Surface Segregation To Design Stable Ru-Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments journal October 2014
The X-ray photoelectron spectra of Ir, IrO 2 and IrCl 3 revisited: The X-ray photoelectron spectra of Ir, IrO 2 and IrCl 3 revisited journal March 2017
Recent Progress in Advanced Electrocatalyst Design for Acidic Oxygen Evolution Reaction journal March 2021

Similar Records

Importance of Surface IrOx in Stabilizing RuO2 for Oxygen Evolution
Journal Article · 2017 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1471514

Rationalizing Acidic Oxygen Evolution Reaction over IrO 2 : Essential Role of Hydronium Cation
Journal Article · 2024 · Angewandte Chemie · OSTI ID:2514496

Related Subjects